MH-Lab | Alexey N. Bilyachenko

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Alexey N. Bilyachenko

Alexey N. Bilyachenko

Senior researcher

Personal Info

Phone

+7-499-135-93-69

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Academic Degree

PhD

Experience

Master degree (2002, Lomonosov Moscow University of Fine Chemical Technology); PhD degree (2006, INEOS RAS); 2006 – 2010: Research Fellow of INEOS RAS; 2010 – present: Senior Research Fellow

Scientific Interests

Cage compounds of transition metals; heterocycles; complexation reactions; supramolecular aggregation; catalysis; molecular magnetism

Additional

Visiting professor and foreign laboratories: 2009 - Poland, Lodz, The Centre of Molecular and Macromolecular Studies of the Polish Academy of Sciences (supported by K.I. Zamaraev foundation http://zam.catalysis.ru/),
2013 - France, Montpellier, Institut des Biomolécules Max Mousseron (IBMM), University of Montpellier 2 (supported by CNRS and French Embassy in Moscow)
2014 - France, Montpellier, Institut Charles Gerhardt, University of Montpellier 2 (supported by Ballard Foundation http://www.polechimie-balard.fr/)
2015 - France, Toulouse, Laboratory of Coordination Chemistry CNRS (supported by French Embassy in Moscow, Programme André Mazon http://www.ambafrance-ru.org/Lancement-du-programme-Andre-Mazon)

Publications

2020

Chem. A Eur. J., 2020, DOI: 10.1002/chem.202003351
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, Khrustalev V., E. S. Shubina, Felix G., Mamontova E., Long J., Guari Y., J. Larionova
New Luminescent Tetranuclear Lanthanide‐based Silsesquioxane Cage‐like Architectures
J. Organomet. Chem., 2020, 906, DOI: 10.1016/j.jorganchem.2019.121022
G. S. Astakhov, M. M. Levitsky, Bantreil X., F. Lamaty, Khrustalev V.N., Zubavichus Y.V., Dorovatovskii P.V., E. S. Shubina, A. N. Bilyachenko
Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
Inorg. Chem., 2020, 59(7) , 4536–4545, DOI: 10.1021/acs.inorgchem.9b03680
G. S. Astakhov, A. N. Bilyachenko, M. M. Levitsky, Lidia S. Shulpina, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Anna V. Vologzhanina, E. S. Shubina, Pavel V. Dorovatovskii, G. B. Shul’pin
Coordination Affinity of Cu(II)-Based Silsesquioxanes toward N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic Products Exhibiting a High Catalytic Activity in Oxidation Reactions

2019

J. Organomet. Chem., 2019, DOI: 10.1016/j.jorganchem.2019.121022
G. S. Astakhov, M. M. Levitsky, X. Bantreil, F. Lamaty, V.N. Khrustalev, Y.V. Zubavichus, P.V. Dorovatovskii, E. S. Shubina, A. N. Bilyachenko
Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
J. Organomet. Chem., 2019, 899, DOI: 10.1016/j.jorganchem.2019.120911
A. N. Kulakova, E.E.Sedykh, M. M. Levitsky, P.V.Dorovatovskii, V.N.Khrustalev, L.S.Shul'pina, E. S. Shubina, Y.N.Kozlov, N.S.Ikonnikova, A. N. Bilyachenko, G. B. Shul’pin
The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
Catalysts, 2019, 9(9), 701-719, DOI: 10.3390/catal9090701
G. S. Astakhov, M. M. Levitsky, A. A. Korlyukov, L. S. Shul’pina, E. S. Shubina, N. S. Ikonnikov, A. V. Vologzhanina, A. N. Bilyachenko, P. V. Dorovatovskii, Y. N. Kozlov, G. B. Shul’pin
New Cu4Na4- and Cu5-Based Phenylsilsesquioxanes. Synthesis via Complexation with 1,10-Phenanthroline, Structures and High Catalytic Activity in Alkane Oxidations with Peroxides in Acetonitrile
Coord. Chem. Rev., 2019, 398, 213015, DOI: 10.1016/j.ccr.2019.213015
M. M. Levitsky, A. N. Bilyachenko, E. S. Shubina, J.Long, Y.Guari, J. Larionova
Magnetic cage-like metallasilsesquioxanes
J. Clust. Sci., 2019, DOI: 10.1007/s10876-019-01567-y
M. M. Levitsky, Y.V. Zubavichus, A.A. Korlyukov, V. N. Khrustalev, E. S. Shubina, A. N. Bilyachenko
Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes
Coord. Chem. Rev., 2019, 386, 209-239, DOI: 10.1016/j.ccr.2019.02.007
M. M. Levitsky, A. N. Bilyachenko, E. S. Shubina
Cagelike metallagermanates and metallagermoxanes: Synthesis, structures and functional properties
Eur. J. Inorg. Chem., 2019, DOI: 10.1002/ejic.201801486
Shirel Cohen, A. N. Bilyachenko, D. Gelman
Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactions
J. Organomet. Chem., 2019, 884, 17-28, DOI: 10.1016/j.jorganchem.2019.01.004
A. N. Kulakova, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Xavier Bantreil, Lidia S. Shul'pina, M. M. Levitsky, Nikolay S. Ikonnikov, E. S. Shubina, F. Lamaty, A. N. Bilyachenko, G. B. Shul’pin
Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
Catalysts, 2019, 9, 154, DOI: 10.3390/catal9020154
A. N. Kulakova, V.N. Khrustalev, Y.V. Zubavichus, L.S. Shul’pina, E. S. Shubina, M. M. Levitsky, N.S. Ikonnikov, A. N. Bilyachenko, Y.N. Kozlov, G. B. Shul’pin
Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides

2018

Inorg. Chem., 2018, 57 (1), 528–534, DOI: 10.1021/acs.inorgchem.7b02881
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, A. N. Kulakova, X. Bantreil, F. Lamaty, M. M. Levitsky, E. I. Gutsul, E. S. Shubina, G. B. Shul’pin
Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
Organometallics, 2018, 37 (2), 168–171, DOI: 10.1021/acs.organomet.7b00845
A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, E. S. Shubina, G. B. Shul’pin
Mild and Regioselective Hydroxylation of Methyl Group in Neocuproine: Approach to an N,O-Ligated Cu6 Cage Phenylsilsesquioxane
J. Organomet. Chem., 2018, 867, 133-141, DOI: 10.1016/j.jorganchem.2017.10.033
A. N. Bilyachenko, A. N. Kulakova, L. S. Shul'pina, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, U. S. Tsareva, E. S. Shubina, A. A. Petrov, N. V. Vorontsov, G. B. Shul’pin
Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
Eur. J. Inorg. Chem., 2018, 22, 2505-2511, DOI: 10.1002/ejic.201701340
A. N. Bilyachenko, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, E. S. Shubina, A. V. Vologzhanina, G. B. Shul’pin
Heptanuclear Cage Cu(II)-Silsesquioxanes. Features of Synthesis, Structure and Catalytic Activity
Crystal Growth and Design, 2018, 18 (4), 2452–2457, DOI: 10.1021/acs.cgd.8b00082
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, A. V. Vologzhanina, G. Astakhov, E. I. Gutsul, E. S. Shubina, M. M. Levitsky
High-nuclearity (Cu8-based) cage silsesquioxanes: Synthesis and structural study
Dalton Trans., 2018, 47(20), 6893-6897, DOI: 10.1039/C8DT00900G
A. N. Kulakova, A. N. Bilyachenko, A. Korlyukov, Jérôme Long, M. M. Levitsky, E. S. Shubina, Yannick Guari, J. Larionova
New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
Crystal Growth and Design, 2018, 18(9), 5377–5384, DOI: 10.1021/acs.cgd.8b00778
G. S. Astakhov, A. N. Bilyachenko, M. M. Levitsky, A.A. Korlyukov, Y.V. Zubavichus, P.V. Dorovatovskii, V.N. Khrustalev, A.V. Vologzhanina, E. S. Shubina
Tridecanuclear CuII11Na2 cagelike silsesquioxanes
Inorg. Chem., 2018, 57 (18), 11524–11529, DOI: 10.1021/acs.inorgchem.8b01496
G. S. Astakhov, A. N. Bilyachenko, A. Korlyukov, M. M. Levitsky, L. Shul'pina, X. Bantreil, F. Lamaty, A. Vologzhanina, E. S. Shubina, P. Dorovatovskii, D. Nesterov, A. Pombeiro, G. B. Shul’pin
High cluster (Cu9) cage silsesquioxanes. Synthesis, structure and catalytic activity
Dalton Trans., 2018, 47, 15666-15669, DOI: 10.1039/C8DT03209B
A. N. Kulakova, A. N. Bilyachenko, A. A. Korlyukov, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, N. S. Ikonnikov, G. B. Shul’pin
A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
Catalysts, 2018, 8(10), 484, DOI: 10.3390/catal8100484
A. N. Kulakova, A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, G. B. Shul’pin
Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity

2017

Journal of Molecular Catalysis A: Chemical, 2017, 426, Part B, 297-304, DOI: 10.1016/j.molcata.2016.06.016
M. M. Levitsky, A. I. Yalymov, A. N. Kulakova, A. A. Petrov, A. N. