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Elena S. Shubina
Head of the Laboratory
Personal Info
Address
A.N.Nesmeyanov Institute of Organoelement Compounds (INEOS)
Russian Academy of Sciences, Vavilov St. 28, Moscow, 119991, Russia
Russian Academy of Sciences, Vavilov St. 28, Moscow, 119991, Russia
Phone
+7 (499) 135-18-71
Email
Academic Degree
Ph.D. in Chemistry, Moscow State University (1982)
D. Sc. in Chemistry, INEOS RAS (1997)
Prof. Physical Chemistry (2006)
D. Sc. in Chemistry, INEOS RAS (1997)
Prof. Physical Chemistry (2006)
Experience
1969-1974 - M.V.Lomonosov Moscow State University, Chemistry Department
1978-1982 - Postgraduate course at Moscow State University
1974-1978 - junior researcher, Moscow Institute of Petrochemical and Gas Industry
1982-1986 - junior research scientist, INEOS RAS
1986-1991 - research scientist, INEOS RAS
1991-1998 - senior research scientist, INEOS RAS
1998-2001 - leading research scientist, INEOS RAS
2001-2003 - leading researcher, Head of the Group of Metal Hydrides
2004 - present time - Head of the Laboratory of Metal Hydrides, INEOS RAS
1978-1982 - Postgraduate course at Moscow State University
1974-1978 - junior researcher, Moscow Institute of Petrochemical and Gas Industry
1982-1986 - junior research scientist, INEOS RAS
1986-1991 - research scientist, INEOS RAS
1991-1998 - senior research scientist, INEOS RAS
1998-2001 - leading research scientist, INEOS RAS
2001-2003 - leading researcher, Head of the Group of Metal Hydrides
2004 - present time - Head of the Laboratory of Metal Hydrides, INEOS RAS
Scientific Interests
Organometallic, Inorganic, Physical chemistry; molecular spectroscopy; structure and reactivity of transition metal hydride complexes and main group hydrides; intermolecular interactions; hydrogen bonding and proton transfer in organometallic chemistry; supramolecular design based on macrocyclic pyrazolates of copper(I) or silver(I) and metal-oxo clusters with organoelement and organic ligands
Awards
Three new types of intermolecular hydrogen bonds typical for organometallic compounds have been comprehensively explored: hydrogen bonds to transition metal atom as proton acceptor, to hydride ligand as proton acceptor and with hydride ligand as proton donor. Approaches to mechanistic studies of proton transfer reactions of transition metal and main group element hydrides have been developed. Their application allowed showing a guiding role of various unusual hydrogen bonds that determine the proton transfer pathway and the reaction selectivity. Relationship between the thermodynamic and kinetic parameters of each reaction step and peculiarities of potential energy profiles have been deduced.
Additional
over 150 Papers in peer-review journals including 3 book chapters: “Dihydrogen bonded complexes and proton transfer to hydride ligand by spectral (IR, NMR) studies” in Recent Advances in Hydride Chemistry, Elsevier Science, 2001; “Weak Interactions and M-H Bond Activation” in Advances in Organometallic Chemistry: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book, First Edition. Ed.: A. J. L. Pombeiro. John Willey & Sons, Inc., 2014, chapt. 8, 97-109; “IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies” in Spectrosc. Prop. Inorg. Organomet. Compd., 2012, 43, 1–28
Supervisor of 10 Ph. D. Thesis
Invited Lecturer:
Lecturer at Universities of Germany, India, Japan, France, Portugal, Spain, Italy in 1995-2014.
Visiting Professor at Université de Bourgogne, Dijon in 2001–2004 and Toulouse 2012
Plenary, Invited or Keynote lecturer at XIII FECHEM Conference on Organometallic Chemistry 1999; 12th International Conference on Boron Chemistry 2005; Japan, International Conference “From molecules towards materials”, Russia, 2005; International Conference on Cluster Chemistry and Polynuclear Compounds, Russia 2006, XVII EuCheMS Conference on Organometallic Chemistry, Sofia, Bulgaria 2007,. XIII IMEBORON, Barcelone, Spain, 2008, XIV IMEBORON, Canada, 2011, International Conference on Organometallic and Coordination Chemistry, N. Novgorod, Russia, 2008, 2010, 2013, 2015, International Conference on Hydrogen and Hydrogen Storage: Methods and Materials, January, 2009, Bangalore, India, XXV ICOMC Portugal 2012, 79th Annual Meeting of the Israeli Chemical Society 2014; International Conference on Coordination Chemistry ICCC-41, Singapore, 2014, International Symposium on “New Horizons in Chemistry” and Interdisciplinary Symposium on Material Chemistry, Mumbai, India, 2014.
Total over 100 Communications at International scientific meetings
International and National Activity:- Russian representative in the EuCheMS Division on Organometallic Chemistry since 2007
- Member of the Organizing Committees of International conferences on Organometallic Chemistry held in Russia since 1993
- Organizer of Franco-Russian seminars “Homogeneous catalysis for the sustainable development” 2009, 2012, 2015
- Russian Coordinator of the 3 bilateral Projects between CNR (Rome) and the Russian Academy of Sciences (Moscow) in 2008-2009; 2010-2011; 2012-2013
- Russian Coordinator of bilateral RFBR - CNRS Projects (PICS) in 2005-2007
- Russian Coordinator of International research group (GDRI) “Homogeneous catalysis for the sustainable development” (France, Italy, Russia) 2008-2015
- Russian Coordinator of RFBR (Russia)- CNR (Italy) research project 2015-2017
- Responsible of 8 RFBR projects since 1995
- Referee of the following international journals: Journal of the American Chemical Society; Coordination Chemistry Reviews; Chemistry – the European Journal; Chemical Communications; Organometallics; Dalton Transactions; Inorganic Chemistry; European Journal of Inorganic Chemistry; Journal of Organometallic Chemistry; Journal of Molecular Structure; Inorganica Chimica Acta; Inorganic Chemistry Communications; Journal of the Physical Chemistry.
Publications
2024
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An ionic Cu9Na4-phenylsilsesquioxane/bis(triphenylphosphine)iminium complex: synthesis, unique structure, and catalytic activity
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Rational (supra)molecular design and catalytic activity of cagelike Cu4-based phenylsilsesquioxanes
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Russian Journal of Coordination Chemistry, 2024, 50(5), 316-325Isonitrile Coordination to Pincer Iridium Hydrido Chlorides
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Electrocatalytic Radical Degradation of 2-Aminoethanol by Nickel, Palladium and Platinum Complexes Bearing Non-Innocent Diarylamido/bis(Phosphine) Pincer Ligand
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Substituents’ Effect on the Photophysics of Trinuclear Copper(I) and Silver(I) Pyrazolate–Phosphine Cages
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Synergism of primary and secondary interactions in a crystalline hydrogen peroxide complex with tin
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A family of hexacopper phenylsilsesquioxane/acetate complexes: synthesis, solvent‐controlled cage structures, and catalytic activity
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Luminescent Ln3+-based silsesquioxanes with a β-diketonate antenna ligand: toward the design of efficient temperature sensors
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Stepwise carbon dioxide hydrosylilation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(But PCP)]
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Electrochemical generation and in situ EPR- and UV–vis- observation of aminyl-radical diarylamido/bis(phosphine) pincer complexes of Ni, Pd and Pt
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Fe(III)-Based Phenylsilsesquioxane/Acetylacetonate Complexes: Synthesis, Cage-like Structure, and High Catalytic Activity
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Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation
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Pyrazolate vs phenylethynide: direct exchange of anionic bridging ligand in cyclic trinuclear silver complex
2023
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Tetranuclear lanthanide-based silsesquioxanes: towards a combination of a slow relaxation of the magnetization and a luminescent thermometry
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Cage-like Cu5Cs4-phenylsilsesquioxanes: synthesis, supramolecular structures, and catalytic activity
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A Family of сagelike Mn-silsesquioxane/bathophenanthroline complexes: synthesis, structure, and catalytic and antifungal activity
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Cagelike manganesesilsesquioxane complexes: synthesis via an acetone approach, structure, and catalytic activity for toluene oxidation
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Role of Non-Covalent Interactions in the Reactions between Palladium Hydrido Complex with Amidoarylphosphine Pincer Ligand and Brønsted Acids
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Reactivity of heterobimetallic ion pairs in formic acid dehydrogenation
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The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes
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Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex
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Cagelike Rb2‑, K2‑, and Na2‑Tetracopper(II) Silsesquioxanes with Quaternary Ammonium Cations: Synthesis, Structures, and Catalytic Activity
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New family of luminescent tetranuclear lanthanide-based germsesquioxanes: luminescence and temperature sensing
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Tetranuclear Copper(I) and Silver(I) Pyrazolate Adducts with 1,1$\prime$-Dimethyl-2,2’-bibenzimidazole: Influence of Structure on Photophysics
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Cagelike octacopper methylsilsesquioxanes: self-assembly in the focus of alkaline metal ion influence—synthesis, structure, and catalytic activity
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Activation of dinitrogen by group 6 metal complexes
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Basicity and hydride-donating ability of palladium(II) hydride complex with diarylamido-bis-phosphine pincer ligand
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Functional pyrazolylpyridine ligands in the design of metal complexes with tunable properties
2022
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Hybrid Silsesquioxane/Benzoate Cu7-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity
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Emissive Silver(I) Cyclic Trinuclear Complexes with Aromatic Amine Donor Pyrazolate Derivatives: Way to Efficiency
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Halogen or Arene: Complexation of 4,4'-Dibromobiphenyl with a Three-Membered Silver(I) Macrocycle
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Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
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A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity
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Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
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The role of weak intermolecular interactions in photophysical behavior of isocoumarins on the example of their interaction with cyclic trinuclear silver(I) pyrazolate
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Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(Ph2PCH2PPh2)Mn(CO)3H]
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Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures
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Amine-boranes reactions promoted by lanthanide(ii) ions
2021
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Nickel(II) dihydrogen and hydride complexes as the intermediates of H2 heterolytic splitting by nickel diazadiphosphacyclooctane complexes
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Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
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Mononuclear copper(I) 3-(2-pyridyl)pyrazole complexes: the crucial role of phosphine on photoluminescence
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The mechanism of halogenation of decahydro-closo-decaborate dianion by hydrogen chloride
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The reaction of hydrogen halides with tetrahydroborate anion and hexahydro-closo-hexaborate dianion
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New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages
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Cu6- and Cu8-Cage Sil- and Germsesquioxanes: Synthetic and Structural Features, Oxidative Rearrangements, and Catalytic Activity
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New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2'-bipyridine
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Iinfluence of phosphine (pincer) ligands on the transition metal hydrides reactivity
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Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
2020
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Regioselective Isomerization of Terminal Alkenes Catalyzed by a PC(sp3)P Pincer Complex with a Hemilabile Pendant Arm
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Dinuclear Silver(I) Nitrate Complexes with Bridging Bisphosphinomethanes: Argentophilicity and Luminescence
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Dichotomous Si–H Bond Activation by Alkoxide and Alcohol in Base-Catalyzed Dehydrocoupling of Silanes
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New Luminescent Tetranuclear Lanthanide‐based Silsesquioxane Cage‐like Architectures
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Steric and Electronic Effect of Cp-Substituents on the Structure of the Ruthenocene Based Pincer Palladium Borohydrides
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Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
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Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
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Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes
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Mechanistic Study in Azide-Alkyne Cycloaddition (CuAAC) Catalyzed by Bifunctional Trinuclear Copper(I) Pyrazolate Complex: Shift in Rate-Determining Step
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Stereoisomerism as an Origin of Different Reactivity of Ir(III) PC(sp3)P Pincer Catalysts
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Coordination Affinity of Cu(II)-Based Silsesquioxanes toward N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic Products Exhibiting a High Catalytic Activity in Oxidation Reactions
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Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation
2019
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Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
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Luminescent AgI Complexes with 2,2′-Bipyridine Derivatives Featuring [Ag-(CF3)2Pyrazolate]4 Units
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Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
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The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
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New Cu4Na4- and Cu5-Based Phenylsilsesquioxanes. Synthesis via Complexation with 1,10-Phenanthroline, Structures and High Catalytic Activity in Alkane Oxidations with Peroxides in Acetonitrile
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Magnetic cage-like metallasilsesquioxanes
