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Alexey N. Bilyachenko
Personal Info
Phone
+7-499-135-93-69
Email
Academic Degree
D.Sc. (Chem.), RUDN University, 2020.
Ph. D. (Chem.), A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 2006.
M. Sc., summa cum laude, Moscow State University of Fine Chemical Technologies, 2002.
Ph. D. (Chem.), A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 2006.
M. Sc., summa cum laude, Moscow State University of Fine Chemical Technologies, 2002.
Experience
2021 - present - Leading Researcher, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; In parallel - Associate professor, Department of Inorganic Chemistry, Faculty of science, RUDN University; Leading Researcher, Research Institute of Chemistry, RUDN University.
2017 – 2020 – Deputy Director, Research Institute of Chemistry, RUDN University.
2010 - 2017 - Senior Researcher, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
2002 - 2010 - Researcher, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
2002 - 2006 - Post-graduate student, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
2017 – 2020 – Deputy Director, Research Institute of Chemistry, RUDN University.
2010 - 2017 - Senior Researcher, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
2002 - 2010 - Researcher, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
2002 - 2006 - Post-graduate student, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
Scientific Interests
Cagelike metallacomplexes and coordination polymers; sesquioxane ligands; complexation reactions; catalysis; molecular magnetism; photophysical properties.
Awards
Laureate of the RUDN University Prize in Science and Innovation, 2019 (with Prof. V.N. Khrustalev).
1st prize at Scientific Conference-Competition at the Semenov Institute of Chemical Physics, Russian Academy of Sciences, 2016 (with L.S. Shul’pina, Dr. Y.N. Kozlov and Prof. G.B. Shul’pin).
Scholarships of the President of the Russian Federation for young scientists-candidates in science, 2007-2008, 2011-2012.
Scholarship of Ballard Foundation (http://www.polechimie-balard.fr), 2014, Visiting Professor at Institut Charles Gerhardt, University of Montpellier 2, France
Scholarship of Ballard Foundation (http://www.polechimie-balard.fr), 2014, Visiting Professor at Institut Charles Gerhardt, University of Montpellier 2, France
Additional
Visiting professor and foreign laboratories: 2009 - Poland, Lodz, The Centre of Molecular and Macromolecular Studies of the Polish Academy of Sciences (supported by K.I. Zamaraev foundation http://zam.catalysis.ru/),
2013 - France, Montpellier, Institut des Biomolécules Max Mousseron (IBMM), University of Montpellier 2 (supported by CNRS and French Embassy in Moscow),
2014 - France, Montpellier, Institut Charles Gerhardt, University of Montpellier 2 (supported by Ballard Foundation http://www.polechimie-balard.fr/),
2015 - France, Toulouse, Laboratory of Coordination Chemistry CNRS (supported by French Embassy in Moscow, Programme André Mazon http://www.ambafrance-ru.org/Lancement-du-programme-Andre-Mazon)
> 70 papers in Russian and international scientific journals (H index = 24);
Two books (both with Dr. M.M. Levitsky and Prof. V.N. Khrustalev):
“Metallasiloxanes. Modern concepts and methods”, 2018, ISBN 978-5-209-08779-3, RUDN University;
“Metal oxide clusters in organoelement matrices”, 2020, ISBN 978-5-209-09905-5, RUDN University,
Chapter: Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes (Alexey N Bilyachenko, Nuno Reis Conceição, M Fátima C Guedes da Silva, Kamran T Mahmudov, Georgiy B Shul'pin, Armando J L Pombeiro) in Series on Chemistry, Energy and the Environment (Synthesis and Applications in Chemistry and Materials) https://doi.org/10.1142/13309
15+ oral presentations at International chemical meetings
Project head of scientific (RSF, RUDN, RFBR and RFBR-CNRS) projects.
2013 - France, Montpellier, Institut des Biomolécules Max Mousseron (IBMM), University of Montpellier 2 (supported by CNRS and French Embassy in Moscow),
2014 - France, Montpellier, Institut Charles Gerhardt, University of Montpellier 2 (supported by Ballard Foundation http://www.polechimie-balard.fr/),
2015 - France, Toulouse, Laboratory of Coordination Chemistry CNRS (supported by French Embassy in Moscow, Programme André Mazon http://www.ambafrance-ru.org/Lancement-du-programme-Andre-Mazon)
> 70 papers in Russian and international scientific journals (H index = 24);
Two books (both with Dr. M.M. Levitsky and Prof. V.N. Khrustalev):
“Metallasiloxanes. Modern concepts and methods”, 2018, ISBN 978-5-209-08779-3, RUDN University;
“Metal oxide clusters in organoelement matrices”, 2020, ISBN 978-5-209-09905-5, RUDN University,
Chapter: Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes (Alexey N Bilyachenko, Nuno Reis Conceição, M Fátima C Guedes da Silva, Kamran T Mahmudov, Georgiy B Shul'pin, Armando J L Pombeiro) in Series on Chemistry, Energy and the Environment (Synthesis and Applications in Chemistry and Materials) https://doi.org/10.1142/13309
15+ oral presentations at International chemical meetings
Project head of scientific (RSF, RUDN, RFBR and RFBR-CNRS) projects.
