MH-Lab | Dmitry A. Valyaev

Dmitry A. Valyaev

Dmitry A. Valyaev, Chargé de Recherche CNRS
Laboratoire de Chimie de Coordination du CNRS
205 route de Narbonne, 31077 Toulouse Cedex 4,
France

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Publications

2023

Eur. J. Inorg. Chem., 2023, e202300143, DOI: 10.1002/ejic.202300143
Matthieu Cavailles, O. A. Filippov, Vincent César, Noël Lugan, D. Valyaev
Half-Sandwich Manganese Complex Bearing Fused Oxazoline-NHC Ligand: Conformational Analysis and Evaluation in Asymmetric Ketone Hydrosilylation
Molecules, 2023, 28(8), 3368, DOI: 10.3390/molecules28083368
E. S. Osipova, S. Kovalenko, E. Gulyaeva, N. V. Kireev, Alexander A. Pavlov, O. A. Filippov, Anastasia A. Danshina, D. Valyaev, Yves Canac, E. S. Shubina, N. V. Belkova
The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes

2022

Chemical Communications, 2022, 58(32), 5017-5020, DOI: 10.1039/D2CC00999D
E. S. Osipova, E. Gulyaeva, N. V. Kireev, Kovalenko Sergey A., Bijani Crisitan, Canac Yves, D. Valyaev, O. A. Filippov, N. V. Belkova, E. S. Shubina
Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(Ph2PCH2PPh2)Mn(CO)3H]
Coord. Chem. Rev., 2022, 458, 214421, DOI: 10.1016/j.ccr.2022.214421
E. Gulyaeva, E. S. Osipova, Buhaibeh Ruqaya, Canac Yves, Sortais Jean-Baptiste, D. Valyaev
Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes

2021

Inorg. Chem., 2021, 60 (6) , 4015–4025, DOI: 10.1021/acs.inorgchem.1c00073
Grineva Alina A., O. A. Filippov, Canac Yves, Sortais Jean-Baptiste, Nefedov Sergei E., Lugan Noël, César Vincent, D. Valyaev
Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes

2020

Chemical Communications, 2020, 56, 2139-2142, DOI: 10.1039/C9CC07713H
N. V. Kireev, O. A. Filippov, E. Gulyaeva, E. S. Shubina, Laure Vendier, Yves CANAC, Jean-Baptiste Sortais, Noël Lugan, D. Valyaev
Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation

2019

Organometallics, 2019, 38(11), 2330-2337, DOI: 10.1021/acs.organomet.9b00151
A.A. Grineva, O. A. Filippov, S.E. Nefedov, Noël Lugan, Vincent César, D. Valyaev
Direct Access to IMesF and IMesF2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes
Angew. Chem. Int. Ed., 2019, 58 (20), 6727-6731, DOI: 10.1002/anie.201901169
R. Buhaibeh, O. A. Filippov, J. Willot, C. Duhayon, D. Valyaev, N. Lugan, Y. Canac, J.-B. Sortais
Phosphine‐NHC Manganese Hydrogenation Catalyst Exhibiting a Non‐Classical Metal‐Ligand Cooperative H2 Activation Mode

2018

Angew. Chem. Int. Ed., 2018, 57(27), 7986-7991, DOI: 10.1002/anie.201801530
N. Lugan, D. Valyaev, A.A. Grineva, V. César, O. A. Filippov, V.N. Khrustalev, S.N. Nefedov
Oxidative Coupling of Anionic Abnormal N‐Heterocyclic Carbenes: an Efficient Access to Janus‐Type 4,4'‐Bis(2H‐Imidazol‐2‐Ylidenes)

2015

Angew. Chem. Int. Ed., 2015, 54(21), 6315-6319, DOI: 10.1002/anie.201501256
D. Valyaev, O. A. Filippov, N. Lugan, G. Lavigne, N. A. Ustynyuk
Umpolung of Methylenephosphonium Ions in Their Manganese Half-Sandwich Complexes and Application to the Synthesis of Chiral Phosphorus-Containing Ligand Scaffolds