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Metal-oxo clusters with organoelement and organic ligands

Metal-oxo clusters with organoelement and organic ligands
Cage-like compounds with metal oxo core, bound to heterochained ligands
Study of cage’ self-assembling and rearrangements, especially in the presence of additional organic ligands (“double ligation principle”)
Study of supramolecular assembling of cage compounds
Study of complexes’ structure in solid state (X-ray, XPD, EXAFS) and solution (IR/UV)
Study of cage activity as precatalysts in wide range of processes
Study of cage’ molecular magnetism
Publications
2024
  • Chem. Eur. J., 2024, e202401164, DOI: 10.1002/chem.202401164
    A. Yu. Zueva, A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., Dorovatovskii Pavel V., Shul’pina Lidia S., Ikonnikov Nikolay S., E. I. Gutsul, Rahimov Karim G., E. S. Shubina, Conceição Nuno Reis, Mahmudov Kamran T., Guedes da Silva M.Fátima C, Pombeiro Armando J.L.
    A family of hexacopper phenylsilsesquioxane/acetate complexes: synthesis, solvent‐controlled cage structures, and catalytic activity
  • Front. Chem., 2024, 12:1379587, DOI: 10.3389/fchem.2024.1379587
    Gautier Félix, A. N. Kulakova, Saad Sene, Victor N. Khrustalev, Miguel A. Hernández-Rodríguez, E. S. Shubina, Tristan Pelluau, Luís D. Carlos, Yannick Guari, Albano N. Carneiro Neto, A. N. Bilyachenko, J. Larionova
    Luminescent Ln3+-based silsesquioxanes with a β-diketonate antenna ligand: toward the design of efficient temperature sensors
  • Synthesis and Applications in Chemistry and Materials, 2024, 11, 245-279, DOI: 10.1142/9789811283208_0008
    A. N. Bilyachenko, Nuno Reis Conceição, M Fátima C Guedes da Silva, Kamran T. Mahmudov, G. B. Shul’pin, and Armando J. L. Pombeiro
    Chapter 8 in book: Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes
  • Inorg. Chem., 2024, 63(4), 1909–1918, DOI: 10.1021/acs.inorgchem.3c03587
    A. N. Bilyachenko, Khrustalev Victor N., Dorovatovskii Pavel V., Shul’pina Lidia S., Ikonnikov Nikolay S., E. S. Shubina, Lobanov Nikolai N., Aliyeva Vusala A., Nunes Ana V.M., Mahmudov Kamran T., Kozlov Yuriy N., Pombeiro Armando J.L.
    Fe(III)-Based Phenylsilsesquioxane/Acetylacetonate Complexes: Synthesis, Cage-like Structure, and High Catalytic Activity
2023
2022
2021
2020
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2013
2012