MH-Lab | Alena N. Kulakova

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Alena N. Kulakova

Alena N. Kulakova

Personal Info

Address

28 Vavilov Str., Moscow 119334, Russia

Phone

+7-499-135-93-69

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Academic Degree

PhD (Chem.) | ICGM, University of Montpellier, France (2020); Prof J. Larionova
PhD (Chem.) | Department of Inorganic Chemistry, Faculty of science, RUDN University, Russia (2020); Prof V.N. Khrustalev
Master Degree | Mendeleev University of Chemical Technology of Russia, Moscow (2016)
M.Sc., Mendeleev University of Chemical Technology of Russia, 2016

Experience

02/2016-present: young scientific researcher in laboratory of metal Hydrides» in A.N.Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russia. Supervisor - E.S. Shubina and A.N. Bilyachenko
08/2020 – 12/2020: assistant – Inorganic chemistry department RUDN University, Moscow, Russia
06/2017 – 08/2017 – trainee – IBMM, University of Montpellier, France
10/2012 - 12/2015: lab assistant in laboratory for studies of homolytic reactions, Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia. Supervisor – Prof Dr. A.O. Terent'ev
December 2015 – present: Research Fellow in the laboratory of Prof. Elena S. Shubina under supervision of Dr. A.N. Bilyachenko

Scientific Interests

Cagelike metallacomplexes and coordination polymers; sesquioxane ligands; lanthanide complexes, complexation reactions; catalysis; molecular magnetism; photophysical properties.

Awards

Scholarship VERNADSKI | French Embassy in Russia (10th May 2017)
Scholarship of the President of the Russian Federation | Awarding organization (30th April 2019)
The winner of PhD students competition | RUDN University (08th October 2017, 30th September, 2018, 10th October2019)

Publications

2023

Organometallics, 2023, DOI: 10.1021/acs.organomet.3c00009
Félix G., A. N. Kulakova, Sene S., Charlot C., A. N. Bilyachenko, Korlyukov A.A., Volodin A.D., E. S. Shubina, Elizbarian I. G. , Guari Y., J. Larionova
New family of luminescent tetranuclear lanthanide-based germsesquioxanes: luminescence and temperature sensing

2022

Crystal Growth and Design, 2022, 22(4), 2146-2157, DOI: 10.1021/acs.cgd.1c01225
A. N. Bilyachenko, G. S. Astakhov, A. N. Kulakova, Korlyukov Alexander A., Zubavichus Yan V., Dorovatovskii Pavel V., Shul’pina Lidia S., E. S. Shubina, Ikonnikov Nikolay S., Kirillova Marina V., Zueva Anna Y., A. Kirillov, G. B. Shul’pin
Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures

2021

RSC Adv., 2021, 11(25), 34735 - 34741, DOI: 10.1039/D1RA06755A
Nigoghossian K., A. N. Kulakova, Félix G., Khrustalev V.N., E. S. Shubina, Long J., Guari Y., Sene S., Carlos L.D., A. N. Bilyachenko, J. Larionova
Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
J. Organomet. Chem., 2021, 942, 121815, DOI: 10.1016/j.jorganchem.2021.121815
A. N. Kulakova, A. N. Bilyachenko, Korlyukov A.A., M. M. Levitsky, Long J., Guari Y., J. Larionova
Novel carbonate/pyridine tetranuclear nickel complex, exhibiting slow relaxation of the magnetization
Eur. J. Inorg. Chem., 2021, 2021(27), 2696-2701, DOI: 10.1002/ejic.202100308
A. N. Kulakova, Nigoghossian Karina, Félix Gautier, Khrustalev Victor N., E. S. Shubina, Long Jérôme, Guari Yannick, Carlos Luis D., A. N. Bilyachenko, J. Larionova
New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages

2020

Chem. A Eur. J., 2020, 26(70), 16594-16598, DOI: 10.1002/chem.202003351
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, Khrustalev V., E. S. Shubina, Felix G., Mamontova E., Long J., Guari Y., J. Larionova
New Luminescent Tetranuclear Lanthanide‐based Silsesquioxane Cage‐like Architectures

2019

J. Organomet. Chem., 2019, 899, DOI: 10.1016/j.jorganchem.2019.120911
A. N. Kulakova, E.E.Sedykh, M. M. Levitsky, P.V.Dorovatovskii, V.N.Khrustalev, L.S.Shul'pina, E. S. Shubina, Y.N.Kozlov, N.S.Ikonnikova, A. N. Bilyachenko, G. B. Shul’pin
The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
J. Organomet. Chem., 2019, 884, 17-28, DOI: 10.1016/j.jorganchem.2019.01.004
A. N. Kulakova, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Xavier Bantreil, Lidia S. Shul'pina, M. M. Levitsky, Nikolay S. Ikonnikov, E. S. Shubina, F. Lamaty, A. N. Bilyachenko, G. B. Shul’pin
Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
Catalysts, 2019, 9, 154, DOI: 10.3390/catal9020154
A. N. Kulakova, V.N. Khrustalev, Y.V. Zubavichus, L.S. Shul’pina, E. S. Shubina, M. M. Levitsky, N.S. Ikonnikov, A. N. Bilyachenko, Y.N. Kozlov, G. B. Shul’pin
Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides

2018

Inorg. Chem., 2018, 57 (1), 528–534, DOI: 10.1021/acs.inorgchem.7b02881
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, A. N. Kulakova, X. Bantreil, F. Lamaty, M. M. Levitsky, E. I. Gutsul, E. S. Shubina, G. B. Shul’pin
Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
J. Organomet. Chem., 2018, 867, 133-141, DOI: 10.1016/j.jorganchem.2017.10.033
A. N. Bilyachenko, A. N. Kulakova, L. S. Shul'pina, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, U. S. Tsareva, E. S. Shubina, A. A. Petrov, N. V. Vorontsov, G. B. Shul’pin
Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
Dalton Trans., 2018, 47(20), 6893-6897, DOI: 10.1039/C8DT00900G
A. N. Kulakova, A. N. Bilyachenko, A. Korlyukov, Jérôme Long, M. M. Levitsky, E. S. Shubina, Yannick Guari, J. Larionova
New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
Dalton Trans., 2018, 47, 15666-15669, DOI: 10.1039/C8DT03209B
A. N. Kulakova, A. N. Bilyachenko, A. A. Korlyukov, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, N. S. Ikonnikov, G. B. Shul’pin
A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
Catalysts, 2018, 8(10), 484, DOI: 10.3390/catal8100484
A. N. Kulakova, A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, G. B. Shul’pin
Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity

2017

Journal of Molecular Catalysis A: Chemical, 2017, 426, Part B, 297-304, DOI: 10.1016/j.molcata.2016.06.016
M. M. Levitsky, A. I. Yalymov, A. N. Kulakova, A. A. Petrov, A. N. Bilyachenko
Cage-like metallsilsesquioxanes in catalysis: A review
Inorg. Chem., 2017, 56 (7), 4093-4103, DOI: 10.1021/acs.inorgchem.7b00061
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Petrov, Alexander A. Korlyukov, Lidia S. Shul’pina, Victor N. Khrustalev, Pavel V. Dorovatovskii, Anna V. Vologzhanina, Ulyana S. Tsareva, I. E. Golub, E. Gulyaeva, E. S. Shubina, G. B. Shul’pin
Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
ChemCatChem, 2017, 9 (23), 4437–4447, DOI: 10.1002/cctc.201701063
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, A. V. Vologzhanina, A. A. Titov, P. V. Dorovatovskii, L. S. Shul’pina, F. Lamaty, X. Bantreil, B. Villemejeanne, C. Ruiz, J. Martinez, E. S. Shubina, G. B. Shul’pin
Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
Dalton Trans., 2017, 46(38), 12935-12949, DOI: 10.1039/C7DT02017A
A. N. Bilyachenko, A. A. Korlyukov, A. V. Vologzhanina, V. N. Khrustalev, A. N. Kulakova, J. Long, J. Larionova, Y. Guari, M. S. Dronova, U. S. Tsareva, P. V. Dorovatovskii, E. S. Shubina, M. M. Levitsky
Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
Inorg. Chem., 2017, 56 (24), 15026–15040, DOI: 10.1021/acs.inorgchem.7b02320
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, A. A. Korlyukov, Y. V. Zubavichus, P. V. Dorovatovskii, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, L. S. Shul’pina, E. S. Shubina, E. I. Gutsul, I. A. Mikhailov, N. S. Ikonnikov, U. S. Tsareva, G. B. Shul’pin
Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations

2015

Tetrahedron, 2015, 71, C. 8985 - 8990
Terent'ev A. O., Zdvizhkov A. T., Fleury F., Pototskiy R. A., A. N. Kulakova, Levitsky D. O., Nikishin G. I.
Organocatalytic peroxidation of malonates, b-ketoesters, and cyanoacetic esters using n-Bu4NI/t-BuOOH-mediated intermolecular oxidative C(sp3)-O coupling

2014

2014, 4, C. 7579 – 7587
Terent'ev A. O., Zdvizhkov A. T., A. N. Kulakova, Novikov R. A., Arzumanyan A. V. and Nikishin G. I.
Reactions of mono- and bicyclic enol ethers with the I2–hydroperoxide system