Metal-oxo clusters with organoelement and organic ligands
Cage-like compounds with metal oxo core, bound to heterochained ligands
Study of cage’ self-assembling and rearrangements, especially in the presence of additional organic ligands (“double ligation principle”)
Study of supramolecular assembling of cage compounds
Study of complexes’ structure in solid state (X-ray, XPD, EXAFS) and solution (IR/UV)
Study of cage activity as precatalysts in wide range of processes
Study of cage’ molecular magnetism
Study of cage’ self-assembling and rearrangements, especially in the presence of additional organic ligands (“double ligation principle”)
Study of supramolecular assembling of cage compounds
Study of complexes’ structure in solid state (X-ray, XPD, EXAFS) and solution (IR/UV)
Study of cage activity as precatalysts in wide range of processes
Study of cage’ molecular magnetism
Publications
2023
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Cagelike Rb2‑, K2‑, and Na2‑Tetracopper(II) Silsesquioxanes with Quaternary Ammonium Cations: Synthesis, Structures, and Catalytic Activity
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New family of luminescent tetranuclear lanthanide-based germsesquioxanes: luminescence and temperature sensing
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Cagelike octacopper methylsilsesquioxanes: self-assembly in the focus of alkaline metal ion influence—synthesis, structure, and catalytic activity
2022
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Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
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A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity
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Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
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Tridecanuclear Gd(III)-silsesquioxane: Synthesis, structure, and magnetic property
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Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures
2021
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Facile synthesis of pyrrolo[2,1-a]isoquinolines by domino reaction of 1-aroyl-3,4-dihydroisoquinolines with conjugated ketones, nitroalkenes and nitriles
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Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
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Novel carbonate/pyridine tetranuclear nickel complex, exhibiting slow relaxation of the magnetization
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New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages
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Cu6- and Cu8-Cage Sil- and Germsesquioxanes: Synthetic and Structural Features, Oxidative Rearrangements, and Catalytic Activity
2020
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New Luminescent Tetranuclear Lanthanide‐based Silsesquioxane Cage‐like Architectures
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Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
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Coordination Affinity of Cu(II)-Based Silsesquioxanes toward N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic Products Exhibiting a High Catalytic Activity in Oxidation Reactions
2019
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Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
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The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
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New Cu4Na4- and Cu5-Based Phenylsilsesquioxanes. Synthesis via Complexation with 1,10-Phenanthroline, Structures and High Catalytic Activity in Alkane Oxidations with Peroxides in Acetonitrile
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Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes
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Cagelike metallagermanates and metallagermoxanes: Synthesis, structures and functional properties
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Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
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Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides
2018
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Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
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Mild and Regioselective Hydroxylation of Methyl Group in Neocuproine: Approach to an N,O-Ligated Cu6 Cage Phenylsilsesquioxane
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Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
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Heptanuclear Cage Cu(II)-Silsesquioxanes. Features of Synthesis, Structure and Catalytic Activity
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High-nuclearity (Cu8-based) cage silsesquioxanes: Synthesis and structural study
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New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
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Tridecanuclear CuII11Na2 cagelike silsesquioxanes
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High cluster (Cu9) cage silsesquioxanes. Synthesis, structure and catalytic activity
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A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
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Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity
2017
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Journal of Molecular Catalysis A: Chemical, 2017, 426, Part B, 297-304, DOI: 10.1016/j.molcata.2016.06.016Cage-like metallsilsesquioxanes in catalysis: A review
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Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
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High Catalytic Activity of Heterometallic (Fe6Na7 and Fe6Na6) Cage Silsesquioxanes in Oxidations with Peroxides
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Oxidation of C‒H compounds with peroxides catalyzed by polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks
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Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
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Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
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Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties
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Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
2016
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Modern concepts and methods in the chemistry of polyhedral metallasiloxanes
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Unusual penta- and hexanuclear Ni(II)-based silsesquioxane polynuclear complexes
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A Heterometallic (Fe6Na8) Cage-like Silsesquioxane: Synthesis, Structure, Spin Glass Behavior and High Catalytic Activity
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Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
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First Cage-Like Pentanuclear Co(II)-Silsesquioxane
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Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity
2015
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Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
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Alkane oxidation with peroxides catalyzed by cage-like copper(II) silsesquioxanes
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Heterometallic Na6Co3 Phenylsilsesquioxane Exhibiting Slow Dynamic Behavior in its Magnetization
2014
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Solvent-controlled synthesis of tetranuclear cage-like copper(II) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation of benzene and alcohols with peroxides
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Quantum chemical study of the template synthesis of cage-like metallasiloxanes
2013
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New Binuclear Cage-like Copper(II) Silsesquioxane (“Cooling Tower”); Its High Catalytic Activity in Oxidation of Benzene and Alcohols
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Russ. Chem. Bull., 2013, 62, 1941-1943A new type of supramolecular organization in the cage-like metallasiloxanes
2012
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Russ. Chem. Bull., 2012, 61, 200-203Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments