MH-Lab | Elena S. Shubina

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Elena S. Shubina

Elena S. Shubina

Personal Info

Address

A.N.Nesmeyanov Institute of Organoelement Compounds (INEOS)
Russian Academy of Sciences, Vavilov St. 28, Moscow, 119991, Russia

Phone

+7 (499) 135-18-71

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Academic Degree

Ph.D. in Chemistry, Moscow State University (1982)
D. Sc. in Chemistry, INEOS RAS (1997)
Prof. Physical Chemistry (2006)

Experience

1969-1974 - M.V.Lomonosov Moscow State University, Chemistry Department
1978-1982 - Postgraduate course at Moscow State University
1974-1978 - junior researcher, Moscow Institute of Petrochemical and Gas Industry
1982-1986 - junior research scientist, INEOS RAS
1986-1991 - research scientist, INEOS RAS
1991-1998 - senior research scientist, INEOS RAS
1998-2001 - leading research scientist, INEOS RAS
2001-2003 - leading researcher, Head of the Group of Metal Hydrides
2004 - present time - Head of the Laboratory of Metal Hydrides, INEOS RAS

Scientific Interests

Organometallic, Inorganic, Physical chemistry; molecular spectroscopy; structure and reactivity of transition metal hydride complexes and main group hydrides; intermolecular interactions; hydrogen bonding and proton transfer in organometallic chemistry; supramolecular design based on macrocyclic pyrazolates of copper(I) or silver(I) and metal-oxo clusters with organoelement and organic ligands

Awards

Three new types of intermolecular hydrogen bonds typical for organometallic compounds have been comprehensively explored: hydrogen bonds to transition metal atom as proton acceptor, to hydride ligand as proton acceptor and with hydride ligand as proton donor. Approaches to mechanistic studies of proton transfer reactions of transition metal and main group element hydrides have been developed. Their application allowed showing a guiding role of various unusual hydrogen bonds that determine the proton transfer pathway and the reaction selectivity. Relationship between the thermodynamic and kinetic parameters of each reaction step and peculiarities of potential energy profiles have been deduced.

Additional

over 150 Papers in peer-review journals including 3 book chapters: “Dihydrogen bonded complexes and proton transfer to hydride ligand by spectral (IR, NMR) studies” in Recent Advances in Hydride Chemistry, Elsevier Science, 2001; “Weak Interactions and M-H Bond Activation” in Advances in Organometallic Chemistry: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book, First Edition. Ed.: A. J. L. Pombeiro. John Willey & Sons, Inc., 2014, chapt. 8, 97-109; “IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies” in Spectrosc. Prop. Inorg. Organomet. Compd., 2012, 43, 1–28

Supervisor of 10 Ph. D. Thesis

Invited Lecturer: Lecturer at Universities of Germany, India, Japan, France, Portugal, Spain, Italy in 1995-2014.
Visiting Professor at Université de Bourgogne, Dijon in 2001–2004 and Toulouse 2012

Plenary, Invited or Keynote lecturer at XIII FECHEM Conference on Organometallic Chemistry 1999; 12th International Conference on Boron Chemistry 2005; Japan, International Conference “From molecules towards materials”, Russia, 2005; International Conference on Cluster Chemistry and Polynuclear Compounds, Russia 2006, XVII EuCheMS Conference on Organometallic Chemistry, Sofia, Bulgaria 2007,. XIII IMEBORON, Barcelone, Spain, 2008, XIV IMEBORON, Canada, 2011, International Conference on Organometallic and Coordination Chemistry, N. Novgorod, Russia, 2008, 2010, 2013, 2015, International Conference on Hydrogen and Hydrogen Storage: Methods and Materials, January, 2009, Bangalore, India, XXV ICOMC Portugal 2012, 79th Annual Meeting of the Israeli Chemical Society 2014; International Conference on Coordination Chemistry ICCC-41, Singapore, 2014, International Symposium on “New Horizons in Chemistry” and Interdisciplinary Symposium on Material Chemistry, Mumbai, India, 2014.

Total over 100 Communications at International scientific meetings

International and National Activity:

Russian representative in the EuCheMS Division on Organometallic Chemistry since 2007
Member of the Organizing Committees of International conferences on Organometallic Chemistry held in Russia since 1993
Organizer of Franco-Russian seminars “Homogeneous catalysis for the sustainable development” 2009, 2012, 2015
Russian Coordinator of the 3 bilateral Projects between CNR (Rome) and the Russian Academy of Sciences (Moscow) in 2008-2009; 2010-2011; 2012-2013
Russian Coordinator of bilateral RFBR - CNRS Projects (PICS) in 2005-2007
Russian Coordinator of International research group (GDRI) “Homogeneous catalysis for the sustainable development” (France, Italy, Russia) 2008-2015
Russian Coordinator of RFBR (Russia)- CNR (Italy) research project 2015-2017
Responsible of 8 RFBR projects since 1995
Referee of the following international journals: Journal of the American Chemical Society; Coordination Chemistry Reviews; Chemistry – the European Journal; Chemical Communications; Organometallics; Dalton Transactions; Inorganic Chemistry; European Journal of Inorganic Chemistry; Journal of Organometallic Chemistry; Journal of Molecular Structure; Inorganica Chimica Acta; Inorganic Chemistry Communications; Journal of the Physical Chemistry.

Publications

2023

Molecules, 2023, 28(3), 1189, DOI: 10.3390/molecules28031189
Yakovlev G. B., A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu, O. A. Filippov, E. S. Shubina
Tetranuclear Copper(I) and Silver(I) Pyrazolate Adducts with 1,1$\prime$-Dimethyl-2,2’-bibenzimidazole: Influence of Structure on Photophysics
Molecules, 2023, 28(3), 1211, DOI: 10.3390/molecules28031211
A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., Zueva Anna Y., Shul’pina Lidia S., E. S. Shubina, Ikonnikov Nikolay S., G. B. Shul’pin
Cagelike octacopper methylsilsesquioxanes: self-assembly in the focus of alkaline metal ion influence—synthesis, structure, and catalytic activity
Russ. Chem. Bull., 2023, 72(1)
N. V. Kireev, O. A. Filippov, L. M. Epstein, E. S. Shubina, N. V. Belkova
Activation of dinitrogen by group 6 metal complexes

2022

Molecules, 2022, 27(23), 8505, DOI: 10.3390/molecules27238505
A. N. Bilyachenko, Khrustalev V. N., E. I. Gutsul, Zueva A. Y., Korlyukov A. A., Shul'pina L. S., Ikonnikov N. S., Dorovatovskii P. V., D. Gelman, E. S. Shubina, G. B. Shul’pin
Hybrid Silsesquioxane/Benzoate Cu7-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity
Inorg. Chem. Front., 2022, 9(21), 5624-5634, DOI: 10.1039/d2qi01648f
S. K. Emashova, A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu, Godovikov Ivan A., Godovikova Maria I., Dorovatovskii Pavel V., Korlyukov Alexander A., O. A. Filippov, E. S. Shubina
Emissive Silver(I) Cyclic Trinuclear Complexes with Aromatic Amine Donor Pyrazolate Derivatives: Way to Efficiency
Russian Journal of Inorganic Chemistry, 2022, 48(10), 615-621, DOI: 10.1134/S1070328422100086
A. A. Titov, Smol'yakov A.F., O. A. Filippov, N. V. Belkova, E. S. Shubina
Halogen or Arene: Complexation of 4,4'-Dibromobiphenyl with a Three-Membered Silver(I) Macrocycle
Inorg. Chem. Front., 2022, 9(17), 4525-4537, DOI: 10.1039/d2qi01054b
G. S. Astakhov, Khrustalev Victor N., M. S. Dronova, E. I. Gutsul, Korlyukov Alexander, D. Gelman, Zubavichus Yan V., Novichkov Daniil, Trigub Alexander, E. S. Shubina, A. N. Bilyachenko
Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
Molecules, 2022, 27(19), 6205, DOI: 10.3390/molecules27196205
A. N. Bilyachenko, Khrustalev V.N., Zueva A.Y., E. M. Kozinets (Titova), G. S. Astakhov, Zubavichus Y.V., Dorovatovskii P.V., Korlyukov A.S., Shul'pina L.S., E. S. Shubina, Kozlov Y.N., Ikonnikov N.S., D. Gelman, G. B. Shul’pin
A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity
Inorg. Chem., 2022, 61(37), 14800-14814, DOI: 10.1021/acs.inorgchem.2c02217
A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., G. S. Astakhov, Zueva Anna Y., Zubavichus Yan V., Kirillova Marina V., Shul’pina Lidia S., Ikonnikov Nikolay S., Dorovatovskii Pavel V., E. S. Shubina, Kirillov Alexander M., G. B. Shul’pin
Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
Inorg. Chim. Acta, 2022, 539, 121004, DOI: 10.1016/j.ica.2022.121004
A. A. Titov, Smol'yakov Alexander F., Godovikov Ivan A., Chernyadyev Andrey Yu, Molotkov Alexander P., Loginov Dmitry A., O. A. Filippov, N. V. Belkova, E. S. Shubina
The role of weak intermolecular interactions in photophysical behavior of isocoumarins on the example of their interaction with cyclic trinuclear silver(I) pyrazolate
Chemical Communications, 2022, 58(32), 5017-5020, DOI: 10.1039/D2CC00999D
E. S. Osipova, E. Gulyaeva, N. V. Kireev, Kovalenko Sergey A., Bijani Crisitan, Canac Yves, D. Valyaev, O. A. Filippov, N. V. Belkova, E. S. Shubina
Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(Ph2PCH2PPh2)Mn(CO)3H]
Crystal Growth and Design, 2022, 22(4), 2146-2157, DOI: 10.1021/acs.cgd.1c01225
A. N. Bilyachenko, G. S. Astakhov, A. N. Kulakova, Korlyukov Alexander A., Zubavichus Yan V., Dorovatovskii Pavel V., Shul’pina Lidia S., E. S. Shubina, Ikonnikov Nikolay S., Kirillova Marina V., Zueva Anna Y., Kirillov Alexander M., G. B. Shul’pin
Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures
Chemical Communications, 2022, 58(6), 859-862, DOI: 10.1039/D1CC06401K
V. A. Kirkina, Kissel Alexander A., Selikhov Alexander N., Nelyubina Yulia V., O. A. Filippov, N. V. Belkova, Trifonov Alexander A., E. S. Shubina
Amine-boranes reactions promoted by lanthanide(ii) ions

2021

Eur. J. Inorg. Chem., 2021, 2021(41), 4265 - 4272, DOI: 10.1002/ejic.202100489
N. V. Kireev, Kiryutin A.S., Pavlov A.A., Yurkovskaya A.V., Musina E.I., Karasik A.A., E. S. Shubina, Ivanov K.L., N. V. Belkova
Nickel(II) dihydrogen and hydride complexes as the intermediates of H2 heterolytic splitting by nickel diazadiphosphacyclooctane complexes
RSC Adv., 2021, 11(25), 34735 - 34741, DOI: 10.1039/D1RA06755A
Nigoghossian K., A. N. Kulakova, Félix G., Khrustalev V.N., E. S. Shubina, Long J., Guari Y., Sene S., Carlos L.D., A. N. Bilyachenko, J. Larionova
Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
Molecules, 2021, 26(22), 6869, DOI: 10.3390/molecules26226869
K. F. Baranova, A. A. Titov, Smol’yakov A.F., Chernyadyev A.Y., O. A. Filippov, E. S. Shubina
Mononuclear copper(I) 3-(2-pyridyl)pyrazole complexes: the crucial role of phosphine on photoluminescence
Russian Journal of Inorganic Chemistry, 2021, 66(11), 1639 - 1648, DOI: 10.3390/molecules26123754
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The mechanism of halogenation of decahydro-closo-decaborate dianion by hydrogen chloride
Molecules, 2021, 26(12), 3754, DOI: 10.3390/molecules26123754
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The reaction of hydrogen halides with tetrahydroborate anion and hexahydro-closo-hexaborate dianion
Eur. J. Inorg. Chem., 2021, 2021(27), 2696-2701, DOI: 10.1002/ejic.202100308
A. N. Kulakova, Nigoghossian Karina, Félix Gautier, Khrustalev Victor N., E. S. Shubina, Long Jérôme, Guari Yannick, Carlos Luis D., A. N. Bilyachenko, J. Larionova
New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages
Inorg. Chem., 2021, 60(11), 8062-8074, DOI: 10.1021/acs.inorgchem.1c00586
G. S. Astakhov, M. M. Levitsky, Zubavichus Y. V., Khrustalev Victor N., A. A. Titov, Dorovatovskii Pavel V., Smol’yakov Alexander F., E. S. Shubina, Kirillova Marina V., A. Kirillov, A. N. Bilyachenko
Cu6- and Cu8-Cage Sil- and Germsesquioxanes: Synthetic and Structural Features, Oxidative Rearrangements, and Catalytic Activity
Mendeleev Communications, 2021, 31(2), 170-172, DOI: 10.1016/j.mencom.2021.03.008
A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., Averin Alexey A., E. S. Shubina
New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2'-bipyridine
Coord. Chem. Rev., 2021, 438, 213799, DOI: 10.1016/j.ccr.2021.213799
N. V. Belkova, O. A. Filippov, E. S. Osipova, S. V. Safronov, L. M. Epstein, E. S. Shubina
Iinfluence of phosphine (pincer) ligands on the transition metal hydrides reactivity
Chemical science, 2021, 12, 3682-3692, DOI: DOI: 10.1039/D0SC06114J
E. S. Osipova, E. Gulyaeva, E. I. Gutsul, V. A. Kirkina, A. A. Pavlov, Y. V. Nelyubina, A. Rossin, M. Peruzzini, L. M. Epstein, N. V. Belkova, O. A. Filippov, E. S. Shubina
Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”

2020

ChemCatChem, 2020, 12(23), 5959-5965, DOI: 10.1002/cctc.202001308
D. Gelman, De-Botton Sophie, O. A. Filippov, E. S. Shubina, N. V. Belkova
Regioselective Isomerization of Terminal Alkenes Catalyzed by a PC(sp3)P Pincer Complex with a Hemilabile Pendant Arm
Crystals, 2020, 10(10), 881, DOI: 10.3390/cryst10100881
K. F. Baranova, A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., Averin Alexey A., E. S. Shubina
Dinuclear Silver(I) Nitrate Complexes with Bridging Bisphosphinomethanes: Argentophilicity and Luminescence
Inorg. Chem., 2020, 59(17), 12240–12251, DOI: 10.1021/acs.inorgchem.0c01293
E. D. Voronova, I. E. Golub, Pavlov A., N. V. Belkova, O. A. Filippov, L. M. Epstein, E. S. Shubina
Dichotomous Si–H Bond Activation by Alkoxide and Alcohol in Base-Catalyzed Dehydrocoupling of Silanes
Chem. A Eur. J., 2020, 26(70), 16594-16598, DOI: 10.1002/chem.202003351
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, Khrustalev V., E. S. Shubina, Felix G., Mamontova E., Long J., Guari Y., J. Larionova
New Luminescent Tetranuclear Lanthanide‐based Silsesquioxane Cage‐like Architectures
Molecules, 2020, 25(9), 2236, DOI: 10.3390/molecules25092236
Safronov S. V., E. S. Osipova, Nelyubina Y. V., O. A. Filippov, Barakovskaya I. G., N. V. Belkova, E. S. Shubina
Steric and Electronic Effect of Cp-Substituents on the Structure of the Ruthenocene Based Pincer Palladium Borohydrides
Mendeleev Communications, 2020, 30(3), 276-278, DOI: 10.1016/j.mencom.2020.05.004
V. A. Kirkina, E. S. Osipova, O. A. Filippov, G. A. Silantyev, D. Gelman, E. S. Shubina, N. V. Belkova
Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
J. Organomet. Chem., 2020, 906, DOI: 10.1016/j.jorganchem.2019.121022
G. S. Astakhov, M. M. Levitsky, Bantreil X., F. Lamaty, Khrustalev V.N., Zubavichus Y.V., Dorovatovskii P.V., E. S. Shubina, A. N. Bilyachenko
Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
Molecules, 2020, 25(12), 2920, DOI: 10.3390/molecules25122920
I. E. Golub, O. A. Filippov, V. Kulikova, N. V. Belkova, L. M. Epstein, E. S. Shubina
Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes
Journal of Catalysis, 2020, 390, 37-45, DOI: 10.1016/j.jcat.2020.07.010
Larionov V. A., Stashneva A. R., A. A. Titov, Lisov A. A., Medvedev M. G., Smol’yakov A. F., Tsedilin A. M., E. S. Shubina, Maleev V. I.
Mechanistic Study in Azide-Alkyne Cycloaddition (CuAAC) Catalyzed by Bifunctional Trinuclear Copper(I) Pyrazolate Complex: Shift in Rate-Determining Step
Inorg. Chem., 2020, 59(17), 11962–11975, DOI: 10.1021/acs.inorgchem.0c00797
V. A. Kirkina, G. A. Silantyev, De-botton Sophie, O. A. Filippov, E. M. Kozinets (Titova), Pavlov Alexander, N. V. Belkova, L. M. Epstein, D. Gelman, E. S. Shubina
Stereoisomerism as an Origin of Different Reactivity of Ir(III) PC(sp3)P Pincer Catalysts
Inorg. Chem., 2020, 59(7) , 4536–4545, DOI: 10.1021/acs.inorgchem.9b03680
G. S. Astakhov, A. N. Bilyachenko, M. M. Levitsky, Lidia S. Shulpina, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Anna V. Vologzhanina, E. S. Shubina, Pavel V. Dorovatovskii, G. B. Shul’pin
Coordination Affinity of Cu(II)-Based Silsesquioxanes toward N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic Products Exhibiting a High Catalytic Activity in Oxidation Reactions
Chemical Communications, 2020, 56, 2139-2142, DOI: 10.1039/C9CC07713H
N. V. Kireev, O. A. Filippov, E. Gulyaeva, E. S. Shubina, Laure Vendier, Yves CANAC, Jean-Baptiste Sortais, Noël Lugan, D. Valyaev
Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation

2019

Mendeleev Communications, 2019, 29 (5), 570-572, DOI: 10.1016/j.mencom.2019.09.031
A. A. Titov, O. A. Filippov, A.F. Smol’yakov, A.A. Averin, E. S. Shubina
Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
Eur. J. Inorg. Chem., 2019, 2019 (45), 4855-4861, DOI: 10.1002/ejic.201901050
S. K. Emashova, A. A. Titov, O. A. Filippov, A.F. Smol'yakov, E. M. Kozinets (Titova), L. M. Epstein, E. S. Shubina
Luminescent AgI Complexes with 2,2′-Bipyridine Derivatives Featuring [Ag-(CF3)2Pyrazolate]4 Units
J. Organomet. Chem., 2019, DOI: 10.1016/j.jorganchem.2019.121022
G. S. Astakhov, M. M. Levitsky, X. Bantreil, F. Lamaty, V.N. Khrustalev, Y.V. Zubavichus, P.V. Dorovatovskii, E. S. Shubina, A. N. Bilyachenko
Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
J. Organomet. Chem., 2019, 899, DOI: 10.1016/j.jorganchem.2019.120911
A. N. Kulakova, E.E.Sedykh, M. M. Levitsky, P.V.Dorovatovskii, V.N.Khrustalev, L.S.Shul'pina, E. S. Shubina, Y.N.Kozlov, N.S.Ikonnikova, A. N. Bilyachenko, G. B. Shul’pin
The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
Catalysts, 2019, 9(9), 701-719, DOI: 10.3390/catal9090701
G. S. Astakhov, M. M. Levitsky, A. A. Korlyukov, L. S. Shul’pina, E. S. Shubina, N. S. Ikonnikov, A. V. Vologzhanina, A. N. Bilyachenko, P. V. Dorovatovskii, Y. N. Kozlov, G. B. Shul’pin
New Cu4Na4- and Cu5-Based Phenylsilsesquioxanes. Synthesis via Complexation with 1,10-Phenanthroline, Structures and High Catalytic Activity in Alkane Oxidations with Peroxides in Acetonitrile
Coord. Chem. Rev., 2019, 398, 213015, DOI: 10.1016/j.ccr.2019.213015
M. M. Levitsky, A. N. Bilyachenko, E. S. Shubina, J.Long, Y.Guari, J. Larionova
Magnetic cage-like metallasilsesquioxanes
Dalton Trans., 2019, 48, 12720 - 12729, DOI: 10.1039/C9DT02176K
S. V. Safronov, E. I. Gutsul, I. E. Golub, F. M. Dolgushin, Y. V. Nelyubina, O. A. Filippov, L. M. Epstein, A. S. Peregudov, N. V. Belkova, E. S. Shubina
Synthesis, Structural Properties and Reactivity of Ruthenocene-based Pincer Pd(II) Tetrahydroborate
Inorg. Chem., 2019, 58(13), 8645-8656, DOI: 10.1021/acs.inorgchem.9b00991
A. A. Titov, O. A. Filippov, A.F. Smolyakov, I.A. Godovikov, J.R. Shakirova, S. P. Tunik, I.S. Podkorytov, E. S. Shubina
Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane
Dalton Trans., 2019, 48, 8410-8417, DOI: 10.1039/c9dt01355e
A. A. Titov, O. A. Filippov, A.F. Smol’yakov, A.A. Averin, E. S. Shubina
Syntheses, Structures and Luminescence of multinuclear Silver(I) pyrazolate adducts with 1, 10-Phenanthroline derivatives
J. Clust. Sci., 2019, DOI: 10.1007/s10876-019-01567-y
M. M. Levitsky, Y.V. Zubavichus, A.A. Korlyukov, V. N. Khrustalev, E. S. Shubina, A. N. Bilyachenko
Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes
Mendeleev Communications, 2019, 29, 121–127, DOI: 10.1016/j.mencom.2019.03.001
E. S. Osipova, O. A. Filippov, E. S. Shubina, N. V. Belkova
Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes
Coord. Chem. Rev., 2019, 386, 209-239, DOI: 10.1016/j.ccr.2019.02.007
M. M. Levitsky, A. N. Bilyachenko, E. S. Shubina
Cagelike metallagermanates and metallagermoxanes: Synthesis, structures and functional properties
Eur. J. Inorg. Chem., 2019, 10, 1389-1397, DOI: 10.1002/ejic.201801341
E. S. Osipova, E. Gulyaeva, O. A. Filippov, S. V. Safronov, A. A. Pavlov, A. V. Polukeev, V. A. Kirkina, E. M. Kozinets (Titova), E. S. Shubina, N. V. Belkova
Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes
J. Organomet. Chem., 2019, 884, 17-28, DOI: 10.1016/j.jorganchem.2019.01.004
A. N. Kulakova, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Xavier Bantreil, Lidia S. Shul'pina, M. M. Levitsky, Nikolay S. Ikonnikov, E. S. Shubina, F. Lamaty, A. N. Bilyachenko, G. B. Shul’pin
Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
Chemical Communications, 2019, 55, 290-293, DOI: 10.1039/C8CC08592G
A. A. Titov, V. A. Larionov, A. F. Smol’yakov, M. I. Godovikova, E. M. Kozinets (Titova), V. I. Maleev, E. S. Shubina
Interaction of a trinuclear copper(I) pyrazolate with alkynes and carbon–carbon triple bond activation
Eur. J. Inorg. Chem., 2019, 6, 821-827, DOI: 10.1002/ejic.201801318
A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., K. F. Baranova, E. M. Kozinets (Titova), Averin Aleksey A., E. S. Shubina
Dinuclear Cu(I) and Ag(I) pyrazolates supported with tertiary phosphines: Synthesis, structures and photophysical properties
Catalysts, 2019, 9, 154, DOI: 10.3390/catal9020154
A. N. Kulakova, V.N. Khrustalev, Y.V. Zubavichus, L.S. Shul’pina, E. S. Shubina, M. M. Levitsky, N.S. Ikonnikov, A. N. Bilyachenko, Y.N. Kozlov, G. B. Shul’pin
Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides

2018

Inorg. Chim. Acta, 2018, 470, 22-35, DOI: 10.1016/j.ica.2017.07.015
A. A. Titov, O. A. Filippov, L. M. Epstein, N. V. Belkova, E. S. Shubina
Macrocyclic Copper(I) and Silver(I) Pyrazolates: Principles of Supramolecular Assemblies with Lewis Bases
Eur. J. Inorg. Chem., 2018, 20-21, 2285-2299, DOI: 10.1002/ejic.201701344
I. S. Sinopalnikova, T. A. Peganova, N. V. Belkova, E. Deydier, J-C. Daran, E. S. Shubina, A.. M. Kalsin, R. Poli
Ruthenium p-cymene iminophosphonamide complexes: activation under basic conditions and transfer hydrogenation catalysis
Inorg. Chem., 2018, 57 (1), 528–534, DOI: 10.1021/acs.inorgchem.7b02881
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, A. N. Kulakova, X. Bantreil, F. Lamaty, M. M. Levitsky, E. I. Gutsul, E. S. Shubina, G. B. Shul’pin
Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
Organometallics, 2018, 37 (2), 168–171, DOI: 10.1021/acs.organomet.7b00845
A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, E. S. Shubina, G. B. Shul’pin
Mild and Regioselective Hydroxylation of Methyl Group in Neocuproine: Approach to an N,O-Ligated Cu6 Cage Phenylsilsesquioxane
J. Organomet. Chem., 2018, 867, 133-141, DOI: 10.1016/j.jorganchem.2017.10.033
A. N. Bilyachenko, A. N. Kulakova, L. S. Shul'pina, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, U. S. Tsareva, E. S. Shubina, A. A. Petrov, N. V. Vorontsov, G. B. Shul’pin
Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
Inorg. Chem., 2018, 57, 1656−1664, DOI: 10.1021/acs.inorgchem.7b03027
N. V. Kireev, O. A. Filippov, A. A. Pavlov, L. M. Epstein, V. D. Makhaev, V. P. Dyadchenko, E. S. Shubina, N. V. Belkova
Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N₂)₂(dppe)₂
Chem. Eur. J., 2018, 24(7), 1464–1470, DOI: 10.1002/chem.201704203
N. V. Belkova, O. A. Filippov, E. S. Shubina
Z-H bond activation in (di)hydrogen bonding as a way to proton/hydride transfer and H2 evolution
Eur. J. Inorg. Chem., 2018, 22, 2505-2511, DOI: 10.1002/ejic.201701340
A. N. Bilyachenko, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, E. S. Shubina, A. V. Vologzhanina, G. B. Shul’pin
Heptanuclear Cage Cu(II)-Silsesquioxanes. Features of Synthesis, Structure and Catalytic Activity
Crystal Growth and Design, 2018, 18 (4), 2452–2457, DOI: 10.1021/acs.cgd.8b00082
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, A. V. Vologzhanina, G. Astakhov, E. I. Gutsul, E. S. Shubina, M. M. Levitsky
High-nuclearity (Cu8-based) cage silsesquioxanes: Synthesis and structural study
J. Organomet. Chem., 2018, 865, 247-256, DOI: 10.1016/j.jorganchem.2018.03.020
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
Hydride donating abilities of the tetracoordinated boron hydrides
Dalton Trans., 2018, 47(20), 6893-6897, DOI: 10.1039/C8DT00900G
A. N. Kulakova, A. N. Bilyachenko, A. Korlyukov, Jérôme Long, M. M. Levitsky, E. S. Shubina, Yannick Guari, J. Larionova
New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
Mendeleev Communications, 2018, 28(4), 387-389, DOI: 10.1016/j.mencom.2018.07.015
A. A. Titov, A F. Smol'yakov, K. F. Baranova, O. A. Filippov, E. S. Shubina
Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis-(trifluoromethyl)pyrazolates
Crystal Growth and Design, 2018, 18(9), 5377–5384, DOI: 10.1021/acs.cgd.8b00778
G. S. Astakhov, A. N. Bilyachenko, M. M. Levitsky, A.A. Korlyukov, Y.V. Zubavichus, P.V. Dorovatovskii, V.N. Khrustalev, A.V. Vologzhanina, E. S. Shubina
Tridecanuclear CuII11Na2 cagelike silsesquioxanes
Inorg. Chem., 2018, 57 (18), 11524–11529, DOI: 10.1021/acs.inorgchem.8b01496
G. S. Astakhov, A. N. Bilyachenko, A. Korlyukov, M. M. Levitsky, L. Shul'pina, X. Bantreil, F. Lamaty, A. Vologzhanina, E. S. Shubina, P. Dorovatovskii, D. Nesterov, A. Pombeiro, G. B. Shul’pin
High cluster (Cu9) cage silsesquioxanes. Synthesis, structure and catalytic activity
Chemistry - An Asian Journal, 2018, 13, 3084-3089, DOI: 10.1002/asia.201801156
E. D. Voronova, I. E. Golub, A. A. Pavlov, N. V. Belkova, O. A. Filippov, L. M. Epstein, E. S. Shubina
Comprehensive Insight into Hydrogen Bonding of Silanes
Dalton Trans., 2018, 47(36), 12570-12581, DOI: 10.1039/C8DT01130C
N. V. Forosenko, I. V. Basalov, A. V. Cherkasov, G. K. Fukin, E. S. Shubina, A. A. Trifonov
Amido Ca(II) complexes supported by Schiff base ligands for catalytic cross-dehydrogenative coupling of amines with silanes
Organometallics, 2018, 37 (18), 3142-3153, DOI: 10.1021/acs.organomet.8b00488
L. Luconi, E. S. Osipova, G. Giambastiani, M. Peruzzini, A. Rossin, N. V. Belkova, O. A. Filippov, E. M. Kozinets (Titova), A. A. Pavlov, E. S. Shubina
Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance
Dalton Trans., 2018, 47, 15666-15669, DOI: 10.1039/C8DT03209B
A. N. Kulakova, A. N. Bilyachenko, A. A. Korlyukov, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, N. S. Ikonnikov, G. B. Shul’pin
A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
Catalysts, 2018, 8(10), 484, DOI: 10.3390/catal8100484
A. N. Kulakova, A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, G. B. Shul’pin
Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity

2017

Journal of Molecular Catalysis A: Chemical, 2017, 426, 376-380, DOI: 10.1016/j.molcata.2016.08.014
E. M. Kozinets (Titova), Rahaman S. M. W, E. S. Shubina, R. Poli, N. V. Belkova, Manoury E.
Catalytic Redox Isomerization of Allylic Alcohols with Rhodium and Iridium Complexes with Ferrocene Phosphine-Thioether Ligands
Inorg. Chem., 2017, 56 (7), 4093-4103, DOI: 10.1021/acs.inorgchem.7b00061
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Petrov, Alexander A. Korlyukov, Lidia S. Shul’pina, Victor N. Khrustalev, Pavel V. Dorovatovskii, Anna V. Vologzhanina, Ulyana S. Tsareva, I. E. Golub, E. Gulyaeva, E. S. Shubina, G. B. Shul’pin
Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
Catalysts, 2017, 7(4), 101, DOI: 10.3390/catal7040101
A. I. Yalymov, A. N. Bilyachenko, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, L. S. Shul’pina, P. V. Dorovatovskii, M. A. Es’kova, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, E. S. Shubina, Y. N. Kozlov, G. B. Shul’pin
High Catalytic Activity of Heterometallic (Fe6Na7 and Fe6Na6) Cage Silsesquioxanes in Oxidations with Peroxides
ACS catalysis, 2017, 7, 2325-2333, DOI: 10.1021/acscatal.6b03207
E. M. Kozinets (Titova), E. S. Osipova, Pavlov Alexander A., O. A. Filippov, Safronov Sergey V., E. S. Shubina, N. V. Belkova
Mechanism of Dimethylamine–Borane Dehydrogenation Catalyzed by an Iridium(III) PCP-Pincer Complex
J. Organomet. Chem., 2017, 827, 86-95, DOI: 10.1016/j.jorganchem.2016.11.010
E. M. Kozinets (Titova), E. S. Osipova, E. Gulyaeva, V.N. Torocheshnikov, A.A. Pavlov, G. A. Silantyev, O. A. Filippov, E. S. Shubina, N. V. Belkova
Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
Inorg. Chem., 2017, 56, 4296−4307, DOI: 10.1021/acs.inorgchem.6b02673
Stefano Todisco, Lapo Luconi, Giuliano Giambastiani, Andrea Rossin, M. Peruzzini, I. E. Golub, O. A. Filippov, N. V. Belkova, E. S. Shubina
Ammonia Borane Dehydrogenation Catalyzed by (κ4‑EP3)Co(H) [EP3 = E(CH2CH2PPh2)3; E = N, P] and H2 Evolution from Their Interaction with NH Acids
ChemCatChem, 2017, 9 (23), 4437–4447, DOI: 10.1002/cctc.201701063
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, A. V. Vologzhanina, A. A. Titov, P. V. Dorovatovskii, L. S. Shul’pina, F. Lamaty, X. Bantreil, B. Villemejeanne, C. Ruiz, J. Martinez, E. S. Shubina, G. B. Shul’pin
Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
Dalton Trans., 2017, 46(38), 12935-12949, DOI: 10.1039/C7DT02017A
A. N. Bilyachenko, A. A. Korlyukov, A. V. Vologzhanina, V. N. Khrustalev, A. N. Kulakova, J. Long, J. Larionova, Y. Guari, M. S. Dronova, U. S. Tsareva, P. V. Dorovatovskii, E. S. Shubina, M. M. Levitsky
Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
Eur. J. Inorg. Chem., 2017, 4673–4682, DOI: 10.1002/ejic.201700624
I. E. Golub, O. A. Filippov, N. V. Belkova, E. I. Gutsul, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ³-P-CH₃C(CH₂CH₂PPh₂)₃}RuH(η²-BH₄)]
Inorg. Chem., 2017, 56, 12751-12763, DOI: 10.1021/acs.inorgchem.7b01436
A. N. Bilyachenko, A. I. Yalymov, M. S. Dronova, Alexander Korlyukov, Anna Vologzhanina, Marina Es’kova, Jérôme Long, J. Larionova, Yannick Guari, Pavel Dorovatovskii, E. S. Shubina, M. M. Levitsky
Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties
Chem. Eur. J., 2017, 23 (61), 15424-15435, DOI: 10.1002/chem.201702862
I. S. Sinoplanikova, T. y. A. Peganova, V. V. Novikov, I. V. Fedyanin, O. A. Filippov, N. V. Belkova, E. S. Shubina, R. Poli, A. M. Kalsin
Coordinatively labile 18-electron arene ruthenium iminophosphonamide complexes
Crystals, 2017, 7(10), 318-335, DOI: 10.3390/cryst7100318
N. V. Belkova, I. E. Golub, E. I. Gutsul, K. A. Lyssenko, A. S. Peregudov, V. D. Makhaev, O. A. Filippov, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
Crystal Growth and Design, 2017, 17 (12), 6770–6779, DOI: 10.1021/acs.cgd.7b01351
A. A. Titov, A. Smol’yakov, O. A. Filippov, I. Godovikov, D. Muratov, F. Dolgushin, L. M. Epstein, E. S. Shubina
Supramolecular design of the trinuclear silver(I) and copper(I) metal pyrazolates complexes with ruthenium sandwich compounds via intermolecular metal-π interactions
Inorg. Chem., 2017, 56 (24), 15026–15040, DOI: 10.1021/acs.inorgchem.7b02320
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, A. A. Korlyukov, Y. V. Zubavichus, P. V. Dorovatovskii, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, L. S. Shul’pina, E. S. Shubina, E. I. Gutsul, I. A. Mikhailov, N. S. Ikonnikov, U. S. Tsareva, G. B. Shul’pin
Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
Russ. Chem. Bull., 2017, 66 (9), 1563–1568, DOI: 10.1007/s11172-017-1925-2
A. A. Titov, A F. Smol´yakov, A. N. Rodionov, I. D. Kosenko, E. Guseva, Ya. V. Zubavichus, P. V. Dorovatovskii, O. A. Filippov, E. S. Shubina
Ferrocenecontaining tri and tetranuclear cyclic copper(I) and silver(I) pyrazolates

2016

Chemical Reviews, 2016, 116, 8545-8587, DOI: 10.1021/acs.chemrev.6b00091
N. V. Belkova, L. M. Epstein, O. A. Filippov, E. S. Shubina
Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides
Dalton Trans., 2016, 45, 7320 - 7327, DOI: 10.1039/C6DT00113K
A. N. Bilyachenko, A. I. Yalymov, A. Korlyukov, J. Long, J. Larionova, Y. Guari, A. V. Vologzhanina, M. Eskova, E. S. Shubina, M. M. Levitsky
Unusual penta- and hexanuclear Ni(II)-based silsesquioxane polynuclear complexes
Eur. J. Inorg. Chem., 2016, 1415–1424, DOI: 10.1002/ejic.201600034
E. S. Osipova, N. V. Belkova, L. M. Epstein, O. A. Filippov, V. A. Kirkina, E. M. Kozinets (Titova), A. Rossin, M. Peruzzini, E. S. Shubina
Dihydrogen Bonding and Proton Transfer from MH vs OH acids to Group 10 Metal Hydrides (tBuPCP)MH [tBuPCP = 3-2,6-(tBu2PCH2)2C6H3; M = Ni, Pd]
RSC Adv., 2016, 6, 48165 - 48180, DOI: 10.1039/C6RA07081G
A. N. Bilyachenko, M. M. Levitsky, A. I. Yalymov, A. Korlyukov, A. Vologzhanina, Yu. Kozlov, L. Shul'pina, D. Nesterov, A. Pombeiro, F. Lamaty, X. Bantreil, A. Fetre, D. Liu, J. Martinez, J. Long, J. Larionova, Y. Guari, A. Trigub, Y. Zubavichus, I. E. Golub, O. A. Filippov, E. S. Shubina, G. B. Shul’pin
A Heterometallic (Fe6Na8) Cage-like Silsesquioxane: Synthesis, Structure, Spin Glass Behavior and High Catalytic Activity
Dalton Trans., 2016, 45, 9127 - 9135, DOI: 10.1039/c6dt01104g
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]
Molecules, 2016, 21, 665, DOI: 10.3390/molecules21050665
A. N. Bilyachenko, A. I. Yalymov, Shul’pina L.S., Mandelli, D., Korlyukov, A.A., Vologzhanina A.V., Es’kova M.A., E. S. Shubina, M. M. Levitsky, G. B. Shul’pin
Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
Dalton Trans., 2016, 45, 13663 - 13666, DOI: 10.1039/C6DT02026G
A. N. Bilyachenko, A. I. Yalymov, M. M. Levitsky, A. Korlyukov, M. Eskova, J. Long, J. Larionova, Y. Guari, L.S. Shul'pina, N.S. Ikonnikov, A. Trigub, Y.V. Zubavichus, I. E. Golub, E. S. Shubina, G. B. Shul’pin
First Cage-Like Pentanuclear Co(II)-Silsesquioxane
J. Phys. Chem. A, 2016, DOI: 10.1021/acs.jpca.6b06579
A. A. Titov, E. Guseva, O. A. Filippov, G. M. Babakhina, I. A. Godovikov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The Role of Weak Interactions in Strong Intermolecular M•••Cl Complexes of Coinage Metal Pyrazolates: Spectroscopic and DFT Study
Angew. Chem. Int. Ed., 2016, 55, 15360-15363, DOI: 10.1002/anie.201607189
A. N. Bilyachenko, M. M. Levitsky, A. I. Yalymov, A.A. Korlyukov, V.N. Khrustalev, A.V. Vologzhanina, L.S. Shul’pina, N.S. Ikonnikov, A.E. Trigub, P.V. Dorovatovsky, X. Bantreil, F. Lamaty, J. Long, J. Larionova, I. E. Golub, E. S. Shubina, G. B. Shul’pin
Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity

2015

Chem. Eur. J., 2015, 21, 13176-13180, DOI: 10.1002/chem.201502085
O. A. Filippov, A. A. Titov, E. Guseva, D. A. Loginov, A. F. Smol'yakov, F. M. Dolgushin, N. V. Belkova, L. M. Epstein, E. S. Shubina
Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene
J. Phys. Chem. A, 2015, 119, 3853-3868, DOI: 10.1021/acs.jpca.5b01921
I. E. Golub, E. Gulyaeva, O. A. Filippov, V. P. Dyadchenko, N. V. Belkova, L. M. Epstein, D. E. Arkhipov, E. S. Shubina
Dihydrogen Bond Intermediated Alcoholysis of Dimethylamine-Borane in Non-Aqueous Media
Chem. A Eur. J., 2015, 21, 8758-8770, DOI: 10.1002/chem.201500791
A. N. Bilyachenko, M. S. Dronova, A. I. Yalymov, F. Lamaty, X. Bantreil, J. Martinez, C. Bizet, L. S. Shul'pina, A. A. Korlyukov, D. E. Arkhipov, M. M. Levitsky, E. S. Shubina, A. M. Kirillov, G. B. Shul’pin
Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
Chem. Eur. J., 2015, 21, 18563–18565, DOI: 10.1002/chem.201503635
A. N. Bilyachenko, A. I. Yalymov, A. A. Korlyukov, J. Long, J. Larionova, Y. Guari, Y. V. Zubavichus, A. L. Trigub, E. S. Shubina, I. L. Eremenko, N. N. Efimov, M. M. Levitsky
Heterometallic Na6Co3 Phenylsilsesquioxane Exhibiting Slow Dynamic Behavior in its Magnetization

2014

Advances in Organometallic Chemistry, 2014, First Edition. Ed.: A. J. L. Pombeiro. John Willey & Sons, Inc. chapt. 8, 97-109. (book chapter)
E. S. Shubina, N. V. Belkova, O. A. Filippov, L. M. Epstein
The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book. Weak Interactions and M-H Bond Activation
Inorg. Chem., 2014, 53, 1080–1090, DOI: 10.1021/ic4026206
N. V. Belkova, E. V. Bakhmutova-Albert, E. I. Gutsul, V. I. Bakhmutov, I. E. Golub, O. A. Filippov, L. M. Epstein, M. Peruzzini, A. Rossin, F. Zanobini, E. S. Shubina
Dihydrogen bonding in complex (PP3)RuH(η1-BH4) featuring two proton-accepting hydride sites: experimental and theoretical studies
RSC Adv., 2014, 4, 8350 – 8359, DOI: 10.1039/C3RA47040G
A. A. Titov, O. A. Filippov, E. Guseva, A. F. Smol’yakov, F. M. Dolgushin, L. M. Epstein, V. K. Belsky, E. S. Shubina
Role of basic sites of substituted ferrocenes in interaction with the trinuclear 3,5-bis(trifluoromethyl)pyrazolates: thermodynamics and structure of complexes
Dalton Trans., 2014, 43, 872 – 882, DOI: 10.1039/C3DT52508B
M. S. Dronova, A. N. Bilyachenko, A. I. Yalymov, Kozlov Y.N., Shul’pina L.S., Korlyukov A.A., Arkhipov D.E., M. M. Levitsky, E. S. Shubina, G. B. Shul’pin
Solvent-controlled synthesis of tetranuclear cage-like copper(II) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation of benzene and alcohols with peroxides
Organometallics, 2014, 33, 5964-5973, DOI: 10.1021/om500308g
G. A. Silantyev, O. A. Filippov, S. Musa, D. Gelman, N. V. Belkova, K. Weisz, L. M. Epstein, E. S. Shubina
Conformational Flexibility of Dibenzobarrelene-Based PC(sp3)P Pincer Iridium Hydride Complexes: The Role of Hemilabile Functional Groups and External Coordinating Solvents

2013

J. Organomet. Chem., 2013, 747, 30-42, DOI: 10.1016/j.jorganchem.2013.04.025
O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
Chemistry of boron hydrides orchestrated by dihydrogen bonds
Z. Phys. Chem., 2013, 227, 69–88
O. A. Filippov, V. A. Kirkina, N. V. Belkova, S. Stoccoro, A. Zucca, G. M. Babakhina, L. M. Epstein, E. S. Shubina
First Example of Hydrogen Bonding to Platinum Hydride
Chem. Eur. J., 2013, 19, 16906–16909, DOI: 10.1002/chem.201303311
S. Musa, O. A. Filippov, N. V. Belkova, E. S. Shubina, G. A. Silantyev, L. Ackermann, D. Gelman
Ligand–Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation
Inorg. Chem., 2013, 52, 1787−1797, DOI: 10.1021/ic301585k
G. A. Silantyev, O. A. Filippov, P.M. Tolstoy, N. V. Belkova, L. M. Epstein, K. Weisz, E. S. Shubina
Hydrogen bonding and proton transfer to ruthenium hydride complex CpRuH(dppe): metal and hydride dichotomy.
Dalton Trans., 2013, 42, 11720-11730, DOI: 10.1039/C3DT51429C
E. M. Kozinets (Titova), M. Fekete, O. A. Filippov, N. V. Belkova, E. S. Shubina, R. Poli, S. Duckett, E. Manoury
Activation of a (cyclooctadiene) rhodium(I) complex supported by a chiral ferrocenyl phosphine thioether ligand for hydrogenation catalysis: a combined parahydrogen NMR and DFT study
Russ. Chem. Bull., 2013, 62, 751-757
E. M. Kozinets (Titova), G. A. Silantyev, N. V. Belkova, E. S. Shubina, R. Poli, E. Manoury
Iridium and rhodium complexes with the planar chiral thioether ligands in asymmetric hydrogenation of ketones and imines
Eur. J. Inorg. Chem., 2013, 5240-5246, DOI: 10.1002/ejic.201300878
A. N. Bilyachenko, M. S. Dronova, A. I. Yalymov, A.A. Korlyukov, L.S. Shul’pina, D.E. Arkhipov, E. S. Shubina, M. M. Levitsky, A.D. Kirilin, G. B. Shul’pin
New Binuclear Cage-like Copper(II) Silsesquioxane (“Cooling Tower”); Its High Catalytic Activity in Oxidation of Benzene and Alcohols
Russ. Chem. Bull., 2013, 62, 1941-1943
M. S. Dronova, A. N. Bilyachenko, A.A. Korlyukov, D.E. Arkhipov, A.D. Kirilin, E. S. Shubina, G. M. Babakhina, M. M. Levitsky
A new type of supramolecular organization in the cage-like metallasiloxanes
Russ. Chem. Bull., 2013, 62, 1829-1834
A. A. Titov, E. Guseva, A. F. Smol’yakov, F. M. Dolgushin, O. A. Filippov, I. E. Golub, ^krylova#, G. M. Babakhina, L. M. Epstein, E. S. Shubina
Complexation of trimeric copper(I) and silver(I) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane

2012

Spectrosc. Prop. Inorg. Organomet. Compd., 2012, 43, 1–28 (book chapter)
N. V. Belkova, L. M. Epstein, O. A. Filippov, E. S. Shubina
IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies
ChemPhysChem, 2012, 13, 2677
O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Lledos, E. S. Shubina
Directionality of Dihydrogen Bonds: The Role of Transition Metal Atoms
Comput Theor Chem, 2012, 998, 129-140
O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Lledos, E. S. Shubina
Hydrogen–deuterium exchange in hydride chemistry: Dihydrogen bonded complexes as key intermediates
Inorg. Chem., 2012, 51, 6486-6497
I. E. Golub, O. A. Filippov, E. I. Gutsul, N. V. Belkova, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond
Eur. J. Inorg. Chem., 2012, 5554–5561
A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A.F. Smol’yakov, F.M. Dolgushin, V.K. Belsky, I.A. Godovikov, L. M. Epstein, E. S. Shubina
Complexes of Trinuclear Macrocyclic Copper(I) and Silver(I) 3,5- Bis(Trifluoromethyl)Pyrazolates with Ketones
Russ. Chem. Bull., 2012, 61, 200-203
M. M. Levitsky, A. N. Bilyachenko, M. S. Dronova, A.I. Dmitriev, R.B. Morgunov, E. S. Shubina, A.D. Kirilin
Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments
Dalton Trans., 2012, 41, 11849-11859
E. M. Kozinets (Titova), O. Koniev, O. A. Filippov, J.-C. Daran, R. Poli, E. S. Shubina, N. V. Belkova, E. Manoury
Coordination chemistry of diphenylphosphinoferrocenylthioethers on cyclooctadiene and norbornadiene rhodium(I) platforms

2011

J. Organomet. Chem., 2011, 696, 1174-1183
P. A. Dub, J.-C. Daran, V. A. Kirkina, N. V. Belkova, E. S. Shubina, R. Poli
Modeling the platinum-catalyzed intermolecular hydroamination of ethylene: the nucleophilic addition of HNEt2 to coordinated ethylene in trans-PtBr2(C2H4)(HNEt2)
Angew. Chem. Int. Ed., 2011, 50, 1367–1370
V. A. Kirkina, A. Rossin, N. V. Belkova, M. R. Chierotti, L. M. Epstein, O. A. Filippov, R. Gobetto, L. Gonsalvi, A. Lledos, E. S. Shubina, F. Zanobini, M. Peruzzini
Acid-base interaction between transition metal hydrides results in dihydrogen bonding and assists H2 evolution
Inorg. Chem., 2011, 50, 3325-3331
V. N.Tsupreva, A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A. F.Smol'yakov, F. M. Dolgushin, D. V. Agapkin, I. A. Godovikov, L. M. Epstein, E. S. Shubina
Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds
Inorg. Chem., 2011, 50, 444-450
O.N. Kazheva, G.G. Alexandrov, A.V. Kravchenko, I.D. Kosenko, I.A. Lobanova, I.B. Sivaev, O. A. Filippov, E. S. Shubina, V.I. Bregadze, V.A. Starodub, L.V. Titov, L.I. Buravov, O.A. Dyachenko
Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion
Inorg. Chem., 2011, 50, 12539-52
A. Béthegnies, V. A. Kirkina, O. A. Filippov, J.-C. Daran, N. V. Belkova, E. S. Shubina, R. Poli
Coordination and Organometallic Chemistry of Relevance to the Rhodium-Based Catalyst for Ethylene Hydroamination