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Lina M. Epstein
Personal Info
Phone
+7(499)135-64-48
Email
Academic Degree
Ph.D. in Chemistry, Moscow State University (1967)
D.Sc., INEOS RAS (1985)
Professor of Chemistry (1991)
D.Sc., INEOS RAS (1985)
Professor of Chemistry (1991)
Experience
1945–1950 M.V.Lomonosov Moscow State University, Department of Philosophy
1953–1957 Moscow State Pedagogical Institute, Department of Physics
1958–1986 – young research scientist, INEOS RAS
1986–1990 – senior research scientist, INEOS RAS
1991–present time – leading research scientist, INEOS RAS
1953–1957 Moscow State Pedagogical Institute, Department of Physics
1958–1986 – young research scientist, INEOS RAS
1986–1990 – senior research scientist, INEOS RAS
1991–present time – leading research scientist, INEOS RAS
Scientific Interests
Theoretical Chemistry and Molecular Spectroscopy. Examination of the fundamental problems such as electronic structure, nature of the bonds and proton donor or proton acceptor ability of transition metal complexes. Molecular Spectroscopy studies of intermolecular interactions, especially neutral and ionic hydrogen bonding as well their participation in proton transfer processes.
Awards
Discovery of the novel intermolecular Hydrogen bonding with d-electrons of transition metal atom as well as hydride ligand of the transition metal and main groups hydrides. The elucidation of their nature, structure and the determination of the H-bond and following low temperature proton transfer leading to classical and non classical cationic hydrides in different solvents .Determination of the ion pairs stabilized by H-bond, formed after proton transfer.
Additional
Over 250 papers in Russian and International journals, two Chapters in the books: "Hydrogen bonds and chemical properties of organic compounds" in "Hydrogen bond", Editor: N.D. Sokolov, Moscow, 1981 and reference 3, as well as modern reviews (references 4-7)
9 candidate dissertations have been defended
Publications
2023
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Reactivity of heterobimetallic ion pairs in formic acid dehydrogenation
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Activation of dinitrogen by group 6 metal complexes
2021
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The mechanism of halogenation of decahydro-closo-decaborate dianion by hydrogen chloride
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The reaction of hydrogen halides with tetrahydroborate anion and hexahydro-closo-hexaborate dianion
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Iinfluence of phosphine (pincer) ligands on the transition metal hydrides reactivity
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Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
2020
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Dichotomous Si–H Bond Activation by Alkoxide and Alcohol in Base-Catalyzed Dehydrocoupling of Silanes
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Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes
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Stereoisomerism as an Origin of Different Reactivity of Ir(III) PC(sp3)P Pincer Catalysts
2019
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Luminescent AgI Complexes with 2,2′-Bipyridine Derivatives Featuring [Ag-(CF3)2Pyrazolate]4 Units
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Synthesis, Structural Properties and Reactivity of Ruthenocene-based Pincer Pd(II) Tetrahydroborate
2018
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Macrocyclic Copper(I) and Silver(I) Pyrazolates: Principles of Supramolecular Assemblies with Lewis Bases
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Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2
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Hydride donating abilities of the tetracoordinated boron hydrides
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Comprehensive Insight into Hydrogen Bonding of Silanes
2017
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Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ3-P-CH3C(CH2CH2PPh2)3}RuH(η2-BH4)]
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Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
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Supramolecular design of the trinuclear silver(I) and copper(I) metal pyrazolates complexes with ruthenium sandwich compounds via intermolecular metal-π interactions
2016
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Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides
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Dihydrogen Bonding and Proton Transfer from MH vs OH acids to Group 10 Metal Hydrides (tBuPCP)MH [tBuPCP = 3-2,6-(tBu2PCH2)2C6H3; M = Ni, Pd]
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Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]
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The Role of Weak Interactions in Strong Intermolecular M•••Cl Complexes of Coinage Metal Pyrazolates: Spectroscopic and DFT Study
2015
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Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene
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Dihydrogen Bond Intermediated Alcoholysis of Dimethylamine-Borane in Non-Aqueous Media
2014
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Advances in Organometallic Chemistry, 2014, First Edition. Ed.: A. J. L. Pombeiro. John Willey & Sons, Inc. chapt. 8, 97-109. (book chapter)The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book. Weak Interactions and M-H Bond Activation
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Dihydrogen bonding in complex (PP3)RuH(η1-BH4) featuring two proton-accepting hydride sites: experimental and theoretical studies
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Role of basic sites of substituted ferrocenes in interaction with the trinuclear 3,5-bis(trifluoromethyl)pyrazolates: thermodynamics and structure of complexes
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Conformational Flexibility of Dibenzobarrelene-Based PC(sp3)P Pincer Iridium Hydride Complexes: The Role of Hemilabile Functional Groups and External Coordinating Solvents
2013
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Chemistry of boron hydrides orchestrated by dihydrogen bonds
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Z. Phys. Chem., 2013, 227, 69–88First Example of Hydrogen Bonding to Platinum Hydride
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Hydrogen bonding and proton transfer to ruthenium hydride complex CpRuH(dppe): metal and hydride dichotomy.
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Russ. Chem. Bull., 2013, 62, 1829-1834Complexation of trimeric copper(I) and silver(I) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane
2012
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Spectrosc. Prop. Inorg. Organomet. Compd., 2012, 43, 1–28 (book chapter)IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies
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ChemPhysChem, 2012, 13, 2677Directionality of Dihydrogen Bonds: The Role of Transition Metal Atoms
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Comput Theor Chem, 2012, 998, 129-140Hydrogen–deuterium exchange in hydride chemistry: Dihydrogen bonded complexes as key intermediates
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Inorg. Chem., 2012, 51, 6486-6497Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond
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Eur. J. Inorg. Chem., 2012, 5554–5561Complexes of Trinuclear Macrocyclic Copper(I) and Silver(I) 3,5- Bis(Trifluoromethyl)Pyrazolates with Ketones
2011
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Angew. Chem. Int. Ed., 2011, 50, 1367–1370Acid-base interaction between transition metal hydrides results in dihydrogen bonding and assists H2 evolution
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Inorg. Chem., 2011, 50, 3325-3331Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds