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Novel types of hydrogen bonding involving organometallic compounds and transition metal hydrides

Novel types of hydrogen bonding involving organometallic compounds and transition metal hydrides
Mechanistic studies of stoichiometric and catalytic reactions involving migration of hydrogen ions. The studies are performed using combination of low temperature molecular spectroscopy measurements and quantum chemical calculations.
Publications
2021
  • Eur. J. Inorg. Chem., 2021, 2021(41), 4265 - 4272, DOI: 10.1002/ejic.202100489
    N. V. Kireev, Kiryutin A.S., Pavlov A.A., Yurkovskaya A.V., Musina E.I., Karasik A.A., E. S. Shubina, Ivanov K.L., N. V. Belkova
    Nickel(II) dihydrogen and hydride complexes as the intermediates of H2 heterolytic splitting by nickel diazadiphosphacyclooctane complexes
  • Inorg. Chem., 2021, 60(13), 9880-9898, DOI: 10.1021/acs.inorgchem.1c01138
    Churusova S.G., Aleksanyan D.V., Rybalkina E.Y., Susova O.Y., Peregudov A.S., Brunova V.V., E. I. Gutsul, Klemenkova Z.S., Nelyubina Y.V., Glushko V.N., Kozlov V.A.
    Palladium(II) pincer complexes of functionalized amides with S-modified cysteine and homocysteine residues: cytotoxic activity and different aspects of their biological effect on living cells
  • Organic and Biomolecular Chemistry, 2021, 19(43), 9421 - 9426, DOI: 10.1039/D1OB01711J
    Petropavlovskikh D.A., Vorobyeva D.V., Godovikov I.A., Nefedov S.E., O. A. Filippov, Osipov S.N.
    Lossen rearrangement by Rh(III)-catalyzed C-H activation/annulation of aryl hydroxamates with alkynes: access to quinolone-containing amino acid derivatives
  • Inorg. Chem., 2021, 60 (6) , 4015–4025, DOI: 10.1021/acs.inorgchem.1c00073
    Grineva Alina A., O. A. Filippov, Canac Yves, Sortais Jean-Baptiste, Nefedov Sergei E., Lugan Noël, César Vincent, D. Valyaev
    Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes
  • Coord. Chem. Rev., 2021, 438, 213799, DOI: 10.1016/j.ccr.2021.213799
    Iinfluence of phosphine (pincer) ligands on the transition metal hydrides reactivity
  • Chemical science, 2021, 12, 3682-3692, DOI: DOI: 10.1039/D0SC06114J
    Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
2020
2019
2018
2017
2016
2015
  • Angew. Chem. Int. Ed., 2015, 54(21), 6315-6319, DOI: 10.1002/anie.201501256
    D. Valyaev, O. A. Filippov, N. Lugan, G. Lavigne, N. A. Ustynyuk
    Umpolung of Methylenephosphonium Ions in Their Manganese Half-Sandwich Complexes and Application to the Synthesis of Chiral Phosphorus-Containing Ligand Scaffolds
2014
2013
2012
2011