Publications
2024
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An ionic Cu9Na4-phenylsilsesquioxane/bis(triphenylphosphine)iminium complex: synthesis, unique structure, and catalytic activity
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Rational (supra)molecular design and catalytic activity of cagelike Cu4-based phenylsilsesquioxanes
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Vanadium-Silsesquioxane Nanocages as Heterogeneous Catalysts for Synthesis of Quinazolinones
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A family of hexacopper phenylsilsesquioxane/acetate complexes: synthesis, solvent‐controlled cage structures, and catalytic activity
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Luminescent Ln3+-based silsesquioxanes with a β-diketonate antenna ligand: toward the design of efficient temperature sensors
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Synthesis and Applications in Chemistry and Materials, 2024, 11, 245-279, DOI: 10.1142/9789811283208_0008Chapter 8 in book: Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes
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Fe(III)-Based Phenylsilsesquioxane/Acetylacetonate Complexes: Synthesis, Cage-like Structure, and High Catalytic Activity
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Combination of phenylsilsesquioxane and acetate ligands as an approach to a record high nuclear Cu13Na2-cage. Synthesis, unique structure, and catalytic activity
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Cu12-Methylsilsesquioxane Cage Decorated with Cu(dppe)2 Moieties for Mild Oxidative Functionalization of Alkanes
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An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity
2023
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Tetranuclear lanthanide-based silsesquioxanes: towards a combination of a slow relaxation of the magnetization and a luminescent thermometry
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Cage-like Cu5Cs4-phenylsilsesquioxanes: synthesis, supramolecular structures, and catalytic activity
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A Family of сagelike Mn-silsesquioxane/bathophenanthroline complexes: synthesis, structure, and catalytic and antifungal activity
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Cagelike manganesesilsesquioxane complexes: synthesis via an acetone approach, structure, and catalytic activity for toluene oxidation
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Cagelike Rb2‑, K2‑, and Na2‑Tetracopper(II) Silsesquioxanes with Quaternary Ammonium Cations: Synthesis, Structures, and Catalytic Activity
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New family of luminescent tetranuclear lanthanide-based germsesquioxanes: luminescence and temperature sensing
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Cagelike octacopper methylsilsesquioxanes: self-assembly in the focus of alkaline metal ion influence—synthesis, structure, and catalytic activity
2022
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Hybrid Silsesquioxane/Benzoate Cu7-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity
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Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
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A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity
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Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
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Tridecanuclear Gd(III)-silsesquioxane: Synthesis, structure, and magnetic property
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Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures
2021
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Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
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Novel carbonate/pyridine tetranuclear nickel complex, exhibiting slow relaxation of the magnetization
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New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages
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Cu6- and Cu8-Cage Sil- and Germsesquioxanes: Synthetic and Structural Features, Oxidative Rearrangements, and Catalytic Activity
2020
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New Luminescent Tetranuclear Lanthanide‐based Silsesquioxane Cage‐like Architectures
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Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
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Coordination Affinity of Cu(II)-Based Silsesquioxanes toward N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic Products Exhibiting a High Catalytic Activity in Oxidation Reactions
2019
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Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
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The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
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New Cu4Na4- and Cu5-Based Phenylsilsesquioxanes. Synthesis via Complexation with 1,10-Phenanthroline, Structures and High Catalytic Activity in Alkane Oxidations with Peroxides in Acetonitrile
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Magnetic cage-like metallasilsesquioxanes
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Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes
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Cagelike metallagermanates and metallagermoxanes: Synthesis, structures and functional properties
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Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactions
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Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
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Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides
2018
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Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
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Mild and Regioselective Hydroxylation of Methyl Group in Neocuproine: Approach to an N,O-Ligated Cu6 Cage Phenylsilsesquioxane
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Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
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Heptanuclear Cage Cu(II)-Silsesquioxanes. Features of Synthesis, Structure and Catalytic Activity
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High-nuclearity (Cu8-based) cage silsesquioxanes: Synthesis and structural study
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New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
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Tridecanuclear CuII11Na2 cagelike silsesquioxanes
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High cluster (Cu9) cage silsesquioxanes. Synthesis, structure and catalytic activity
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A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
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Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity
2017
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Journal of Molecular Catalysis A: Chemical, 2017, 426, Part B, 297-304, DOI: 10.1016/j.molcata.2016.06.016Cage-like metallsilsesquioxanes in catalysis: A review
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Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
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High Catalytic Activity of Heterometallic (Fe6Na7 and Fe6Na6) Cage Silsesquioxanes in Oxidations with Peroxides
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Oxidation of C‒H compounds with peroxides catalyzed by polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks
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Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
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Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
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Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties
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Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
2016
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Modern concepts and methods in the chemistry of polyhedral metallasiloxanes
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Unusual penta- and hexanuclear Ni(II)-based silsesquioxane polynuclear complexes
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A Heterometallic (Fe6Na8) Cage-like Silsesquioxane: Synthesis, Structure, Spin Glass Behavior and High Catalytic Activity
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Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
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First Cage-Like Pentanuclear Co(II)-Silsesquioxane
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Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity
2015
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Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
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Alkane oxidation with peroxides catalyzed by cage-like copper(II) silsesquioxanes
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Heterometallic Na6Co3 Phenylsilsesquioxane Exhibiting Slow Dynamic Behavior in its Magnetization
2014
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Solvent-controlled synthesis of tetranuclear cage-like copper(II) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation of benzene and alcohols with peroxides
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Quantum chemical study of the template synthesis of cage-like metallasiloxanes
2013
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New Binuclear Cage-like Copper(II) Silsesquioxane (“Cooling Tower”); Its High Catalytic Activity in Oxidation of Benzene and Alcohols
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Russ. Chem. Bull., 2013, 62, 1941-1943A new type of supramolecular organization in the cage-like metallasiloxanes
2012
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Eur. J. Inorg. Chem., 2012, 5554–5561Complexes of Trinuclear Macrocyclic Copper(I) and Silver(I) 3,5- Bis(Trifluoromethyl)Pyrazolates with Ketones
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Russ. Chem. Bull., 2012, 61, 200-203Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments
2011
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Inorg. Chem., 2011, 50, 3325-3331Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds