Dr. Sci., Leading Scientific Researcher,
Department of Kinetics and Catalysis,
Semenov Institute of Chemical Physics,
Russian Academy of Sciences, Moscow
Coordination Affinity of Cu(II)-Based Silsesquioxanes toward
N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic
Products Exhibiting a High Catalytic Activity in Oxidation Reactions
The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
New Cu4Na4- and Cu5-Based Phenylsilsesquioxanes. Synthesis via Complexation with 1,10-Phenanthroline, Structures and High Catalytic Activity in Alkane Oxidations with Peroxides in Acetonitrile
Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via
Oxidation of 1,1-bis(Diphenylphosphino)methane),
Structure and Catalytic Activity in Alkane or Alcohol
Oxidation with Peroxides
Solvent-controlled synthesis of tetranuclear cage-like copper(II) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation of benzene and alcohols with peroxides