Metal-oxo clusters with organoelement and organic ligands
Cage-like compounds with metal oxo core, bound to heterochained ligands
Study of cage’ self-assembling and rearrangements, especially in the presence of additional organic ligands (“double ligation principle”)
Study of supramolecular assembling of cage compounds
Study of complexes’ structure in solid state (X-ray, XPD, EXAFS) and solution (IR/UV)
Study of cage activity as precatalysts in wide range of processes
Study of cage’ molecular magnetism
Publications
2024
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A. N. Bilyachenko, Khrustalev Victor N., Huang Zhibin, Dubinina Kristina D., E. S. Shubina, Lobanov Nikolai N., Sun Di, Alegria Elisabete C.B.A, Pombeiro Armando J.L. An ionic Cu9Na4-phenylsilsesquioxane/bis(triphenylphosphine)iminium complex: synthesis, unique structure, and catalytic activity
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Rational (supra)molecular design and catalytic activity of cagelike Cu4-based phenylsilsesquioxanes
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Shen Qi, Sheng Kai, Gao Zhi-Yong, A. N. Bilyachenko, Huang Xian-Qiang, Azam Mohammad, Tung Chen-Ho, Sun Di. Vanadium-Silsesquioxane Nanocages as Heterogeneous Catalysts for Synthesis of Quinazolinones
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A. Yu. Zueva, A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., Dorovatovskii Pavel V., Shul’pina Lidia S., Ikonnikov Nikolay S., E. I. Gutsul, Rahimov Karim G., E. S. Shubina, Conceição Nuno Reis, Mahmudov Kamran T., Guedes da Silva M.Fátima C, Pombeiro Armando J.L. A family of hexacopper phenylsilsesquioxane/acetate complexes: synthesis, solvent‐controlled cage structures, and catalytic activity
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Gautier Félix, A. N. Kulakova, Saad Sene, Victor N. Khrustalev, Miguel A. Hernández-Rodríguez, E. S. Shubina, Tristan Pelluau, Luís D. Carlos, Yannick Guari, Albano N. Carneiro Neto, A. N. Bilyachenko, J. Larionova Luminescent Ln3+-based silsesquioxanes with a β-diketonate antenna ligand: toward the design of efficient temperature sensors
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Chapter 8 in book: Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes
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A. N. Bilyachenko, Khrustalev Victor N., Dorovatovskii Pavel V., Shul’pina Lidia S., Ikonnikov Nikolay S., E. S. Shubina, Lobanov Nikolai N., Aliyeva Vusala A., Nunes Ana V.M., Mahmudov Kamran T., Kozlov Yuriy N., Pombeiro Armando J.L. Fe(III)-Based Phenylsilsesquioxane/Acetylacetonate Complexes: Synthesis, Cage-like Structure, and High Catalytic Activity
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A. N. Bilyachenko, Victor N. Khrustalev, Zhibin Huang, Pavel V. Dorovatovskii, E. S. Shubina, Nikolai N. Lobanov, Zhi Wang, Karim Ragimov, Nuno Reis Conceição, Abdallah G. Mahmoud, Armando J. L. Pombeiro Combination of phenylsilsesquioxane and acetate ligands as an approach to a record high nuclear Cu13Na2-cage. Synthesis, unique structure, and catalytic activity
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A. N. Bilyachenko, Khrustalev V. N., Arteev I. S., Shul’pina L. S., Ikonnikov N. S., Kirillova M. V., E. S. Shubina, Kirillov A. M., Kozlov Y.N., Lobanov N. N., Ragimov K. G., Sun Di. Cu12-Methylsilsesquioxane Cage Decorated with Cu(dppe)2 Moieties for Mild Oxidative Functionalization of Alkanes
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A. N. Bilyachenko, Khrustalev V. N., Huang Z., Shul'pina L. S., Dorovatovskii P., E. S. Shubina, Ikonnikov N. S., Lobanov N. N., Rahimov K. G., Sun Di. An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity
2023
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Tetranuclear lanthanide-based silsesquioxanes: towards a combination of a slow relaxation of the magnetization and a luminescent thermometry
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A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., Shul’pina Lidia S., Korlyukov Alexander A., Ikonnikov Nikolay S., E. S. Shubina, Kozlov Yuriy N., Conceição Nuno Reis, Guedes da Silva M.Fátima C, Mahmudov Kamran T., Pombeiro Armando J.L. Cage-like Cu5Cs4-phenylsilsesquioxanes: synthesis, supramolecular structures, and catalytic activity
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A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., Chusova Olga, Dorovatovskii Pavel V., Aliyeva Vusala A., Paninho Ana B., Nunes Ana V.M., Mahmudov Kamran T., E. S. Shubina, Pombeiro Armando J.L A Family of сagelike Mn-silsesquioxane/bathophenanthroline complexes: synthesis, structure, and catalytic and antifungal activity
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Cagelike manganesesilsesquioxane complexes: synthesis via an acetone approach, structure, and catalytic activity for toluene oxidation
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A. N. Bilyachenko, Victor N. Khrustalev, G. S. Astakhov, A. Yu. Zueva, Arteev I. S., Yan V. Zubavichus, Alexander A. Korlyukov, Pavel V. Dorovatovskii, Lidia S. Shul’pina, Nikolay S. Ikonnikov, Marina V. Kirillova, E. S. Shubina, * Yuriy N. Kozlov, A. Kirillov, G. B. Shul’pin Cagelike Rb2‑, K2‑, and Na2‑Tetracopper(II) Silsesquioxanes with Quaternary
Ammonium Cations: Synthesis, Structures, and Catalytic Activity
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Félix G., A. N. Kulakova, Sene S., Charlot C., A. N. Bilyachenko, Korlyukov A.A., Volodin A.D., E. S. Shubina, Elizbarian I. G. , Guari Y., J. Larionova New family of luminescent tetranuclear lanthanide-based germsesquioxanes: luminescence and temperature sensing
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Cagelike octacopper methylsilsesquioxanes: self-assembly in the focus of alkaline metal ion influence—synthesis, structure, and catalytic activity
2022
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G. S. Astakhov, Khrustalev Victor N., M. S. Dronova, E. I. Gutsul, Korlyukov Alexander, D. Gelman, Zubavichus Yan V., Novichkov Daniil, Trigub Alexander, E. S. Shubina, A. N. Bilyachenko Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
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A. N. Bilyachenko, Khrustalev V.N., A. Yu. Zueva, E. M. Kozinets (Titova), G. S. Astakhov, Zubavichus Y.V., Dorovatovskii P.V., Korlyukov A.S., Shul'pina L.S., E. S. Shubina, Kozlov Y.N., Ikonnikov N.S., D. Gelman, G. B. Shul’pin A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity
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A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., G. S. Astakhov, A. Yu. Zueva, Zubavichus Yan V., Kirillova Marina V., Shul’pina Lidia S., Ikonnikov Nikolay S., Dorovatovskii Pavel V., E. S. Shubina, A. Kirillov, G. B. Shul’pin Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
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Sheng Kai, Wang Ran, A. N. Bilyachenko, Khrustalev Victor, Jagodič Marko, Jagličić Zvonko, Li Zhaoyang, Wang Likai, Tung Chenho, Sun Di Tridecanuclear Gd(III)-silsesquioxane: Synthesis, structure, and magnetic property
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A. N. Bilyachenko, G. S. Astakhov, A. N. Kulakova, Korlyukov Alexander A., Zubavichus Yan V., Dorovatovskii Pavel V., Shul’pina Lidia S., E. S. Shubina, Ikonnikov Nikolay S., Kirillova Marina V., A. Yu. Zueva, A. Kirillov, G. B. Shul’pin Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures
2021
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G. S. Astakhov, Shigaev R.R., Borisova T.N., Ershova A.A., Alexander A. Titov, Varlamov A.V., Voskressensky L.G., Matveeva M.D. Facile synthesis of pyrrolo[2,1-a]isoquinolines by domino reaction of 1-aroyl-3,4-dihydroisoquinolines with conjugated ketones, nitroalkenes and nitriles
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Nigoghossian K., A. N. Kulakova, Félix G., Khrustalev V.N., E. S. Shubina, Long J., Guari Y., Sene S., Carlos L.D., A. N. Bilyachenko, J. Larionova Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
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Novel carbonate/pyridine tetranuclear nickel complex, exhibiting slow relaxation of the magnetization
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New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages
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G. S. Astakhov, M. M. Levitsky, Zubavichus Y. V., Khrustalev Victor N., A. A. Titov, Dorovatovskii Pavel V., Smol’yakov Alexander F., E. S. Shubina, Kirillova Marina V., A. Kirillov, A. N. Bilyachenko Cu6- and Cu8-Cage Sil- and Germsesquioxanes: Synthetic and Structural Features, Oxidative Rearrangements, and Catalytic Activity
2020
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New Luminescent Tetranuclear Lanthanide‐based Silsesquioxane Cage‐like Architectures
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Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
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G. S. Astakhov, A. N. Bilyachenko, M. M. Levitsky, Lidia S. Shulpina, Alexander A. Korlyukov, Yan V. Zubavichus, Victor
