Intermolecular interactions and reactivity of main group hydrides including polyhedral boron compounds
Intermolecular interactions and reactivity of main group hydrides including polyhedral boron compounds
Publications
2021
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The mechanism of halogenation of decahydro-closo-decaborate dianion by hydrogen chloride
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Stogniy Marina Yu, Anufriev Sergey A., Shmal'ko Akim V., Antropov Sergey M., Anisimov Aleksei A., Suponitsky Kyrill Yu, O. A. Filippov, Sivaev Igor B. The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4’,4”-(MeOCH2CH2O)3-3,3’,3”-Co3(μ3-O)(μ3-S)(1,2-C2B9H10)3]
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Asawa Yasunobu, Arsent’eva Aleksandra V., Anufriev Sergey A., Anisimov Alexei A., Suponitsky Kyrill Yu, O. A. Filippov, Nakamura Hiroyuki, Sivaev Igor B Synthesis of Bis(Carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) and Attempt of Synthesis of Gadolinium Bis(Dicarbollide)
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E. S. Osipova, E. Gulyaeva, E. I. Gutsul, V. A. Kirkina, A. A. Pavlov, Y. V. Nelyubina, A. Rossin, M. Peruzzini, L. M. Epstein, N. V. Belkova, O. A. Filippov, E. S. Shubina Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
2020
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Dichotomous Si–H Bond Activation by Alkoxide and Alcohol in Base-Catalyzed Dehydrocoupling of Silanes
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Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
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Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes
2019
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Synthesis, Structural Properties and Reactivity of Ruthenocene-based Pincer Pd(II) Tetrahydroborate
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Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes
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Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes
2018
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Z-H bond activation in (di)hydrogen bonding as a way to proton/hydride transfer and H2 evolution
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Hydride donating abilities of the tetracoordinated boron hydrides
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Comprehensive Insight into Hydrogen Bonding of Silanes
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N. V. Forosenko, I. V. Basalov, A. V. Cherkasov, G. K. Fukin, E. S. Shubina, A. A. Trifonov Amido Ca(II) complexes supported by Schiff base ligands for catalytic cross-dehydrogenative coupling of amines with silanes
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Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance
2017
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Mechanism of Dimethylamine–Borane Dehydrogenation Catalyzed by an Iridium(III) PCP-Pincer Complex
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Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
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Ammonia Borane Dehydrogenation Catalyzed by (κ4‑EP3)Co(H) [EP3 = E(CH2CH2PPh2)3; E = N, P] and H2 Evolution from Their Interaction with NH Acids
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The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis
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Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ3-P-CH3C(CH2CH2PPh2)3}RuH(η2-BH4)]
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Sergey A. Anufriev, Svetlana A. Erokhina, Kyrill Yu. Suponitsky, Ivan A. Godovikov, O. A. Filippov, Fabrizia Fabrizi de Biani, Maddalena Corsini, Alexander O. Chizhov, Igor B. Sivaev Methylsulfanyl-Stabilized Rotamers of Cobalt Bis(dicarbollide)
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N. V. Belkova, I. E. Golub, E. I. Gutsul, K. A. Lyssenko, A. S. Peregudov, V. D. Makhaev, O. A. Filippov, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
2016
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Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides
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Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]
2014
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Advances in Organometallic Chemistry, 2014, First Edition. Ed.: A. J. L. Pombeiro. John Willey & Sons, Inc. chapt. 8, 97-109. (book chapter)
The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book. Weak Interactions and M-H Bond Activation
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N. V. Belkova, E. V. Bakhmutova-Albert, E. I. Gutsul, V. I. Bakhmutov, I. E. Golub, O. A. Filippov, L. M. Epstein, M. Peruzzini, A. Rossin, F. Zanobini, E. S. Shubina Dihydrogen bonding in complex (PP3)RuH(η1-BH4) featuring two proton-accepting hydride sites: experimental and theoretical studies
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Dihydrogen bonding formed by (hydrido)[hydrotris(pyrazolyl)borato]ruthenium. The effect of ligands on the proton-withdrawing ability of ruthenium complexes
2012
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Spectrosc. Prop. Inorg. Organomet. Compd., 2012, 43, 1–28 (book chapter)
IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies
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Comput Theor Chem, 2012, 998, 129-140
Hydrogen–deuterium exchange in hydride chemistry: Dihydrogen bonded complexes as key intermediates
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Inorg. Chem., 2012, 51, 6486-6497
Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond
2011
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Inorg. Chem., 2011, 50, 444-450
O.N. Kazheva, G.G. Alexandrov, A.V. Kravchenko, I.D. Kosenko, I.A. Lobanova, I.B. Sivaev, O. A. Filippov, E. S. Shubina, V.I. Bregadze, V.A. Starodub, L.V. Titov, L.I. Buravov, O.A. Dyachenko Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion