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Alexey N. Bilyachenko

Leading researcher
Alexey N. Bilyachenko
Personal Info
Phone
+7-499-135-93-69
Email
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Academic Degree
D.Sc. (Chem.), RUDN University, 2020.
Ph. D. (Chem.), A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 2006.
M. Sc., summa cum laude, Moscow State University of Fine Chemical Technologies, 2002.
Experience
2021 - present - Leading Researcher, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; In parallel - Associate professor, Department of Inorganic Chemistry, Faculty of science, RUDN University; Leading Researcher, Research Institute of Chemistry, RUDN University.
2017 – 2020 – Deputy Director, Research Institute of Chemistry, RUDN University.
2010 - 2017 - Senior Researcher, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
2002 - 2010 - Researcher, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
2002 - 2006 - Post-graduate student, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.
Scientific Interests
Cagelike metallacomplexes and coordination polymers; sesquioxane ligands; complexation reactions; catalysis; molecular magnetism; photophysical properties.
Awards
Laureate of the RUDN University Prize in Science and Innovation, 2019 (with Prof. V.N. Khrustalev).
1st prize at Scientific Conference-Competition at the Semenov Institute of Chemical Physics, Russian Academy of Sciences, 2016 (with L.S. Shul’pina, Dr. Y.N. Kozlov and Prof. G.B. Shul’pin). Scholarships of the President of the Russian Federation for young scientists-candidates in science, 2007-2008, 2011-2012.
Scholarship of Ballard Foundation (http://www.polechimie-balard.fr), 2014, Visiting Professor at Institut Charles Gerhardt, University of Montpellier 2, France
Additional
Visiting professor and foreign laboratories: 2009 - Poland, Lodz, The Centre of Molecular and Macromolecular Studies of the Polish Academy of Sciences (supported by K.I. Zamaraev foundation http://zam.catalysis.ru/),
2013 - France, Montpellier, Institut des Biomolécules Max Mousseron (IBMM), University of Montpellier 2 (supported by CNRS and French Embassy in Moscow),
2014 - France, Montpellier, Institut Charles Gerhardt, University of Montpellier 2 (supported by Ballard Foundation http://www.polechimie-balard.fr/),
2015 - France, Toulouse, Laboratory of Coordination Chemistry CNRS (supported by French Embassy in Moscow, Programme André Mazon http://www.ambafrance-ru.org/Lancement-du-programme-Andre-Mazon)

> 70 papers in Russian and international scientific journals (H index = 24);

Two books (both with Dr. M.M. Levitsky and Prof. V.N. Khrustalev):
“Metallasiloxanes. Modern concepts and methods”, 2018, ISBN 978-5-209-08779-3, RUDN University;
“Metal oxide clusters in organoelement matrices”, 2020, ISBN 978-5-209-09905-5, RUDN University,
Chapter: Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes (Alexey N Bilyachenko, Nuno Reis Conceição, M Fátima C Guedes da Silva, Kamran T Mahmudov, Georgiy B Shul'pin, Armando J L Pombeiro) in Series on Chemistry, Energy and the Environment (Synthesis and Applications in Chemistry and Materials) https://doi.org/10.1142/13309

15+ oral presentations at International chemical meetings

Project head of scientific (RSF, RUDN, RFBR and RFBR-CNRS) projects.
Publications
2024
  • Inorg. Chem., 2024, DOI: 10.1021/acs.inorgchem.4c01748
    Shen Qi, Sheng Kai, Gao Zhi-Yong, A. N. Bilyachenko, Huang Xian-Qiang, Azam Mohammad, Tung Chen-Ho, Sun Di.
    Vanadium-Silsesquioxane Nanocages as Heterogeneous Catalysts for Synthesis of Quinazolinones
  • Chem. Eur. J., 2024, e202401164, DOI: 10.1002/chem.202401164
    A. Yu. Zueva, A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., Dorovatovskii Pavel V., Shul’pina Lidia S., Ikonnikov Nikolay S., E. I. Gutsul, Rahimov Karim G., E. S. Shubina, Conceição Nuno Reis, Mahmudov Kamran T., Guedes da Silva M.Fátima C, Pombeiro Armando J.L.
    A family of hexacopper phenylsilsesquioxane/acetate complexes: synthesis, solvent‐controlled cage structures, and catalytic activity
  • Front. Chem., 2024, 12:1379587, DOI: 10.3389/fchem.2024.1379587
    Gautier Félix, A. N. Kulakova, Saad Sene, Victor N. Khrustalev, Miguel A. Hernández-Rodríguez, E. S. Shubina, Tristan Pelluau, Luís D. Carlos, Yannick Guari, Albano N. Carneiro Neto, A. N. Bilyachenko, J. Larionova
    Luminescent Ln3+-based silsesquioxanes with a β-diketonate antenna ligand: toward the design of efficient temperature sensors
  • Synthesis and Applications in Chemistry and Materials, 2024, 11, 245-279, DOI: 10.1142/9789811283208_0008
    A. N. Bilyachenko, Nuno Reis Conceição, M Fátima C Guedes da Silva, Kamran T. Mahmudov, G. B. Shul’pin, and Armando J. L. Pombeiro
    Chapter 8 in book: Synthesis, Structure and Catalytic Application of Cage Metallasilsesquioxanes
  • Inorg. Chem., 2024, 63(4), 1909–1918, DOI: 10.1021/acs.inorgchem.3c03587
    A. N. Bilyachenko, Khrustalev Victor N., Dorovatovskii Pavel V., Shul’pina Lidia S., Ikonnikov Nikolay S., E. S. Shubina, Lobanov Nikolai N., Aliyeva Vusala A., Nunes Ana V.M., Mahmudov Kamran T., Kozlov Yuriy N., Pombeiro Armando J.L.
    Fe(III)-Based Phenylsilsesquioxane/Acetylacetonate Complexes: Synthesis, Cage-like Structure, and High Catalytic Activity
2023
  • RSC Adv., 2023, 13(37), 26302-26312, DOI: 10.1039/D3RA04901A
    Félix Gautier, Sene Saad, A. N. Kulakova, A. N. Bilyachenko, Khrustalev Victor N., E. S. Shubina, Guari Yannick, J. Larionova
    Tetranuclear lanthanide-based silsesquioxanes: towards a combination of a slow relaxation of the magnetization and a luminescent thermometry
  • Inorg. Chem., 2023, 62(33), 13573-13586, DOI: 10.1021/acs.inorgchem.3c01989
    A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., Shul’pina Lidia S., Korlyukov Alexander A., Ikonnikov Nikolay S., E. S. Shubina, Kozlov Yuriy N., Conceição Nuno Reis, Guedes da Silva M.Fátima C, Mahmudov Kamran T., Pombeiro Armando J.L.
    Cage-like Cu5Cs4-phenylsilsesquioxanes: synthesis, supramolecular structures, and catalytic activity
  • Inorg. Chem., 2023, 62(38), 15537-15549, DOI: 10.1021/acs.inorgchem.3c02040
    A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., Chusova Olga, Dorovatovskii Pavel V., Aliyeva Vusala A., Paninho Ana B., Nunes Ana V.M., Mahmudov Kamran T., E. S. Shubina, Pombeiro Armando J.L
    A Family of сagelike Mn-silsesquioxane/bathophenanthroline complexes: synthesis, structure, and catalytic and antifungal activity
  • Crystal Growth and Design, 2023, 23(12), 8707–8717, DOI: 10.1021/acs.cgd.3c00863
    A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., Dorovatovskii Pavel V., E. S. Shubina, Guari Yannick, Félix Gautier, J. Larionova, Mahmoud Abdallah G., Pombeiro Armando J.L
    Cagelike manganesesilsesquioxane complexes: synthesis via an acetone approach, structure, and catalytic activity for toluene oxidation
  • Organometallics, 2023, 42(18), 2577–2589, DOI: 10.1021/acs.organomet.2c00649
    A. N. Bilyachenko, Victor N. Khrustalev, G. S. Astakhov, A. Yu. Zueva, Arteev I. S., Yan V. Zubavichus, Alexander A. Korlyukov, Pavel V. Dorovatovskii, Lidia S. Shul’pina, Nikolay S. Ikonnikov, Marina V. Kirillova, E. S. Shubina, * Yuriy N. Kozlov, A. Kirillov, G. B. Shul’pin
    Cagelike Rb2‑, K2‑, and Na2‑Tetracopper(II) Silsesquioxanes with Quaternary Ammonium Cations: Synthesis, Structures, and Catalytic Activity
  • Organometallics, 2023, 42(18), 2613–2622, DOI: 10.1021/acs.organomet.3c00009
    Félix G., A. N. Kulakova, Sene S., Charlot C., A. N. Bilyachenko, Korlyukov A.A., Volodin A.D., E. S. Shubina, Elizbarian I. G. , Guari Y., J. Larionova
    New family of luminescent tetranuclear lanthanide-based germsesquioxanes: luminescence and temperature sensing
  • Molecules, 2023, 28(3), 1211, DOI: 10.3390/molecules28031211
    A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., A. Yu. Zueva, Shul’pina Lidia S., E. S. Shubina, Ikonnikov Nikolay S., G. B. Shul’pin
    Cagelike octacopper methylsilsesquioxanes: self-assembly in the focus of alkaline metal ion influence—synthesis, structure, and catalytic activity
2022
2021
2020
2019
2018
2017
2016
2015
2014
2013
2012
  • Eur. J. Inorg. Chem., 2012, 5554–5561
    A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A.F. Smol’yakov, F.M. Dolgushin, V.K. Belsky, I.A. Godovikov, L. M. Epstein, E. S. Shubina
    Complexes of Trinuclear Macrocyclic Copper(I) and Silver(I) 3,5- Bis(Trifluoromethyl)Pyrazolates with Ketones
  • Russ. Chem. Bull., 2012, 61, 200-203
    M. M. Levitsky, A. N. Bilyachenko, M. S. Dronova, A.I. Dmitriev, R.B. Morgunov, E. S. Shubina, A.D. Kirilin
    Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments
2011
  • Inorg. Chem., 2011, 50, 3325-3331
    V. N.Tsupreva, A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A. F.Smol'yakov, F. M. Dolgushin, D. V. Agapkin, I. A. Godovikov, L. M. Epstein, E. S. Shubina
    Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds