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2024

Russian Journal of Coordination Chemistry, 2024, 50(5), 343-348
Nekrasov R.I., Peganova T.A., Kal’sin A.M., N. V. Belkova
Half-Sandwich Iminophosphonamide Rhodium Complexes as Highly Efficient Catalysts for Dehydrogenation of Dimethylamine-Borane
Inorg. Chem., 2024, DOI: 10.1021/acs.inorgchem.4c00751
K. F. Baranova, A. A. Titov, Shakirova Julia R., Baigildin Vadim A., Smol’yakov Alexander F., D. Valyaev, Ning Guo-Hong, O. A. Filippov, S. P. Tunik, E. S. Shubina
Substituents’ Effect on the Photophysics of Trinuclear Copper(I) and Silver(I) Pyrazolate–Phosphine Cages
Nat. Commun., 2024, 15, 5758, DOI: 10.1038/s41467-024-50164-9
Alexander G. Medvedev, Pavel A. Egorov, Alexey A. Mikhaylov, Evgeny S. Belyaev, Gayane A. Kirakosyan, Yulia G. Gorbunova, O. A. Filippov, N. V. Belkova, E. S. Shubina, Maria N. Brekhovskikh, Anna A. Kirsanova, Maria V. Babak, Ovadia Lev, Petr V. Prikhodchenko
Synergism of primary and secondary interactions in a crystalline hydrogen peroxide complex with tin
Inorg. Chem., 2024, DOI: 10.1021/acs.inorgchem.4c01748
Shen Qi, Sheng Kai, Gao Zhi-Yong, A. N. Bilyachenko, Huang Xian-Qiang, Azam Mohammad, Tung Chen-Ho, Sun Di.
Vanadium-Silsesquioxane Nanocages as Heterogeneous Catalysts for Synthesis of Quinazolinones
Dalton Trans., 2024, 53(11), 4976-4983, DOI: 10.1039/d3dt04388f
Rumyantsev Andrey V., Bushkov Nikolai S., Ryzhikova Margarita A., Zhizhin Anton A., Takazova Rina, Talanova Valeria, E. I. Gutsul, Novikov Roman A., Zhizhko Pavel A., Zarubin Dmitry N.
Readily available Ti-based in situ catalytic system for oxo/imido heterometathesis
ChemPlusChem, 2024, e202400029, DOI: 10.1002/cplu.202400029
Bushkov Nikolai S., Rumyantsev Andrey V., Zhizhin Anton A., Strelkova Tatyana V., Novikov Roman A., E. I. Gutsul, Takazova Rina U., Kitaeva Dinara Kh, Ustynyuk Nikolai A., Zhizhko Pavel A., Zarubin Dmitry N.
Tungsten Oxide Dispersed on Silica as Robust and Readily Available Oxo/Imido Heterometathesis Catalyst
Chem. Eur. J., 2024, e202401164, DOI: 10.1002/chem.202401164
A. Yu. Zueva, A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., Dorovatovskii Pavel V., Shul’pina Lidia S., Ikonnikov Nikolay S., E. I. Gutsul, Rahimov Karim G., E. S. Shubina, Conceição Nuno Reis, Mahmudov Kamran T., Guedes da Silva M.Fátima C, Pombeiro Armando J.L.
A family of hexacopper phenylsilsesquioxane/acetate complexes: synthesis, solvent‐controlled cage structures, and catalytic activity
Front. Chem., 2024, 12:1379587, DOI: 10.3389/fchem.2024.1379587
Gautier Félix, A. N. Kulakova, Saad Sene, Victor N. Khrustalev, Miguel A. Hernández-Rodríguez, E. S. Shubina, Tristan Pelluau, Luís D. Carlos, Yannick Guari, Albano N. Carneiro Neto, A. N. Bilyachenko, J. Larionova
Luminescent Ln3+-based silsesquioxanes with a β-diketonate antenna ligand: toward the design of efficient temperature sensors
Synthesis and Applications in Chemistry and Materials, 2024, 11, 245-279, DOI: 10.1142/9789811283208_0008
A. N. Bilyachenko, Nuno Reis Conceição, M Fátima C Guedes da Silva, Kamran T. Mahmudov, G. B. Shul’pin, and Armando J. L. Pombeiro
Chapter 8 in book: Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes
Mendeleev Communications, 2024, 34, 192–194, DOI: 10.1016/j.mencom.2024.02.010
Sedlova D.V., E. S. Osipova, E. I. Gutsul, Ivan A. Godovikov, O. A. Filippov, E. S. Shubina, N. V. Belkova
Stepwise carbon dioxide hydrosylilation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(But PCP)]
Chem. Eur. J., 2024, e202304201, DOI: 10.1002/chem.202304201
E. Gulyaeva, Ruqaya Buhaibeh, Mohamed Boundor, Karim Azouzi, Jérémy Willot, Stéphanie Bastin, Carine Duhayon, Noël Lugan, O. A. Filippov, Jean-Baptiste Sortais, D. Valyaev, and Yves Canac
Impact of the Methylene Bridge Substitution in Chelating NHC- Phosphine Mn(I) Catalyst for Ketone Hydrogenation
Journal of Electroanalytical Chemistry, 2024, DOI: 10.1016/j.jelechem.2024.118084
Alexey A. Kagilev, Zufar N. Gafurov, Il'yas F. Sakhapov, Vladimir I. Morozov, Artyom O. Kantyukov, Ruslan B. Zaripov, Ekaterina M. Zueva, Ilya K. Mikhailov, Alexey B. Dobrynin, V. Kulikova, V. A. Kirkina, E. I. Gutsul, E. S. Shubina, N. V. Belkova, Oleg G. Sinyashin, Dmitry G. Yakhvarov
Electrochemical generation and in situ EPR- and UV–vis- observation of aminyl-radical diarylamido/bis(phosphine) pincer complexes of Ni, Pd and Pt
Inorg. Chem., 2024, 63(4), 1909–1918, DOI: 10.1021/acs.inorgchem.3c03587
A. N. Bilyachenko, Khrustalev Victor N., Dorovatovskii Pavel V., Shul’pina Lidia S., Ikonnikov Nikolay S., E. S. Shubina, Lobanov Nikolai N., Aliyeva Vusala A., Nunes Ana V.M., Mahmudov Kamran T., Kozlov Yuriy N., Pombeiro Armando J.L.
Fe(III)-Based Phenylsilsesquioxane/Acetylacetonate Complexes: Synthesis, Cage-like Structure, and High Catalytic Activity
Chemical science, 2024, 15, 1409-1417, DOI: 10.1039/D3SC05356C
E. Gulyaeva, E. S. Osipova, S. Kovalenko, O. A. Filippov, N. V. Belkova, Vendier Laure, Canac Yves, E. S. Shubina, D. Valyaev
Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation
Chemical Communications, 2024, 60, 847-850, DOI: 10.1039/D3CC05659G
A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu., Godovikov Ivan A., O. A. Filippov, E. S. Shubina
Pyrazolate vs phenylethynide: direct exchange of anionic bridging ligand in cyclic trinuclear silver complex

2023

Inorg. Chem., 2023, 62(49), 20129-20141, DOI: 10.1021/acs.inorgchem.3c03025
Ameskal Mohammad, Taakili Rachid, E. Gulyaeva, Duhayon Carine, Willot Jérémy, Lugan Noël, Lepetit Christine, D. Valyaev, Canac Yves
Phosphine-NHC-phosphonium ylide pincer ligand: complexation with Pd(II) and unconventional P-coordination of the ylide moiety
RSC Adv., 2023, 13(37), 26302-26312, DOI: 10.1039/D3RA04901A
Félix Gautier, Sene Saad, A. N. Kulakova, A. N. Bilyachenko, Khrustalev Victor N., E. S. Shubina, Guari Yannick, J. Larionova
Tetranuclear lanthanide-based silsesquioxanes: towards a combination of a slow relaxation of the magnetization and a luminescent thermometry
Inorg. Chem., 2023, 62(33), 13573-13586, DOI: 10.1021/acs.inorgchem.3c01989
A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., Shul’pina Lidia S., Korlyukov Alexander A., Ikonnikov Nikolay S., E. S. Shubina, Kozlov Yuriy N., Conceição Nuno Reis, Guedes da Silva M.Fátima C, Mahmudov Kamran T., Pombeiro Armando J.L.
Cage-like Cu5Cs4-phenylsilsesquioxanes: synthesis, supramolecular structures, and catalytic activity
Inorg. Chem., 2023, 62(38), 15537-15549, DOI: 10.1021/acs.inorgchem.3c02040
A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., Chusova Olga, Dorovatovskii Pavel V., Aliyeva Vusala A., Paninho Ana B., Nunes Ana V.M., Mahmudov Kamran T., E. S. Shubina, Pombeiro Armando J.L
A Family of сagelike Mn-silsesquioxane/bathophenanthroline complexes: synthesis, structure, and catalytic and antifungal activity
Crystal Growth and Design, 2023, 23(12), 8707–8717, DOI: 10.1021/acs.cgd.3c00863
A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., Dorovatovskii Pavel V., E. S. Shubina, Guari Yannick, Félix Gautier, J. Larionova, Mahmoud Abdallah G., Pombeiro Armando J.L
Cagelike manganesesilsesquioxane complexes: synthesis via an acetone approach, structure, and catalytic activity for toluene oxidation
Inorganics, 2023, 11(5), 212, DOI: 10.3390/inorganics11050212
V. A. Kirkina, V. Kulikova, E. I. Gutsul, Gafurov Zufar N., Sakhapov Ilias F., Yakhvarov Dmitry G., Nelyubina Yulia V., O. A. Filippov, E. S. Shubina, N. V. Belkova
Role of Non-Covalent Interactions in the Reactions between Palladium Hydrido Complex with Amidoarylphosphine Pincer Ligand and Brønsted Acids
Organometallics, 2023, 42(18), 2651–2660, DOI: 10.1021/acs.organomet.3c00125
E. S. Osipova, Sedlova D.V., E. I. Gutsul, Nelyubina Yulia V., Dorovatovsii Pavel V., L. M. Epstein, O. A. Filippov, E. S. Shubina, N. V. Belkova
Reactivity of heterobimetallic ion pairs in formic acid dehydrogenation
Pharmaceutics, 2023, 15(4), 1088, DOI: 10.3390/pharmaceutics15041088
Diana V. Aleksanyan, Aleksandr V. Konovalov, Svetlana G. Churusova, Ekaterina Yu. Rybalkina, Alexander S. Peregudov, Svetlana A. Aksenova, E. I. Gutsul, Zinaida S. Klemenkova, Vladimir A. Kozlov
Modulation of the Cytotoxic Properties of Pd(II) Complexes Based on Functionalized Carboxamides Featuring Labile Phosphoryl Coordination Sites
Eur. J. Inorg. Chem., 2023, e202300143, DOI: 10.1002/ejic.202300143
Matthieu Cavailles, O. A. Filippov, Vincent César, Noël Lugan, D. Valyaev
Half-Sandwich Manganese Complex Bearing Fused Oxazoline-NHC Ligand: Conformational Analysis and Evaluation in Asymmetric Ketone Hydrosilylation
Molecules, 2023, 28(8), 3368, DOI: 10.3390/molecules28083368
E. S. Osipova, S. Kovalenko, E. Gulyaeva, N. V. Kireev, Alexander A. Pavlov, O. A. Filippov, Anastasia A. Danshina, D. Valyaev, Yves Canac, E. S. Shubina, N. V. Belkova
The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes
Inorganics, 2023, 11(4), 175, DOI: 10.3390/inorganics11040175
Arina Olbrykh, A. A. Titov, Alexander Smol’yakov, O. A. Filippov, E. S. Shubina
Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex
Organometallics, 2023, 42(18), 2577–2589, DOI: 10.1021/acs.organomet.2c00649
A. N. Bilyachenko, Victor N. Khrustalev, G. S. Astakhov, A. Yu. Zueva, Arteev I. S., Yan V. Zubavichus, Alexander A. Korlyukov, Pavel V. Dorovatovskii, Lidia S. Shul’pina, Nikolay S. Ikonnikov, Marina V. Kirillova, E. S. Shubina, * Yuriy N. Kozlov, A. Kirillov, G. B. Shul’pin
Cagelike Rb2‑, K2‑, and Na2‑Tetracopper(II) Silsesquioxanes with Quaternary Ammonium Cations: Synthesis, Structures, and Catalytic Activity
Organometallics, 2023, 42(18), 2613–2622, DOI: 10.1021/acs.organomet.3c00009
Félix G., A. N. Kulakova, Sene S., Charlot C., A. N. Bilyachenko, Korlyukov A.A., Volodin A.D., E. S. Shubina, Elizbarian I. G. , Guari Y., J. Larionova
New family of luminescent tetranuclear lanthanide-based germsesquioxanes: luminescence and temperature sensing
Molecules, 2023, 28(3), 1189, DOI: 10.3390/molecules28031189
Yakovlev G. B., A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu, O. A. Filippov, E. S. Shubina
Tetranuclear Copper(I) and Silver(I) Pyrazolate Adducts with 1,1$\prime$-Dimethyl-2,2’-bibenzimidazole: Influence of Structure on Photophysics
Molecules, 2023, 28(3), 1211, DOI: 10.3390/molecules28031211
A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., A. Yu. Zueva, Shul’pina Lidia S., E. S. Shubina, Ikonnikov Nikolay S., G. B. Shul’pin
Cagelike octacopper methylsilsesquioxanes: self-assembly in the focus of alkaline metal ion influence—synthesis, structure, and catalytic activity
Russ. Chem. Bull., 2023, 72(1), 83-102, DOI: 10.1007/s11172-023-3716-2
N. V. Kireev, O. A. Filippov, L. M. Epstein, E. S. Shubina, N. V. Belkova
Activation of dinitrogen by group 6 metal complexes
Russian Journal of Inorganic Chemistry, 2023, 68(9), 1200-1208, DOI: 10.1134/S0036023623601320
V. Kulikova, V. A. Kirkina, E. I. Gutsul, Gafurov Z. N., Kagliev A. A., Sakhapov I. F., Yakhvarov D. G., O. A. Filippov, N. V. Belkova, E. S. Shubina
Basicity and hydride-donating ability of palladium(II) hydride complex with diarylamido-bis-phosphine pincer ligand
Russian Chemical Reviews, 2023, 92(11), RCR5099, DOI: 10.59761/rcr5099
E. M. Kozinets (Titova), A. A. Titov, E. S. Shubina
Functional pyrazolylpyridine ligands in the design of metal complexes with tunable properties

2022

Molecules, 2022, 27(23), 8575, DOI: 10.3390/molecules27238575
Laskova J., Serdyukov A., Kosenko I., Ananyev I., E. M. Kozinets (Titova), Druzina A., Sivaev I., Antonets A.A., Nazarov A. A., Bregadze V. I.
New Azido Coumarins as Potential Agents for Fluorescent Labeling and Their “Click” Chemistry Reactions for the Conjugation with closo-Dodecaborate Anion
Molecules, 2022, 27(23), 8505, DOI: 10.3390/molecules27238505
A. N. Bilyachenko, Khrustalev V. N., E. I. Gutsul, A. Yu. Zueva, Korlyukov A. A., Shul'pina L. S., Ikonnikov N. S., Dorovatovskii P. V., D. Gelman, E. S. Shubina, G. B. Shul’pin
Hybrid Silsesquioxane/Benzoate Cu7-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity
J. Org. Chem, 2022, 87(18), 12182-12195, DOI: 10.1021/acs.joc.2c01339
Afanasyev Oleg, Kliuev Fedor, Tsygankov Alexey, Nelyubina Yulia, E. I. Gutsul, Novikov Valentin, Chusov Denis
Fluoride Additive as a Simple Tool to Qualitatively Improve Performance of Nickel-Catalyzed Asymmetric Michael Addition of Malonates to Nitroolefins
Inorg. Chem. Front., 2022, 9(21), 5624-5634, DOI: 10.1039/d2qi01648f
S. K. Emashova, A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu, Godovikov Ivan A., Godovikova Maria I., Dorovatovskii Pavel V., Korlyukov Alexander A., O. A. Filippov, E. S. Shubina
Emissive Silver(I) Cyclic Trinuclear Complexes with Aromatic Amine Donor Pyrazolate Derivatives: Way to Efficiency
Inorg. Chem., 2022, 61(40), 16081-16092, DOI: 10.1021/acs.inorgchem.2c02478
Nekrasov Roman I., Peganova Tat’yana A., Fedyanin Ivan V., E. I. Gutsul, O. A. Filippov, N. V. Belkova, Kalsin Alexander M.
Versatile Reactivity of Half-Sandwich Rhodium(III) Iminophosphonamide Complexes
Russian Journal of Coordination Chemistry, 2022, 48(10), 615-621, DOI: 10.1134/S1070328422100086
A. A. Titov, Smol'yakov A.F., O. A. Filippov, N. V. Belkova, E. S. Shubina
Halogen or Arene: Complexation of 4,4'-Dibromobiphenyl with a Three-Membered Silver(I) Macrocycle
Inorg. Chem. Front., 2022, 9(17), 4525-4537, DOI: 10.1039/d2qi01054b
G. S. Astakhov, Khrustalev Victor N., M. S. Dronova, E. I. Gutsul, Korlyukov Alexander, D. Gelman, Zubavichus Yan V., Novichkov Daniil, Trigub Alexander, E. S. Shubina, A. N. Bilyachenko
Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
Molecules, 2022, 27(19), 6205, DOI: 10.3390/molecules27196205
A. N. Bilyachenko, Khrustalev V.N., A. Yu. Zueva, E. M. Kozinets (Titova), G. S. Astakhov, Zubavichus Y.V., Dorovatovskii P.V., Korlyukov A.S., Shul'pina L.S., E. S. Shubina, Kozlov Y.N., Ikonnikov N.S., D. Gelman, G. B. Shul’pin
A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity
Inorg. Chem., 2022, 61(37), 14800-14814, DOI: 10.1021/acs.inorgchem.2c02217
A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., G. S. Astakhov, A. Yu. Zueva, Zubavichus Yan V., Kirillova Marina V., Shul’pina Lidia S., Ikonnikov Nikolay S., Dorovatovskii Pavel V., E. S. Shubina, A. Kirillov, G. B. Shul’pin
Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
J. Inorg. Biochem., 2022, 235, 111908, DOI: 10.1016/j.jinorgbio.2022.111908
Churusova Svetlana G., Aleksanyan Diana V., Rybalkina Ekaterina Yu., E. I. Gutsul, Peregudov Alexander S., Klemenkova Zinaida S., Nelyubina Yulia V., Buyanovskaya Anastasiya G., Kozlov Vladimir A.
Pincer–dipeptide and pseudodipeptide conjugates: synthesis and bioactivity studies
Dalton Trans., 2022, 51(11), 4354-4365, DOI: 10.1039/D1DT03967A
Ganguli K., N. V. Belkova, Kundu S.
Cyclometalated (NNC)Ru(ii) complex catalyzed β-methylation of alcohols using methanol
Inorg. Chim. Acta, 2022, 539, 121004, DOI: 10.1016/j.ica.2022.121004
A. A. Titov, Smol'yakov Alexander F., Godovikov Ivan A., Chernyadyev Andrey Yu, Molotkov Alexander P., Loginov Dmitry A., O. A. Filippov, N. V. Belkova, E. S. Shubina
The role of weak intermolecular interactions in photophysical behavior of isocoumarins on the example of their interaction with cyclic trinuclear silver(I) pyrazolate
Chemical Communications, 2022, 58(32), 5017-5020, DOI: 10.1039/D2CC00999D
E. S. Osipova, E. Gulyaeva, N. V. Kireev, S. Kovalenko, Bijani Crisitan, Canac Yves, D. Valyaev, O. A. Filippov, N. V. Belkova, E. S. Shubina
Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(Ph2PCH2PPh2)Mn(CO)3H]
ChemPhysMater, 2022, 1(4), 247-251, DOI: 10.1016/j.chphma.2022.04.008
Sheng Kai, Wang Ran, A. N. Bilyachenko, Khrustalev Victor, Jagodič Marko, Jagličić Zvonko, Li Zhaoyang, Wang Likai, Tung Chenho, Sun Di
Tridecanuclear Gd(III)-silsesquioxane: Synthesis, structure, and magnetic property
Crystal Growth and Design, 2022, 22(4), 2146-2157, DOI: 10.1021/acs.cgd.1c01225
A. N. Bilyachenko, G. S. Astakhov, A. N. Kulakova, Korlyukov Alexander A., Zubavichus Yan V., Dorovatovskii Pavel V., Shul’pina Lidia S., E. S. Shubina, Ikonnikov Nikolay S., Kirillova Marina V., A. Yu. Zueva, A. Kirillov, G. B. Shul’pin
Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures
Coord. Chem. Rev., 2022, 458, 214421, DOI: 10.1016/j.ccr.2022.214421
E. Gulyaeva, E. S. Osipova, Buhaibeh Ruqaya, Canac Yves, Sortais Jean-Baptiste, D. Valyaev
Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
Chemical Communications, 2022, 58(6), 859-862, DOI: 10.1039/D1CC06401K
V. A. Kirkina, Kissel Alexander A., Selikhov Alexander N., Nelyubina Yulia V., O. A. Filippov, N. V. Belkova, Trifonov Alexander A., E. S. Shubina
Amine-boranes reactions promoted by lanthanide(ii) ions

2021

Molecular Diversity, 2021, 25(4), 2441-2446, DOI: 10.1007/s11030-020-10146-7
G. S. Astakhov, Shigaev R.R., Borisova T.N., Ershova A.A., Alexander A. Titov, Varlamov A.V., Voskressensky L.G., Matveeva M.D.
Facile synthesis of pyrrolo[2,1-a]isoquinolines by domino reaction of 1-aroyl-3,4-dihydroisoquinolines with conjugated ketones, nitroalkenes and nitriles
Eur. J. Inorg. Chem., 2021, 2021(41), 4265 - 4272, DOI: 10.1002/ejic.202100489
N. V. Kireev, Kiryutin A.S., Pavlov A.A., Yurkovskaya A.V., Musina E.I., Karasik A.A., E. S. Shubina, Ivanov K.L., N. V. Belkova
Nickel(II) dihydrogen and hydride complexes as the intermediates of H2 heterolytic splitting by nickel diazadiphosphacyclooctane complexes
Inorg. Chem., 2021, 60(13), 9880-9898, DOI: 10.1021/acs.inorgchem.1c01138
Churusova S.G., Aleksanyan D.V., Rybalkina E.Y., Susova O.Y., Peregudov A.S., Brunova V.V., E. I. Gutsul, Klemenkova Z.S., Nelyubina Y.V., Glushko V.N., Kozlov V.A.
Palladium(II) pincer complexes of functionalized amides with S-modified cysteine and homocysteine residues: cytotoxic activity and different aspects of their biological effect on living cells
RSC Adv., 2021, 11(25), 34735 - 34741, DOI: 10.1039/D1RA06755A
Nigoghossian K., A. N. Kulakova, Félix G., Khrustalev V.N., E. S. Shubina, Long J., Guari Y., Sene S., Carlos L.D., A. N. Bilyachenko, J. Larionova
Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
J. Organomet. Chem., 2021, 942, 121815, DOI: 10.1016/j.jorganchem.2021.121815
A. N. Kulakova, A. N. Bilyachenko, Korlyukov A.A., M. M. Levitsky, Long J., Guari Y., J. Larionova
Novel carbonate/pyridine tetranuclear nickel complex, exhibiting slow relaxation of the magnetization
J. Organomet. Chem., 2021, 942, 121813, DOI: 10.1016/j.jorganchem.2021.121813
A. A. Titov, Smol’yakov A.F., O. A. Filippov
Heterobimetallic silver(I) and copper(I) pyrazolates supported with 1,1'-bis(diphenylphosphino)ferrocene
Organic and Biomolecular Chemistry, 2021, 19(43), 9421 - 9426, DOI: 10.1039/D1OB01711J
Petropavlovskikh D.A., Vorobyeva D.V., Godovikov I.A., Nefedov S.E., O. A. Filippov, Osipov S.N.
Lossen rearrangement by Rh(III)-catalyzed C-H activation/annulation of aryl hydroxamates with alkynes: access to quinolone-containing amino acid derivatives
Molecules, 2021, 26(22), 6869, DOI: 10.3390/molecules26226869
K. F. Baranova, A. A. Titov, Smol’yakov A.F., Chernyadyev A.Y., O. A. Filippov, E. S. Shubina
Mononuclear copper(I) 3-(2-pyridyl)pyrazole complexes: the crucial role of phosphine on photoluminescence
Russian Journal of Inorganic Chemistry, 2021, 66(11), 1639 - 1648, DOI: 10.1134/s0036023621110073
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The mechanism of halogenation of decahydro-closo-decaborate dianion by hydrogen chloride
Molecules, 2021, 26(12), 3754, DOI: 10.3390/molecules26123754
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The reaction of hydrogen halides with tetrahydroborate anion and hexahydro-closo-hexaborate dianion
Eur. J. Inorg. Chem., 2021, 2021(27), 2696-2701, DOI: 10.1002/ejic.202100308
A. N. Kulakova, Nigoghossian Karina, Félix Gautier, Khrustalev Victor N., E. S. Shubina, Long Jérôme, Guari Yannick, Carlos Luis D., A. N. Bilyachenko, J. Larionova
New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages
Inorg. Chem., 2021, 60(11), 8062-8074, DOI: 10.1021/acs.inorgchem.1c00586
G. S. Astakhov, M. M. Levitsky, Zubavichus Y. V., Khrustalev Victor N., A. A. Titov, Dorovatovskii Pavel V., Smol’yakov Alexander F., E. S. Shubina, Kirillova Marina V., A. Kirillov, A. N. Bilyachenko
Cu6- and Cu8-Cage Sil- and Germsesquioxanes: Synthetic and Structural Features, Oxidative Rearrangements, and Catalytic Activity
Dalton Trans., 2021, 50(7) , 2671-2688, DOI: 10.1039/d0dt03857a
Stogniy Marina Yu, Anufriev Sergey A., Shmal'ko Akim V., Antropov Sergey M., Anisimov Aleksei A., Suponitsky Kyrill Yu, O. A. Filippov, Sivaev Igor B.
The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4’,4”-(MeOCH2CH2O)3-3,3’,3”-Co3(μ3-O)(μ3-S)(1,2-C2B9H10)3]
Molecules, 2021, 26(5), 1321, DOI: 10.3390/molecules26051321
Asawa Yasunobu, Arsent’eva Aleksandra V., Anufriev Sergey A., Anisimov Alexei A., Suponitsky Kyrill Yu, O. A. Filippov, Nakamura Hiroyuki, Sivaev Igor B
Synthesis of Bis(Carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) and Attempt of Synthesis of Gadolinium Bis(Dicarbollide)
Mendeleev Communications, 2021, 31(2), 170-172, DOI: 10.1016/j.mencom.2021.03.008
A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., Averin Alexey A., E. S. Shubina
New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2'-bipyridine
Inorg. Chem., 2021, 60 (6) , 4015–4025, DOI: 10.1021/acs.inorgchem.1c00073
Grineva Alina A., O. A. Filippov, Canac Yves, Sortais Jean-Baptiste, Nefedov Sergei E., Lugan Noël, César Vincent, D. Valyaev
Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes
Coord. Chem. Rev., 2021, 438, 213799, DOI: 10.1016/j.ccr.2021.213799
N. V. Belkova, O. A. Filippov, E. S. Osipova, S. V. Safronov, L. M. Epstein, E. S. Shubina
Iinfluence of phosphine (pincer) ligands on the transition metal hydrides reactivity
Chemical science, 2021, 12, 3682-3692, DOI: DOI: 10.1039/D0SC06114J
E. S. Osipova, E. Gulyaeva, E. I. Gutsul, V. A. Kirkina, A. A. Pavlov, Y. V. Nelyubina, A. Rossin, M. Peruzzini, L. M. Epstein, N. V. Belkova, O. A. Filippov, E. S. Shubina
Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”

2020

ChemCatChem, 2020, 12(23), 5959-5965, DOI: 10.1002/cctc.202001308
D. Gelman, De-Botton Sophie, O. A. Filippov, E. S. Shubina, N. V. Belkova
Regioselective Isomerization of Terminal Alkenes Catalyzed by a PC(sp3)P Pincer Complex with a Hemilabile Pendant Arm
Crystals, 2020, 10(10), 881, DOI: 10.3390/cryst10100881
K. F. Baranova, A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., Averin Alexey A., E. S. Shubina
Dinuclear Silver(I) Nitrate Complexes with Bridging Bisphosphinomethanes: Argentophilicity and Luminescence
Inorg. Chem., 2020, 59(17), 12240–12251, DOI: 10.1021/acs.inorgchem.0c01293
E. D. Voronova, I. E. Golub, Pavlov A., N. V. Belkova, O. A. Filippov, L. M. Epstein, E. S. Shubina
Dichotomous Si–H Bond Activation by Alkoxide and Alcohol in Base-Catalyzed Dehydrocoupling of Silanes
Chem. A Eur. J., 2020, 26(70), 16594-16598, DOI: 10.1002/chem.202003351
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, Khrustalev V., E. S. Shubina, Felix G., Mamontova E., Long J., Guari Y., J. Larionova
New Luminescent Tetranuclear Lanthanide‐based Silsesquioxane Cage‐like Architectures
Mendeleev Communications, 2020, 30(3), 366-368, DOI: 10.1016/j.mencom.2020.05.035
Khotina I. A., O. A. Filippov, Kovalev A. I.
Microporous polyphenylenes based on diacetylaromatic compounds
Dalton Trans., 2020, 49, 1473-1484, DOI: 10.1039/C9DT04532E
Kalsin A. M., Peganova T. A., Sinopalnikova I. S., Fedyanin I. V., N. V. Belkova, Deydier E., R. Poli
Mechanistic diversity in acetophenone transfer hydrogenation catalyzed by ruthenium iminophosphonamide complexes
Molecules, 2020, 25(9), 2236, DOI: 10.3390/molecules25092236
Safronov S. V., E. S. Osipova, Nelyubina Y. V., O. A. Filippov, Barakovskaya I. G., N. V. Belkova, E. S. Shubina
Steric and Electronic Effect of Cp-Substituents on the Structure of the Ruthenocene Based Pincer Palladium Borohydrides
Mendeleev Communications, 2020, 30(3), 276-278, DOI: 10.1016/j.mencom.2020.05.004
V. A. Kirkina, E. S. Osipova, O. A. Filippov, G. A. Silantyev, D. Gelman, E. S. Shubina, N. V. Belkova
Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
J. Organomet. Chem., 2020, 906, DOI: 10.1016/j.jorganchem.2019.121022
G. S. Astakhov, M. M. Levitsky, Bantreil X., F. Lamaty, Khrustalev V.N., Zubavichus Y.V., Dorovatovskii P.V., E. S. Shubina, A. N. Bilyachenko
Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
Molecules, 2020, 25(12), 2920, DOI: 10.3390/molecules25122920
I. E. Golub, O. A. Filippov, V. Kulikova, N. V. Belkova, L. M. Epstein, E. S. Shubina
Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes
Journal of Catalysis, 2020, 390, 37-45, DOI: 10.1016/j.jcat.2020.07.010
Larionov V. A., Stashneva A. R., A. A. Titov, Lisov A. A., Medvedev M. G., Smol’yakov A. F., Tsedilin A. M., E. S. Shubina, Maleev V. I.
Mechanistic Study in Azide-Alkyne Cycloaddition (CuAAC) Catalyzed by Bifunctional Trinuclear Copper(I) Pyrazolate Complex: Shift in Rate-Determining Step
Inorg. Chem., 2020, 59(17), 11962–11975, DOI: 10.1021/acs.inorgchem.0c00797
V. A. Kirkina, G. A. Silantyev, De-botton Sophie, O. A. Filippov, E. M. Kozinets (Titova), Pavlov Alexander, N. V. Belkova, L. M. Epstein, D. Gelman, E. S. Shubina
Stereoisomerism as an Origin of Different Reactivity of Ir(III) PC(sp3)P Pincer Catalysts
Inorg. Chem., 2020, 59(7) , 4536–4545, DOI: 10.1021/acs.inorgchem.9b03680
G. S. Astakhov, A. N. Bilyachenko, M. M. Levitsky, Lidia S. Shulpina, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Anna V. Vologzhanina, E. S. Shubina, Pavel V. Dorovatovskii, G. B. Shul’pin
Coordination Affinity of Cu(II)-Based Silsesquioxanes toward N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic Products Exhibiting a High Catalytic Activity in Oxidation Reactions
Chemical Communications, 2020, 56, 2139-2142, DOI: 10.1039/C9CC07713H
N. V. Kireev, O. A. Filippov, E. Gulyaeva, E. S. Shubina, Laure Vendier, Yves CANAC, Jean-Baptiste Sortais, Noël Lugan, D. Valyaev
Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation
Molecules, 2020, 24(24), 4449, DOI: 10.3390/molecules24244449
Sergey A. Anufriev, Kyrill Yu. Suponitsky, O. A. Filippov, Igor B. Sivaev
Synthesis and Structure of Methylsulfanyl Derivatives of Nickel Bis(Dicarbollide)
RSC Adv., 2020, 10(5), 2887-2896, DOI: 10.1039/c9ra08551c
Marina Yu. Stogniy, Olga N. Kazheva, Denis M. Chudak, Gennady V. Shilov, O. A. Filippov, Igor B. Sivaev, Andrey V. Kravchenko, Vladimir A. Starodub, Lev I. Buravov, Vladimir I. Bregadze, Oleg A. Dyachenkob
Synthesis and study of C-substituted methylthio derivatives of cobalt bis(dicarbollide)

2019

Mendeleev Communications, 2019, 29 (5), 570-572, DOI: 10.1016/j.mencom.2019.09.031
A. A. Titov, O. A. Filippov, A.F. Smol’yakov, A.A. Averin, E. S. Shubina
Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
Eur. J. Inorg. Chem., 2019, 2019 (45), 4855-4861, DOI: 10.1002/ejic.201901050
S. K. Emashova, A. A. Titov, O. A. Filippov, A.F. Smol'yakov, E. M. Kozinets (Titova), L. M. Epstein, E. S. Shubina
Luminescent AgI Complexes with 2,2′-Bipyridine Derivatives Featuring [Ag-(CF3)2Pyrazolate]4 Units
J. Organomet. Chem., 2019, DOI: 10.1016/j.jorganchem.2019.121022
G. S. Astakhov, M. M. Levitsky, X. Bantreil, F. Lamaty, V.N. Khrustalev, Y.V. Zubavichus, P.V. Dorovatovskii, E. S. Shubina, A. N. Bilyachenko
Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
J. Organomet. Chem., 2019, 899, DOI: 10.1016/j.jorganchem.2019.120911
A. N. Kulakova, E.E.Sedykh, M. M. Levitsky, P.V.Dorovatovskii, V.N.Khrustalev, L.S.Shul'pina, E. S. Shubina, Y.N.Kozlov, N.S.Ikonnikova, A. N. Bilyachenko, G. B. Shul’pin
The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
Catalysts, 2019, 9(9), 701-719, DOI: 10.3390/catal9090701
G. S. Astakhov, M. M. Levitsky, A. A. Korlyukov, L. S. Shul’pina, E. S. Shubina, N. S. Ikonnikov, A. V. Vologzhanina, A. N. Bilyachenko, P. V. Dorovatovskii, Y. N. Kozlov, G. B. Shul’pin
New Cu4Na4- and Cu5-Based Phenylsilsesquioxanes. Synthesis via Complexation with 1,10-Phenanthroline, Structures and High Catalytic Activity in Alkane Oxidations with Peroxides in Acetonitrile
Coord. Chem. Rev., 2019, 398, 213015, DOI: 10.1016/j.ccr.2019.213015
M. M. Levitsky, A. N. Bilyachenko, E. S. Shubina, J.Long, Y.Guari, J. Larionova
Magnetic cage-like metallasilsesquioxanes
Dalton Trans., 2019, 48, 12720 - 12729, DOI: 10.1039/C9DT02176K
S. V. Safronov, E. I. Gutsul, I. E. Golub, F. M. Dolgushin, Y. V. Nelyubina, O. A. Filippov, L. M. Epstein, A. S. Peregudov, N. V. Belkova, E. S. Shubina
Synthesis, Structural Properties and Reactivity of Ruthenocene-based Pincer Pd(II) Tetrahydroborate
Inorg. Chem., 2019, 58(13), 8645-8656, DOI: 10.1021/acs.inorgchem.9b00991
A. A. Titov, O. A. Filippov, A.F. Smolyakov, I.A. Godovikov, J.R. Shakirova, S. P. Tunik, I.S. Podkorytov, E. S. Shubina
Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane
Organometallics, 2019, 38(11), 2330-2337, DOI: 10.1021/acs.organomet.9b00151
A.A. Grineva, O. A. Filippov, S.E. Nefedov, Noël Lugan, Vincent César, D. Valyaev
Direct Access to IMesF and IMesF2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes
Dalton Trans., 2019, 48, 8410-8417, DOI: 10.1039/c9dt01355e
A. A. Titov, O. A. Filippov, A.F. Smol’yakov, A.A. Averin, E. S. Shubina
Syntheses, Structures and Luminescence of multinuclear Silver(I) pyrazolate adducts with 1, 10-Phenanthroline derivatives
J. Clust. Sci., 2019, DOI: 10.1007/s10876-019-01567-y
M. M. Levitsky, Y.V. Zubavichus, A.A. Korlyukov, V. N. Khrustalev, E. S. Shubina, A. N. Bilyachenko
Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes
Angew. Chem. Int. Ed., 2019, 58 (20), 6727-6731, DOI: 10.1002/anie.201901169
R. Buhaibeh, O. A. Filippov, J. Willot, C. Duhayon, D. Valyaev, N. Lugan, Y. Canac, J.-B. Sortais
Phosphine‐NHC Manganese Hydrogenation Catalyst Exhibiting a Non‐Classical Metal‐Ligand Cooperative H2 Activation Mode
Mendeleev Communications, 2019, 29, 121–127, DOI: 10.1016/j.mencom.2019.03.001
E. S. Osipova, O. A. Filippov, E. S. Shubina, N. V. Belkova
Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes
Coord. Chem. Rev., 2019, 386, 209-239, DOI: 10.1016/j.ccr.2019.02.007
M. M. Levitsky, A. N. Bilyachenko, E. S. Shubina
Cagelike metallagermanates and metallagermoxanes: Synthesis, structures and functional properties
Eur. J. Inorg. Chem., 2019, 10, 1389-1397, DOI: 10.1002/ejic.201801341
E. S. Osipova, E. Gulyaeva, O. A. Filippov, S. V. Safronov, A. A. Pavlov, A. V. Polukeev, V. A. Kirkina, E. M. Kozinets (Titova), E. S. Shubina, N. V. Belkova
Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes
Eur. J. Inorg. Chem., 2019, DOI: 10.1002/ejic.201801486
Shirel Cohen, A. N. Bilyachenko, D. Gelman
Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactions
J. Organomet. Chem., 2019, 884, 17-28, DOI: 10.1016/j.jorganchem.2019.01.004
A. N. Kulakova, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Xavier Bantreil, Lidia S. Shul'pina, M. M. Levitsky, Nikolay S. Ikonnikov, E. S. Shubina, F. Lamaty, A. N. Bilyachenko, G. B. Shul’pin
Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
Chemical Communications, 2019, 55, 290-293, DOI: 10.1039/C8CC08592G
A. A. Titov, V. A. Larionov, A. F. Smol’yakov, M. I. Godovikova, E. M. Kozinets (Titova), V. I. Maleev, E. S. Shubina
Interaction of a trinuclear copper(I) pyrazolate with alkynes and carbon–carbon triple bond activation
Eur. J. Inorg. Chem., 2019, 1, 18-22, DOI: 10.1002/ejic.201801094
Aullón Gabriel, Laguna Antonio, O. A. Filippov, Oliva-Enrich Josep M.
Trinuclear Gold-Carborane Cluster as a Host Structure
Eur. J. Inorg. Chem., 2019, 6, 821-827, DOI: 10.1002/ejic.201801318
A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., K. F. Baranova, E. M. Kozinets (Titova), Averin Aleksey A., E. S. Shubina
Dinuclear Cu(I) and Ag(I) pyrazolates supported with tertiary phosphines: Synthesis, structures and photophysical properties
Catalysts, 2019, 9, 154, DOI: 10.3390/catal9020154
A. N. Kulakova, V.N. Khrustalev, Y.V. Zubavichus, L.S. Shul’pina, E. S. Shubina, M. M. Levitsky, N.S. Ikonnikov, A. N. Bilyachenko, Y.N. Kozlov, G. B. Shul’pin
Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides

2018

Inorg. Chim. Acta, 2018, 470, 22-35, DOI: 10.1016/j.ica.2017.07.015
A. A. Titov, O. A. Filippov, L. M. Epstein, N. V. Belkova, E. S. Shubina
Macrocyclic Copper(I) and Silver(I) Pyrazolates: Principles of Supramolecular Assemblies with Lewis Bases
Eur. J. Inorg. Chem., 2018, 20-21, 2285-2299, DOI: 10.1002/ejic.201701344
I. S. Sinopalnikova, T. A. Peganova, N. V. Belkova, E. Deydier, J-C. Daran, E. S. Shubina, A.. M. Kalsin, R. Poli
Ruthenium p-cymene iminophosphonamide complexes: activation under basic conditions and transfer hydrogenation catalysis
Inorg. Chem., 2018, 57 (1), 528–534, DOI: 10.1021/acs.inorgchem.7b02881
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, A. N. Kulakova, X. Bantreil, F. Lamaty, M. M. Levitsky, E. I. Gutsul, E. S. Shubina, G. B. Shul’pin
Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
Organometallics, 2018, 37 (2), 168–171, DOI: 10.1021/acs.organomet.7b00845
A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, E. S. Shubina, G. B. Shul’pin
Mild and Regioselective Hydroxylation of Methyl Group in Neocuproine: Approach to an N,O-Ligated Cu6 Cage Phenylsilsesquioxane
J. Organomet. Chem., 2018, 867, 133-141, DOI: 10.1016/j.jorganchem.2017.10.033
A. N. Bilyachenko, A. N. Kulakova, L. S. Shul'pina, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, U. S. Tsareva, E. S. Shubina, A. A. Petrov, N. V. Vorontsov, G. B. Shul’pin
Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
Inorg. Chem., 2018, 57, 1656−1664, DOI: 10.1021/acs.inorgchem.7b03027
N. V. Kireev, O. A. Filippov, A. A. Pavlov, L. M. Epstein, V. D. Makhaev, V. P. Dyadchenko, E. S. Shubina, N. V. Belkova
Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N₂)₂(dppe)₂
Chem. Eur. J., 2018, 24(7), 1464–1470, DOI: 10.1002/chem.201704203
N. V. Belkova, O. A. Filippov, E. S. Shubina
Z-H bond activation in (di)hydrogen bonding as a way to proton/hydride transfer and H2 evolution
Eur. J. Inorg. Chem., 2018, 22, 2505-2511, DOI: 10.1002/ejic.201701340
A. N. Bilyachenko, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, E. S. Shubina, A. V. Vologzhanina, G. B. Shul’pin
Heptanuclear Cage Cu(II)-Silsesquioxanes. Features of Synthesis, Structure and Catalytic Activity
Crystal Growth and Design, 2018, 18 (4), 2452–2457, DOI: 10.1021/acs.cgd.8b00082
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, A. V. Vologzhanina, G. Astakhov, E. I. Gutsul, E. S. Shubina, M. M. Levitsky
High-nuclearity (Cu8-based) cage silsesquioxanes: Synthesis and structural study
J. Organomet. Chem., 2018, 865, 247-256, DOI: 10.1016/j.jorganchem.2018.03.020
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
Hydride donating abilities of the tetracoordinated boron hydrides
Angew. Chem. Int. Ed., 2018, 57(27), 7986-7991, DOI: 10.1002/anie.201801530
N. Lugan, D. Valyaev, A.A. Grineva, V. César, O. A. Filippov, V.N. Khrustalev, S.N. Nefedov
Oxidative Coupling of Anionic Abnormal N‐Heterocyclic Carbenes: an Efficient Access to Janus‐Type 4,4'‐Bis(2H‐Imidazol‐2‐Ylidenes)
Dalton Trans., 2018, 47(20), 6893-6897, DOI: 10.1039/C8DT00900G
A. N. Kulakova, A. N. Bilyachenko, A. Korlyukov, Jérôme Long, M. M. Levitsky, E. S. Shubina, Yannick Guari, J. Larionova
New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
Mendeleev Communications, 2018, 28(4), 387-389, DOI: 10.1016/j.mencom.2018.07.015
A. A. Titov, A F. Smol'yakov, K. F. Baranova, O. A. Filippov, E. S. Shubina
Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis-(trifluoromethyl)pyrazolates
Crystal Growth and Design, 2018, 18(9), 5377–5384, DOI: 10.1021/acs.cgd.8b00778
G. S. Astakhov, A. N. Bilyachenko, M. M. Levitsky, A.A. Korlyukov, Y.V. Zubavichus, P.V. Dorovatovskii, V.N. Khrustalev, A.V. Vologzhanina, E. S. Shubina
Tridecanuclear CuII11Na2 cagelike silsesquioxanes
Inorg. Chem., 2018, 57 (18), 11524–11529, DOI: 10.1021/acs.inorgchem.8b01496
G. S. Astakhov, A. N. Bilyachenko, A. Korlyukov, M. M. Levitsky, L. Shul'pina, X. Bantreil, F. Lamaty, A. Vologzhanina, E. S. Shubina, P. Dorovatovskii, D. Nesterov, A. Pombeiro, G. B. Shul’pin
High cluster (Cu9) cage silsesquioxanes. Synthesis, structure and catalytic activity
Chemistry - An Asian Journal, 2018, 13, 3084-3089, DOI: 10.1002/asia.201801156
E. D. Voronova, I. E. Golub, A. A. Pavlov, N. V. Belkova, O. A. Filippov, L. M. Epstein, E. S. Shubina
Comprehensive Insight into Hydrogen Bonding of Silanes
Dalton Trans., 2018, 47(36), 12570-12581, DOI: 10.1039/C8DT01130C
N. V. Forosenko, I. V. Basalov, A. V. Cherkasov, G. K. Fukin, E. S. Shubina, A. A. Trifonov
Amido Ca(II) complexes supported by Schiff base ligands for catalytic cross-dehydrogenative coupling of amines with silanes
Organometallics, 2018, 37 (18), 3142-3153, DOI: 10.1021/acs.organomet.8b00488
L. Luconi, E. S. Osipova, G. Giambastiani, M. Peruzzini, A. Rossin, N. V. Belkova, O. A. Filippov, E. M. Kozinets (Titova), A. A. Pavlov, E. S. Shubina
Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance
Dalton Trans., 2018, 47, 15666-15669, DOI: 10.1039/C8DT03209B
A. N. Kulakova, A. N. Bilyachenko, A. A. Korlyukov, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, N. S. Ikonnikov, G. B. Shul’pin
A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
Catalysts, 2018, 8(10), 484, DOI: 10.3390/catal8100484
A. N. Kulakova, A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, G. B. Shul’pin
Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity
IUCrJ, 2018, 5(3), 293-303, DOI: 10.1107/s2052252518001641
Zorina-Tikhonova E. N., Chistyakov A. S., Kiskin M. A., Sidorov A. A., Dorovatovskii P. V., Zubavichus Y. V., E. D. Voronova, Godovikov I. A., Korlyukov A. A., Eremenko I. L., Vologzhanina A. V.
Exploitation of knowledge databases in the synthesis of zinc(II) malonates with photo-sensitive and photo-insensitive N,N'-containing linkers
ChemistrySelect, 2018, 3(2), 653-656, DOI: 10.1002/slct.201702689
Larionov V. A., Yashkina L. V., Smolyakov A. F., Zubavichus Y.V., Babevsky K. K., Akatyev N. V., A. A. Titov, Belokon Y. N., Maleev V. I.
Synthesis and Investigations of Chiral NNO Type Copper(II) coordination Polymers
Eur. J. Inorg. Chem., 2018, 47, 5098-5107, DOI: 10.1002/ejic.201801119
Peganova T. A., O. A. Filippov, N. V. Belkova, Fedyanin I. V., Kalsin A. M.
The Origin of the MNXN Metallacycle Flexibility in the Chelate Iminophosphonamide and Amidinate Transition Metal Complexes

2017

Journal of Molecular Catalysis A: Chemical, 2017, 426, Part B, 297-304, DOI: 10.1016/j.molcata.2016.06.016
M. M. Levitsky, A. I. Yalymov, A. N. Kulakova, A. A. Petrov, A. N. Bilyachenko
Cage-like metallsilsesquioxanes in catalysis: A review
Journal of Molecular Catalysis A: Chemical, 2017, 426, 376-380, DOI: 10.1016/j.molcata.2016.08.014
E. M. Kozinets (Titova), Rahaman S. M. W, E. S. Shubina, R. Poli, N. V. Belkova, Manoury E.
Catalytic Redox Isomerization of Allylic Alcohols with Rhodium and Iridium Complexes with Ferrocene Phosphine-Thioether Ligands
Inorg. Chem., 2017, 56 (7), 4093-4103, DOI: 10.1021/acs.inorgchem.7b00061
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Petrov, Alexander A. Korlyukov, Lidia S. Shul’pina, Victor N. Khrustalev, Pavel V. Dorovatovskii, Anna V. Vologzhanina, Ulyana S. Tsareva, I. E. Golub, E. Gulyaeva, E. S. Shubina, G. B. Shul’pin
Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
Catalysts, 2017, 7(4), 101, DOI: 10.3390/catal7040101
A. I. Yalymov, A. N. Bilyachenko, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, L. S. Shul’pina, P. V. Dorovatovskii, M. A. Es’kova, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, E. S. Shubina, Y. N. Kozlov, G. B. Shul’pin
High Catalytic Activity of Heterometallic (Fe6Na7 and Fe6Na6) Cage Silsesquioxanes in Oxidations with Peroxides
ACS catalysis, 2017, 7, 2325-2333, DOI: 10.1021/acscatal.6b03207
E. M. Kozinets (Titova), E. S. Osipova, Pavlov Alexander A., O. A. Filippov, Safronov Sergey V., E. S. Shubina, N. V. Belkova
Mechanism of Dimethylamine–Borane Dehydrogenation Catalyzed by an Iridium(III) PCP-Pincer Complex
J. Organomet. Chem., 2017, 827, 86-95, DOI: 10.1016/j.jorganchem.2016.11.010
E. M. Kozinets (Titova), E. S. Osipova, E. Gulyaeva, V.N. Torocheshnikov, A.A. Pavlov, G. A. Silantyev, O. A. Filippov, E. S. Shubina, N. V. Belkova
Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
J. Organomet. Chem., 2017, 849–850 , 201-218, DOI: 10.1016/j.jorganchem.2017.05.007
M. M. Levitsky, A. N. Bilyachenko, G. B. Shul’pin
Oxidation of C‒H compounds with peroxides catalyzed by polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks
Inorg. Chem., 2017, 56, 4296−4307, DOI: 10.1021/acs.inorgchem.6b02673
Stefano Todisco, Lapo Luconi, Giuliano Giambastiani, Andrea Rossin, M. Peruzzini, I. E. Golub, O. A. Filippov, N. V. Belkova, E. S. Shubina
Ammonia Borane Dehydrogenation Catalyzed by (κ4‑EP3)Co(H) [EP3 = E(CH2CH2PPh2)3; E = N, P] and H2 Evolution from Their Interaction with NH Acids
ChemCatChem, 2017, 9 (23), 4437–4447, DOI: 10.1002/cctc.201701063
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, A. V. Vologzhanina, A. A. Titov, P. V. Dorovatovskii, L. S. Shul’pina, F. Lamaty, X. Bantreil, B. Villemejeanne, C. Ruiz, J. Martinez, E. S. Shubina, G. B. Shul’pin
Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
Dalton Trans., 2017, 46(38), 12935-12949, DOI: 10.1039/C7DT02017A
A. N. Bilyachenko, A. A. Korlyukov, A. V. Vologzhanina, V. N. Khrustalev, A. N. Kulakova, J. Long, J. Larionova, Y. Guari, M. S. Dronova, U. S. Tsareva, P. V. Dorovatovskii, E. S. Shubina, M. M. Levitsky
Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
Inorg. Chim. Acta, 2017, 456, 113-119, DOI: 10.1016/j.ica.2016.10.037
I. E. Golub, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, N. V. Belkova
The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis
Eur. J. Inorg. Chem., 2017, 4673–4682, DOI: 10.1002/ejic.201700624
I. E. Golub, O. A. Filippov, N. V. Belkova, E. I. Gutsul, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ³-P-CH₃C(CH₂CH₂PPh₂)₃}RuH(η²-BH₄)]
Inorg. Chem., 2017, 56, 12751-12763, DOI: 10.1021/acs.inorgchem.7b01436
A. N. Bilyachenko, A. I. Yalymov, M. S. Dronova, Alexander Korlyukov, Anna Vologzhanina, Marina Es’kova, Jérôme Long, J. Larionova, Yannick Guari, Pavel Dorovatovskii, E. S. Shubina, M. M. Levitsky
Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties
Chem. Eur. J., 2017, 23 (61), 15424-15435, DOI: 10.1002/chem.201702862
I. S. Sinoplanikova, T. y. A. Peganova, V. V. Novikov, I. V. Fedyanin, O. A. Filippov, N. V. Belkova, E. S. Shubina, R. Poli, A. M. Kalsin
Coordinatively labile 18-electron arene ruthenium iminophosphonamide complexes
Eur. J. Inorg. Chem., 2017, 4444–4451, DOI: 10.1002/ejic.201700575
Sergey A. Anufriev, Svetlana A. Erokhina, Kyrill Yu. Suponitsky, Ivan A. Godovikov, O. A. Filippov, Fabrizia Fabrizi de Biani, Maddalena Corsini, Alexander O. Chizhov, Igor B. Sivaev
Methylsulfanyl-Stabilized Rotamers of Cobalt Bis(dicarbollide)
Crystals, 2017, 7(10), 318-335, DOI: 10.3390/cryst7100318
N. V. Belkova, I. E. Golub, E. I. Gutsul, K. A. Lyssenko, A. S. Peregudov, V. D. Makhaev, O. A. Filippov, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
Crystal Growth and Design, 2017, 17 (12), 6770–6779, DOI: 10.1021/acs.cgd.7b01351
A. A. Titov, A. Smol’yakov, O. A. Filippov, I. Godovikov, D. Muratov, F. Dolgushin, L. M. Epstein, E. S. Shubina
Supramolecular design of the trinuclear silver(I) and copper(I) metal pyrazolates complexes with ruthenium sandwich compounds via intermolecular metal-π interactions
ACS catalysis, 2017, 7, 8139-8146, DOI: 10.1021/acscatal.7b02482
Shirel Cohen, Veniamin Borin, Igor Schapiro, Sanaa Musa, Sophie De-Botton, N. V. Belkova, D. Gelman
Ir(III)-PC(sp3)P Bifunctional Catalysts for Production of H2 by Dehydrogenation of Formic Acid: Experimental and Theoretical Study
Inorg. Chem., 2017, 56 (16), 9834–9850, DOI: 10.1021/acs.inorgchem.7b01348
Svetlana G. Churusova, Diana V. Aleksanyan, Ekaterina Yu. Rybalkina, Olga Yu. Susova, Valentina V. Brunova, Rinat R. Aysin, Yulia V. Nelyubina, Alexander S. Peregudov, E. I. Gutsul, Zinaida S. Klemenkova, and Vladimir A. Kozlov
Highly Cytotoxic Palladium(II) Pincer Complexes Based on Picolinylamides Functionalized with Amino Acids Bearing Ancillary S-Donor Groups
Inorg. Chem., 2017, 56 (24), 15026–15040, DOI: 10.1021/acs.inorgchem.7b02320
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, A. A. Korlyukov, Y. V. Zubavichus, P. V. Dorovatovskii, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, L. S. Shul’pina, E. S. Shubina, E. I. Gutsul, I. A. Mikhailov, N. S. Ikonnikov, U. S. Tsareva, G. B. Shul’pin
Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
Russ. Chem. Bull., 2017, 66 (9), 1563–1568, DOI: 10.1007/s11172-017-1925-2
A. A. Titov, A F. Smol´yakov, A. N. Rodionov, I. D. Kosenko, E. Guseva, Ya. V. Zubavichus, P. V. Dorovatovskii, O. A. Filippov, E. S. Shubina
Ferrocenecontaining tri and tetranuclear cyclic copper(I) and silver(I) pyrazolates
Eur. J. Inorg. Chem., 2017, 48, 5663–5669, DOI: 10.1002/ejic.201701160
M.M. Vinogradov, D.S. Perekalin, E. I. Gutsul, V.V. Novikov, A.F. Smol'yakov, H. Wadepohl, A.R. Kudinov, D.A. Loginov
Cluster [Co₃(CO)₃(µ₂-CO)₃(µ₃-C₈H₈)]^– as a Ligand: Experimental and Theoretical Study

2016

Chemical Reviews, 2016, 116, 8545-8587, DOI: 10.1021/acs.chemrev.6b00091
N. V. Belkova, L. M. Epstein, O. A. Filippov, E. S. Shubina
Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides
Coord. Chem. Rev., 2016, 306, 235-269, DOI: 10.1016/j.ccr.2015.07.007
M. M. Levitsky, A. N. Bilyachenko
Modern concepts and methods in the chemistry of polyhedral metallasiloxanes
Eur. J. Inorg. Chem., 2016, 56–63, DOI: 10.1002/ejic.201501083
E. M. Kozinets (Titova), G. A. Silantyev, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, Fedor M. Dolgushin, N. V. Belkova
PCP Pincer Iridium Chemistry: Coordination of Pyridines to (tBuPCP)IrH(Cl)
Dalton Trans., 2016, 45, 7320 - 7327, DOI: 10.1039/C6DT00113K
A. N. Bilyachenko, A. I. Yalymov, A. Korlyukov, J. Long, J. Larionova, Y. Guari, A. V. Vologzhanina, M. Eskova, E. S. Shubina, M. M. Levitsky
Unusual penta- and hexanuclear Ni(II)-based silsesquioxane polynuclear complexes
Eur. J. Inorg. Chem., 2016, 1415–1424, DOI: 10.1002/ejic.201600034
E. S. Osipova, N. V. Belkova, L. M. Epstein, O. A. Filippov, V. A. Kirkina, E. M. Kozinets (Titova), A. Rossin, M. Peruzzini, E. S. Shubina
Dihydrogen Bonding and Proton Transfer from MH vs OH acids to Group 10 Metal Hydrides (tBuPCP)MH [tBuPCP = 3-2,6-(tBu2PCH2)2C6H3; M = Ni, Pd]
RSC Adv., 2016, 6, 48165 - 48180, DOI: 10.1039/C6RA07081G
A. N. Bilyachenko, M. M. Levitsky, A. I. Yalymov, A. Korlyukov, A. Vologzhanina, Yu. Kozlov, L. Shul'pina, D. Nesterov, A. Pombeiro, F. Lamaty, X. Bantreil, A. Fetre, D. Liu, J. Martinez, J. Long, J. Larionova, Y. Guari, A. Trigub, Y. Zubavichus, I. E. Golub, O. A. Filippov, E. S. Shubina, G. B. Shul’pin
A Heterometallic (Fe6Na8) Cage-like Silsesquioxane: Synthesis, Structure, Spin Glass Behavior and High Catalytic Activity
Dalton Trans., 2016, 45, 9127 - 9135, DOI: 10.1039/c6dt01104g
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]
Molecules, 2016, 21, 665, DOI: 10.3390/molecules21050665
A. N. Bilyachenko, A. I. Yalymov, Shul’pina L.S., Mandelli, D., Korlyukov, A.A., Vologzhanina A.V., Es’kova M.A., E. S. Shubina, M. M. Levitsky, G. B. Shul’pin
Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
Dalton Trans., 2016, 45, 13663 - 13666, DOI: 10.1039/C6DT02026G
A. N. Bilyachenko, A. I. Yalymov, M. M. Levitsky, A. Korlyukov, M. Eskova, J. Long, J. Larionova, Y. Guari, L.S. Shul'pina, N.S. Ikonnikov, A. Trigub, Y.V. Zubavichus, I. E. Golub, E. S. Shubina, G. B. Shul’pin
First Cage-Like Pentanuclear Co(II)-Silsesquioxane
J. Phys. Chem. A, 2016, DOI: 10.1021/acs.jpca.6b06579
A. A. Titov, E. Guseva, O. A. Filippov, G. M. Babakhina, I. A. Godovikov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The Role of Weak Interactions in Strong Intermolecular M•••Cl Complexes of Coinage Metal Pyrazolates: Spectroscopic and DFT Study
Angew. Chem. Int. Ed., 2016, 55, 15360-15363, DOI: 10.1002/anie.201607189
A. N. Bilyachenko, M. M. Levitsky, A. I. Yalymov, A.A. Korlyukov, V.N. Khrustalev, A.V. Vologzhanina, L.S. Shul’pina, N.S. Ikonnikov, A.E. Trigub, P.V. Dorovatovsky, X. Bantreil, F. Lamaty, J. Long, J. Larionova, I. E. Golub, E. S. Shubina, G. B. Shul’pin
Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity

2015

Chem. Eur. J., 2015, 21, 13176-13180, DOI: 10.1002/chem.201502085
O. A. Filippov, A. A. Titov, E. Guseva, D. A. Loginov, A. F. Smol'yakov, F. M. Dolgushin, N. V. Belkova, L. M. Epstein, E. S. Shubina
Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene
J. Phys. Chem. A, 2015, 119, 3853-3868, DOI: 10.1021/acs.jpca.5b01921
I. E. Golub, E. Gulyaeva, O. A. Filippov, V. P. Dyadchenko, N. V. Belkova, L. M. Epstein, D. E. Arkhipov, E. S. Shubina
Dihydrogen Bond Intermediated Alcoholysis of Dimethylamine-Borane in Non-Aqueous Media
Chem. A Eur. J., 2015, 21, 8758-8770, DOI: 10.1002/chem.201500791
A. N. Bilyachenko, M. S. Dronova, A. I. Yalymov, F. Lamaty, X. Bantreil, J. Martinez, C. Bizet, L. S. Shul'pina, A. A. Korlyukov, D. E. Arkhipov, M. M. Levitsky, E. S. Shubina, A. M. Kirillov, G. B. Shul’pin
Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
New J. Chem., 2015, 39, 187-199, DOI: 10.1039/C4NJ01163E
M. M. Vinogradov, Yu. N. Kozlov, A. N. Bilyachenko, D. S. Nesterov, L. S. Shul'pina, Ya. V. Zubavichus, A. J. L. Pombeiro, M. M. Levitsky, A. I. Yalymov, G. B. Shul’pin
Alkane oxidation with peroxides catalyzed by cage-like copper(II) silsesquioxanes
Chem. Eur. J., 2015, 21, 18563–18565, DOI: 10.1002/chem.201503635
A. N. Bilyachenko, A. I. Yalymov, A. A. Korlyukov, J. Long, J. Larionova, Y. Guari, Y. V. Zubavichus, A. L. Trigub, E. S. Shubina, I. L. Eremenko, N. N. Efimov, M. M. Levitsky
Heterometallic Na6Co3 Phenylsilsesquioxane Exhibiting Slow Dynamic Behavior in its Magnetization
Angew. Chem. Int. Ed., 2015, 54(21), 6315-6319, DOI: 10.1002/anie.201501256
D. Valyaev, O. A. Filippov, N. Lugan, G. Lavigne, N. A. Ustynyuk
Umpolung of Methylenephosphonium Ions in Their Manganese Half-Sandwich Complexes and Application to the Synthesis of Chiral Phosphorus-Containing Ligand Scaffolds
Russ. Chem. Bull., 2015, 64(12), 2806–2810, DOI: 10.1007/s11172-015-1230-x
G. A. Silantyev, E. M. Kozinets (Titova), O. A. Filippov, E. I. Gutsul, D. Gelman, N. V. Belkova
Hydrogen bonds, coordination isomerism, and catalytic dehydrogenation of alcohols with the bifunctional iridium pincer complex (HOCH2)2(PCsp3P)IrHCl

2014

Advances in Organometallic Chemistry, 2014, First Edition. Ed.: A. J. L. Pombeiro. John Willey & Sons, Inc. chapt. 8, 97-109. (book chapter)
E. S. Shubina, N. V. Belkova, O. A. Filippov, L. M. Epstein
The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book. Weak Interactions and M-H Bond Activation
Inorg. Chem., 2014, 53, 1080–1090, DOI: 10.1021/ic4026206
N. V. Belkova, E. V. Bakhmutova-Albert, E. I. Gutsul, V. I. Bakhmutov, I. E. Golub, O. A. Filippov, L. M. Epstein, M. Peruzzini, A. Rossin, F. Zanobini, E. S. Shubina
Dihydrogen bonding in complex (PP3)RuH(η1-BH4) featuring two proton-accepting hydride sites: experimental and theoretical studies
RSC Adv., 2014, 4, 8350 – 8359, DOI: 10.1039/C3RA47040G
A. A. Titov, O. A. Filippov, E. Guseva, A. F. Smol’yakov, F. M. Dolgushin, L. M. Epstein, V. K. Belsky, E. S. Shubina
Role of basic sites of substituted ferrocenes in interaction with the trinuclear 3,5-bis(trifluoromethyl)pyrazolates: thermodynamics and structure of complexes
Dalton Trans., 2014, 43, 872 – 882, DOI: 10.1039/C3DT52508B
M. S. Dronova, A. N. Bilyachenko, A. I. Yalymov, Kozlov Y.N., Shul’pina L.S., Korlyukov A.A., Arkhipov D.E., M. M. Levitsky, E. S. Shubina, G. B. Shul’pin
Solvent-controlled synthesis of tetranuclear cage-like copper(II) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation of benzene and alcohols with peroxides
Russ. Chem. Bull., 2014, 63, 821-825, DOI: 10.1007/s11172-014-0515-9
A. I. Yalymov, M. S. Dronova, O. A. Filippov, A. N. Bilyachenko, M. M. Levitsky
Quantum chemical study of the template synthesis of cage-like metallasiloxanes
Russ. Chem. Bull., 2014, 63, 2434-2437, DOI: 10.1007/s11172-014-0759-4
G. A. Silantyev, E. M. Kozinets (Titova), O. A. Filippov, E. Yakurnova, N. V. Belkova
Dihydrogen bonding formed by (hydrido)[hydrotris(pyrazolyl)borato]ruthenium. The effect of ligands on the proton-withdrawing ability of ruthenium complexes
Organometallics, 2014, 33, 5964-5973, DOI: 10.1021/om500308g
G. A. Silantyev, O. A. Filippov, S. Musa, D. Gelman, N. V. Belkova, K. Weisz, L. M. Epstein, E. S. Shubina
Conformational Flexibility of Dibenzobarrelene-Based PC(sp3)P Pincer Iridium Hydride Complexes: The Role of Hemilabile Functional Groups and External Coordinating Solvents
Russ. Chem. Bull., 2014, 63, 2428-2433, DOI: 10.1007/s11172-014-0758-5
O. A. Filippov, I. E. Golub, E. S. Osipova, V. A. Kirkina, E. I. Gutsul, N. V. Belkova
Transition metal hydride M—H bond activation upon the formation of complexes with acids and bases

2013

J. Organomet. Chem., 2013, 747, 30-42, DOI: 10.1016/j.jorganchem.2013.04.025
O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
Chemistry of boron hydrides orchestrated by dihydrogen bonds
Z. Phys. Chem., 2013, 227, 69–88
O. A. Filippov, V. A. Kirkina, N. V. Belkova, S. Stoccoro, A. Zucca, G. M. Babakhina, L. M. Epstein, E. S. Shubina
First Example of Hydrogen Bonding to Platinum Hydride
Chem. Eur. J., 2013, 19, 16906–16909, DOI: 10.1002/chem.201303311
S. Musa, O. A. Filippov, N. V. Belkova, E. S. Shubina, G. A. Silantyev, L. Ackermann, D. Gelman
Ligand–Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation
Inorg. Chem., 2013, 52, 1787−1797, DOI: 10.1021/ic301585k
G. A. Silantyev, O. A. Filippov, P.M. Tolstoy, N. V. Belkova, L. M. Epstein, K. Weisz, E. S. Shubina
Hydrogen bonding and proton transfer to ruthenium hydride complex CpRuH(dppe): metal and hydride dichotomy.
Dalton Trans., 2013, 42, 11720-11730, DOI: 10.1039/C3DT51429C
E. M. Kozinets (Titova), M. Fekete, O. A. Filippov, N. V. Belkova, E. S. Shubina, R. Poli, S. Duckett, E. Manoury
Activation of a (cyclooctadiene) rhodium(I) complex supported by a chiral ferrocenyl phosphine thioether ligand for hydrogenation catalysis: a combined parahydrogen NMR and DFT study
Russ. Chem. Bull., 2013, 62, 751-757
E. M. Kozinets (Titova), G. A. Silantyev, N. V. Belkova, E. S. Shubina, R. Poli, E. Manoury
Iridium and rhodium complexes with the planar chiral thioether ligands in asymmetric hydrogenation of ketones and imines
Eur. J. Inorg. Chem., 2013, 5240-5246, DOI: 10.1002/ejic.201300878
A. N. Bilyachenko, M. S. Dronova, A. I. Yalymov, A.A. Korlyukov, L.S. Shul’pina, D.E. Arkhipov, E. S. Shubina, M. M. Levitsky, A.D. Kirilin, G. B. Shul’pin
New Binuclear Cage-like Copper(II) Silsesquioxane (“Cooling Tower”); Its High Catalytic Activity in Oxidation of Benzene and Alcohols
Russ. Chem. Bull., 2013, 62, 1941-1943
M. S. Dronova, A. N. Bilyachenko, A.A. Korlyukov, D.E. Arkhipov, A.D. Kirilin, E. S. Shubina, G. M. Babakhina, M. M. Levitsky
A new type of supramolecular organization in the cage-like metallasiloxanes
Russ. Chem. Bull., 2013, 62, 1829-1834
A. A. Titov, E. Guseva, A. F. Smol’yakov, F. M. Dolgushin, O. A. Filippov, I. E. Golub, ^krylova#, G. M. Babakhina, L. M. Epstein, E. S. Shubina
Complexation of trimeric copper(I) and silver(I) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane

2012

Spectrosc. Prop. Inorg. Organomet. Compd., 2012, 43, 1–28 (book chapter)
N. V. Belkova, L. M. Epstein, O. A. Filippov, E. S. Shubina
IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies
ChemPhysChem, 2012, 13, 2677
O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Lledos, E. S. Shubina
Directionality of Dihydrogen Bonds: The Role of Transition Metal Atoms
Comput Theor Chem, 2012, 998, 129-140
O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Lledos, E. S. Shubina
Hydrogen–deuterium exchange in hydride chemistry: Dihydrogen bonded complexes as key intermediates
Inorg. Chem., 2012, 51, 6486-6497
I. E. Golub, O. A. Filippov, E. I. Gutsul, N. V. Belkova, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond
Eur. J. Inorg. Chem., 2012, 5554–5561
A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A.F. Smol’yakov, F.M. Dolgushin, V.K. Belsky, I.A. Godovikov, L. M. Epstein, E. S. Shubina
Complexes of Trinuclear Macrocyclic Copper(I) and Silver(I) 3,5- Bis(Trifluoromethyl)Pyrazolates with Ketones
Russ. Chem. Bull., 2012, 61, 200-203
M. M. Levitsky, A. N. Bilyachenko, M. S. Dronova, A.I. Dmitriev, R.B. Morgunov, E. S. Shubina, A.D. Kirilin
Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments
Dalton Trans., 2012, 41, 11849-11859
E. M. Kozinets (Titova), O. Koniev, O. A. Filippov, J.-C. Daran, R. Poli, E. S. Shubina, N. V. Belkova, E. Manoury
Coordination chemistry of diphenylphosphinoferrocenylthioethers on cyclooctadiene and norbornadiene rhodium(I) platforms

2011

J. Organomet. Chem., 2011, 696, 1174-1183
P. A. Dub, J.-C. Daran, V. A. Kirkina, N. V. Belkova, E. S. Shubina, R. Poli
Modeling the platinum-catalyzed intermolecular hydroamination of ethylene: the nucleophilic addition of HNEt2 to coordinated ethylene in trans-PtBr2(C2H4)(HNEt2)
Dalton Trans., 2011, 40, 1535-46?
D V Aleksanyan, V A Kozlov, Y V Nelyubina, K A Lyssenko, L N Puntus, E. I. Gutsul, N E Shepel, A A Vasil'ev, P V Petrovskii, I L Odinets
Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS'-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides
Angew. Chem. Int. Ed., 2011, 50, 1367–1370
V. A. Kirkina, A. Rossin, N. V. Belkova, M. R. Chierotti, L. M. Epstein, O. A. Filippov, R. Gobetto, L. Gonsalvi, A. Lledos, E. S. Shubina, F. Zanobini, M. Peruzzini
Acid-base interaction between transition metal hydrides results in dihydrogen bonding and assists H2 evolution
Inorg. Chem., 2011, 50, 3325-3331
V. N.Tsupreva, A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A. F.Smol'yakov, F. M. Dolgushin, D. V. Agapkin, I. A. Godovikov, L. M. Epstein, E. S. Shubina
Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds
Inorg. Chem., 2011, 50, 444-450
O.N. Kazheva, G.G. Alexandrov, A.V. Kravchenko, I.D. Kosenko, I.A. Lobanova, I.B. Sivaev, O. A. Filippov, E. S. Shubina, V.I. Bregadze, V.A. Starodub, L.V. Titov, L.I. Buravov, O.A. Dyachenko
Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion
Inorg. Chem., 2011, 50, 12539-52
A. Béthegnies, V. A. Kirkina, O. A. Filippov, J.-C. Daran, N. V. Belkova, E. S. Shubina, R. Poli
Coordination and Organometallic Chemistry of Relevance to the Rhodium-Based Catalyst for Ethylene Hydroamination