Metal-oxo clusters with organoelement and organic ligands

Metal-oxo clusters with organoelement and organic ligands
Cage-like compounds with metal oxo core, bound to heterochained ligands
Study of cage’ self-assembling and rearrangements, especially in the presence of additional organic ligands (“double ligation principle”)
Study of supramolecular assembling of cage compounds
Study of complexes’ structure in solid state (X-ray, XPD, EXAFS) and solution (IR/UV)
Study of cage activity as precatalysts in wide range of processes
Study of cage’ molecular magnetism
Publications
2022
  • ChemPhysMater, 2022, DOI: 10.1016/j.chphma.2022.04.008
    Sheng Kai, Wang Ran, A. N. Bilyachenko, Khrustalev Victor, Jagodič Marko, Jagličić Zvonko, Li Zhaoyang, Wang Likai, Tung Chenho, Sun Di
    Tridecanuclear Gd(III)-silsesquioxane: Synthesis, structure, and magnetic property
  • Crystal Growth and Design, 2022, 22(4), 2146-2157, DOI: 10.1021/acs.cgd.1c01225
    A. N. Bilyachenko, G. S. Astakhov, A. N. Kulakova, Korlyukov Alexander A., Zubavichus Yan V., Dorovatovskii Pavel V., Shul’pina Lidia S., E. S. Shubina, Ikonnikov Nikolay S., Kirillova Marina V., Zueva Anna Y., Kirillov Alexander M., G. B. Shul’pin
    Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures
2021
2020
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2014
2013
2012