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Dmitry A. Valyaev

Dmitry A. Valyaev
Dmitry A. Valyaev, Chargé de Recherche CNRS
Laboratoire de Chimie de Coordination du CNRS
205 route de Narbonne, 31077 Toulouse Cedex 4,
France
Publications
2024
  • Chem. Eur. J., 2024, e202304201, DOI: 10.1002/chem.202304201
    E. Gulyaeva, Ruqaya Buhaibeh, Mohamed Boundor, Karim Azouzi, Jérémy Willot, Stéphanie Bastin, Carine Duhayon, Noël Lugan, O. A. Filippov, Jean-Baptiste Sortais, D. Valyaev, and Yves Canac
    Impact of the Methylene Bridge Substitution in Chelating NHC- Phosphine Mn(I) Catalyst for Ketone Hydrogenation
  • Chemical science, 2024, 15, 1409-1417, DOI: 10.1039/D3SC05356C
    Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation
2023
  • Inorg. Chem., 2023, 62(49), 20129-20141, DOI: 10.1021/acs.inorgchem.3c03025
    Ameskal Mohammad, Taakili Rachid, E. Gulyaeva, Duhayon Carine, Willot Jérémy, Lugan Noël, Lepetit Christine, D. Valyaev, Canac Yves
    Phosphine-NHC-phosphonium ylide pincer ligand: complexation with Pd(II) and unconventional P-coordination of the ylide moiety
  • Eur. J. Inorg. Chem., 2023, e202300143, DOI: 10.1002/ejic.202300143
    Matthieu Cavailles, O. A. Filippov, Vincent César, Noël Lugan, D. Valyaev
    Half-Sandwich Manganese Complex Bearing Fused Oxazoline-NHC Ligand: Conformational Analysis and Evaluation in Asymmetric Ketone Hydrosilylation
  • Molecules, 2023, 28(8), 3368, DOI: 10.3390/molecules28083368
    E. S. Osipova, S. Kovalenko, E. Gulyaeva, N. V. Kireev, Alexander A. Pavlov, O. A. Filippov, Anastasia A. Danshina, D. Valyaev, Yves Canac, E. S. Shubina, N. V. Belkova
    The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes
2022
2021
  • Inorg. Chem., 2021, 60 (6) , 4015–4025, DOI: 10.1021/acs.inorgchem.1c00073
    Grineva Alina A., O. A. Filippov, Canac Yves, Sortais Jean-Baptiste, Nefedov Sergei E., Lugan Noël, César Vincent, D. Valyaev
    Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes
2020
2019
  • Organometallics, 2019, 38(11), 2330-2337, DOI: 10.1021/acs.organomet.9b00151
    A.A. Grineva, O. A. Filippov, S.E. Nefedov, Noël Lugan, Vincent César, D. Valyaev
    Direct Access to IMesF and IMesF2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes
  • Angew. Chem. Int. Ed., 2019, 58 (20), 6727-6731, DOI: 10.1002/anie.201901169
    R. Buhaibeh, O. A. Filippov, J. Willot, C. Duhayon, D. Valyaev, N. Lugan, Y. Canac, J.-B. Sortais
    Phosphine‐NHC Manganese Hydrogenation Catalyst Exhibiting a Non‐Classical Metal‐Ligand Cooperative H2 Activation Mode
2018
  • Angew. Chem. Int. Ed., 2018, 57(27), 7986-7991, DOI: 10.1002/anie.201801530
    N. Lugan, D. Valyaev, A.A. Grineva, V. César, O. A. Filippov, V.N. Khrustalev, S.N. Nefedov
    Oxidative Coupling of Anionic Abnormal N‐Heterocyclic Carbenes: an Efficient Access to Janus‐Type 4,4'‐Bis(2H‐Imidazol‐2‐Ylidenes)
2015
  • Angew. Chem. Int. Ed., 2015, 54(21), 6315-6319, DOI: 10.1002/anie.201501256
    D. Valyaev, O. A. Filippov, N. Lugan, G. Lavigne, N. A. Ustynyuk
    Umpolung of Methylenephosphonium Ions in Their Manganese Half-Sandwich Complexes and Application to the Synthesis of Chiral Phosphorus-Containing Ligand Scaffolds