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Synthesis, Structural Properties and Reactivity of Ruthenocene-based Pincer Pd(II) Tetrahydroborate
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Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane
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Syntheses, Structures and Luminescence of multinuclear Silver(I) pyrazolate adducts with 1, 10-Phenanthroline derivatives
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Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes
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Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes
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Cagelike metallagermanates and metallagermoxanes: Synthesis, structures and functional properties
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Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes
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Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
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Interaction of a trinuclear copper(I) pyrazolate with alkynes and carbon–carbon triple bond activation
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Dinuclear Cu(I) and Ag(I) pyrazolates supported with tertiary phosphines: Synthesis, structures and photophysical properties
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Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides
2018
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Macrocyclic Copper(I) and Silver(I) Pyrazolates: Principles of Supramolecular Assemblies with Lewis Bases
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Ruthenium p-cymene iminophosphonamide complexes: activation under basic conditions and transfer hydrogenation catalysis
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Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
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Mild and Regioselective Hydroxylation of Methyl Group in Neocuproine: Approach to an N,O-Ligated Cu6 Cage Phenylsilsesquioxane
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Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
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Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N2)2(dppe)2
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Z-H bond activation in (di)hydrogen bonding as a way to proton/hydride transfer and H2 evolution
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Heptanuclear Cage Cu(II)-Silsesquioxanes. Features of Synthesis, Structure and Catalytic Activity
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High-nuclearity (Cu8-based) cage silsesquioxanes: Synthesis and structural study
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Hydride donating abilities of the tetracoordinated boron hydrides
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New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
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Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis-(trifluoromethyl)pyrazolates
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Tridecanuclear CuII11Na2 cagelike silsesquioxanes
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High cluster (Cu9) cage silsesquioxanes. Synthesis, structure and catalytic activity
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Comprehensive Insight into Hydrogen Bonding of Silanes
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Amido Ca(II) complexes supported by Schiff base ligands for catalytic cross-dehydrogenative coupling of amines with silanes
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Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance
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A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
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Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity
2017
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Catalytic Redox Isomerization of Allylic Alcohols with Rhodium and Iridium Complexes with Ferrocene Phosphine-Thioether Ligands
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Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
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High Catalytic Activity of Heterometallic (Fe6Na7 and Fe6Na6) Cage Silsesquioxanes in Oxidations with Peroxides
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Mechanism of Dimethylamine–Borane Dehydrogenation Catalyzed by an Iridium(III) PCP-Pincer Complex
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Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
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Ammonia Borane Dehydrogenation Catalyzed by (κ4‑EP3)Co(H) [EP3 = E(CH2CH2PPh2)3; E = N, P] and H2 Evolution from Their Interaction with NH Acids
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Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
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Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
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Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ3-P-CH3C(CH2CH2PPh2)3}RuH(η2-BH4)]
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Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties
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Coordinatively labile 18-electron arene ruthenium iminophosphonamide complexes
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Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
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Supramolecular design of the trinuclear silver(I) and copper(I) metal pyrazolates complexes with ruthenium sandwich compounds via intermolecular metal-π interactions
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Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
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Ferrocenecontaining tri and tetranuclear cyclic copper(I) and silver(I) pyrazolates
2016
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Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides
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Unusual penta- and hexanuclear Ni(II)-based silsesquioxane polynuclear complexes
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Dihydrogen Bonding and Proton Transfer from MH vs OH acids to Group 10 Metal Hydrides (tBuPCP)MH [tBuPCP = 3-2,6-(tBu2PCH2)2C6H3; M = Ni, Pd]
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A Heterometallic (Fe6Na8) Cage-like Silsesquioxane: Synthesis, Structure, Spin Glass Behavior and High Catalytic Activity
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Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]
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Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
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First Cage-Like Pentanuclear Co(II)-Silsesquioxane
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The Role of Weak Interactions in Strong Intermolecular M•••Cl Complexes of Coinage Metal Pyrazolates: Spectroscopic and DFT Study
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Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity
2015
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Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene
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Dihydrogen Bond Intermediated Alcoholysis of Dimethylamine-Borane in Non-Aqueous Media
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Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
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Heterometallic Na6Co3 Phenylsilsesquioxane Exhibiting Slow Dynamic Behavior in its Magnetization
2014
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Advances in Organometallic Chemistry, 2014, First Edition. Ed.: A. J. L. Pombeiro. John Willey & Sons, Inc. chapt. 8, 97-109. (book chapter)The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book. Weak Interactions and M-H Bond Activation
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Dihydrogen bonding in complex (PP3)RuH(η1-BH4) featuring two proton-accepting hydride sites: experimental and theoretical studies
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Role of basic sites of substituted ferrocenes in interaction with the trinuclear 3,5-bis(trifluoromethyl)pyrazolates: thermodynamics and structure of complexes
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Solvent-controlled synthesis of tetranuclear cage-like copper(II) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation of benzene and alcohols with peroxides
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Conformational Flexibility of Dibenzobarrelene-Based PC(sp3)P Pincer Iridium Hydride Complexes: The Role of Hemilabile Functional Groups and External Coordinating Solvents
2013
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Chemistry of boron hydrides orchestrated by dihydrogen bonds
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Z. Phys. Chem., 2013, 227, 69–88First Example of Hydrogen Bonding to Platinum Hydride
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Ligand–Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation
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Hydrogen bonding and proton transfer to ruthenium hydride complex CpRuH(dppe): metal and hydride dichotomy.
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Activation of a (cyclooctadiene) rhodium(I) complex supported by a chiral ferrocenyl phosphine thioether ligand for hydrogenation catalysis: a combined parahydrogen NMR and DFT study
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Russ. Chem. Bull., 2013, 62, 751-757Iridium and rhodium complexes with the planar chiral thioether ligands in asymmetric hydrogenation of ketones and imines
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New Binuclear Cage-like Copper(II) Silsesquioxane (“Cooling Tower”); Its High Catalytic Activity in Oxidation of Benzene and Alcohols
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Russ. Chem. Bull., 2013, 62, 1941-1943A new type of supramolecular organization in the cage-like metallasiloxanes
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Russ. Chem. Bull., 2013, 62, 1829-1834Complexation of trimeric copper(I) and silver(I) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane
2012
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Spectrosc. Prop. Inorg. Organomet. Compd., 2012, 43, 1–28 (book chapter)IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies
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ChemPhysChem, 2012, 13, 2677Directionality of Dihydrogen Bonds: The Role of Transition Metal Atoms
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Comput Theor Chem, 2012, 998, 129-140Hydrogen–deuterium exchange in hydride chemistry: Dihydrogen bonded complexes as key intermediates
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Inorg. Chem., 2012, 51, 6486-6497Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond
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Eur. J. Inorg. Chem., 2012, 5554–5561Complexes of Trinuclear Macrocyclic Copper(I) and Silver(I) 3,5- Bis(Trifluoromethyl)Pyrazolates with Ketones
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Russ. Chem. Bull., 2012, 61, 200-203Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments
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Dalton Trans., 2012, 41, 11849-11859Coordination chemistry of diphenylphosphinoferrocenylthioethers on cyclooctadiene and norbornadiene rhodium(I) platforms
2011
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J. Organomet. Chem., 2011, 696, 1174-1183Modeling the platinum-catalyzed intermolecular hydroamination of ethylene: the nucleophilic addition of HNEt2 to coordinated ethylene in trans-PtBr2(C2H4)(HNEt2)
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Angew. Chem. Int. Ed., 2011, 50, 1367–1370Acid-base interaction between transition metal hydrides results in dihydrogen bonding and assists H2 evolution
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Inorg. Chem., 2011, 50, 3325-3331Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds
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Inorg. Chem., 2011, 50, 444-450Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion
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Inorg. Chem., 2011, 50, 12539-52Coordination and Organometallic Chemistry of Relevance to the Rhodium-Based Catalyst for Ethylene Hydroamination