N. Khrustalev, Anna V. Vologzhanina, E. S. Shubina, Pavel V.
Dorovatovskii, G. B. Shul’pin Coordination Affinity of Cu(II)-Based Silsesquioxanes toward
N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic
Products Exhibiting a High Catalytic Activity in Oxidation Reactions
2019
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Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
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A. N. Kulakova, E.E.Sedykh, M. M. Levitsky, P.V.Dorovatovskii, V.N.Khrustalev, L.S.Shul'pina, E. S. Shubina, Y.N.Kozlov, N.S.Ikonnikova, A. N. Bilyachenko, G. B. Shul’pin The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
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G. S. Astakhov, M. M. Levitsky, A. A. Korlyukov, L. S. Shul’pina, E. S. Shubina, N. S. Ikonnikov, A. V. Vologzhanina, A. N. Bilyachenko, P. V. Dorovatovskii, Y. N. Kozlov, G. B. Shul’pin New Cu4Na4- and Cu5-Based Phenylsilsesquioxanes. Synthesis via Complexation with 1,10-Phenanthroline, Structures and High Catalytic Activity in Alkane Oxidations with Peroxides in Acetonitrile
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Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes
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Cagelike metallagermanates and metallagermoxanes: Synthesis, structures and functional properties
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A. N. Kulakova, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Xavier Bantreil, Lidia S. Shul'pina, M. M. Levitsky, Nikolay S. Ikonnikov, E. S. Shubina, F. Lamaty, A. N. Bilyachenko, G. B. Shul’pin Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
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Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via
Oxidation of 1,1-bis(Diphenylphosphino)methane),
Structure and Catalytic Activity in Alkane or Alcohol
Oxidation with Peroxides
2018
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A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, A. N. Kulakova, X. Bantreil, F. Lamaty, M. M. Levitsky, E. I. Gutsul, E. S. Shubina, G. B. Shul’pin Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
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Mild and Regioselective Hydroxylation of Methyl Group in Neocuproine: Approach to an N,O-Ligated Cu6 Cage Phenylsilsesquioxane
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A. N. Bilyachenko, A. N. Kulakova, L. S. Shul'pina, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, U. S. Tsareva, E. S. Shubina, A. A. Petrov, N. V. Vorontsov, G. B. Shul’pin Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
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Heptanuclear Cage Cu(II)-Silsesquioxanes. Features of Synthesis, Structure and Catalytic Activity
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High-nuclearity (Cu8-based) cage silsesquioxanes: Synthesis and structural study
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New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
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Tridecanuclear CuII11Na2 cagelike silsesquioxanes
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G. S. Astakhov, A. N. Bilyachenko, A. Korlyukov, M. M. Levitsky, L. Shul'pina, X. Bantreil, F. Lamaty, A. Vologzhanina, E. S. Shubina, P. Dorovatovskii, D. Nesterov, A. Pombeiro, G. B. Shul’pin High cluster (Cu9) cage silsesquioxanes. Synthesis, structure and catalytic activity
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A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
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A. N. Kulakova, A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, G. B. Shul’pin Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity
2017
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Cage-like metallsilsesquioxanes in catalysis: A review
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A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Petrov, Alexander A. Korlyukov, Lidia S. Shul’pina, Victor N. Khrustalev, Pavel V. Dorovatovskii, Anna V. Vologzhanina, Ulyana S. Tsareva, I. E. Golub, E. Gulyaeva, E. S. Shubina, G. B. Shul’pin Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
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A. I. Yalymov, A. N. Bilyachenko, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, L. S. Shul’pina, P. V. Dorovatovskii, M. A. Es’kova, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, E. S. Shubina, Y. N. Kozlov, G. B. Shul’pin High Catalytic Activity of Heterometallic (Fe6Na7 and Fe6Na6) Cage Silsesquioxanes in Oxidations with Peroxides
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Oxidation of C‒H compounds with peroxides catalyzed by polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks
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A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, A. V. Vologzhanina, A. A. Titov, P. V. Dorovatovskii, L. S. Shul’pina, F. Lamaty, X. Bantreil, B. Villemejeanne, C. Ruiz, J. Martinez, E. S. Shubina, G. B. Shul’pin Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
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A. N. Bilyachenko, A. A. Korlyukov, A. V. Vologzhanina, V. N. Khrustalev, A. N. Kulakova, J. Long, J. Larionova, Y. Guari, M. S. Dronova, U. S. Tsareva, P. V. Dorovatovskii, E. S. Shubina, M. M. Levitsky Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
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A. N. Bilyachenko, A. I. Yalymov, M. S. Dronova, Alexander Korlyukov, Anna Vologzhanina, Marina Es’kova, Jérôme Long, J. Larionova, Yannick Guari, Pavel Dorovatovskii, E. S. Shubina, M. M. Levitsky Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties
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A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, A. A. Korlyukov, Y. V. Zubavichus, P. V. Dorovatovskii, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, L. S. Shul’pina, E. S. Shubina, E. I. Gutsul, I. A. Mikhailov, N. S. Ikonnikov, U. S. Tsareva, G. B. Shul’pin Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
2016
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Modern concepts and methods in the chemistry of polyhedral metallasiloxanes
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Unusual penta- and hexanuclear Ni(II)-based silsesquioxane polynuclear complexes
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A. N. Bilyachenko, M. M. Levitsky, A. I. Yalymov, A. Korlyukov, A. Vologzhanina, Yu. Kozlov, L. Shul'pina, D. Nesterov, A. Pombeiro, F. Lamaty, X. Bantreil, A. Fetre, D. Liu, J. Martinez, J. Long, J. Larionova, Y. Guari, A. Trigub, Y. Zubavichus, I. E. Golub, O. A. Filippov, E. S. Shubina, G. B. Shul’pin A Heterometallic (Fe6Na8) Cage-like Silsesquioxane: Synthesis, Structure, Spin Glass Behavior and High Catalytic Activity
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A. N. Bilyachenko, A. I. Yalymov, Shul’pina L.S., Mandelli, D., Korlyukov, A.A., Vologzhanina A.V., Es’kova M.A., E. S. Shubina, M. M. Levitsky, G. B. Shul’pin Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
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A. N. Bilyachenko, A. I. Yalymov, M. M. Levitsky, A. Korlyukov, M. Eskova, J. Long, J. Larionova, Y. Guari, L.S. Shul'pina, N.S. Ikonnikov, A. Trigub, Y.V. Zubavichus, I. E. Golub, E. S. Shubina, G. B. Shul’pin First Cage-Like Pentanuclear Co(II)-Silsesquioxane
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A. N. Bilyachenko, M. M. Levitsky, A. I. Yalymov, A.A. Korlyukov, V.N. Khrustalev, A.V. Vologzhanina, L.S. Shul’pina, N.S. Ikonnikov, A.E. Trigub, P.V. Dorovatovsky, X. Bantreil, F. Lamaty, J. Long, J. Larionova, I. E. Golub, E. S. Shubina, G. B. Shul’pin Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity
2015
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A. N. Bilyachenko, M. S. Dronova, A. I. Yalymov, F. Lamaty, X. Bantreil, J. Martinez, C. Bizet, L. S. Shul'pina, A. A. Korlyukov, D. E. Arkhipov, M. M. Levitsky, E. S. Shubina, A. M. Kirillov, G. B. Shul’pin Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
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Alkane oxidation with peroxides catalyzed by cage-like copper(II) silsesquioxanes
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A. N. Bilyachenko, A. I. Yalymov, A. A. Korlyukov, J. Long, J. Larionova, Y. Guari, Y. V. Zubavichus, A. L. Trigub, E. S. Shubina, I. L. Eremenko, N. N. Efimov, M. M. Levitsky Heterometallic Na6Co3 Phenylsilsesquioxane Exhibiting Slow Dynamic Behavior in its Magnetization
2014
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Solvent-controlled synthesis of tetranuclear cage-like copper(II) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation of benzene and alcohols with peroxides
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Quantum chemical study of the template synthesis of cage-like metallasiloxanes
2013
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New Binuclear Cage-like Copper(II) Silsesquioxane (“Cooling Tower”); Its High Catalytic Activity in Oxidation of Benzene and Alcohols
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Russ. Chem. Bull., 2013, 62, 1941-1943
A new type of supramolecular organization in the cage-like metallasiloxanes
2012
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Russ. Chem. Bull., 2012, 61, 200-203
Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments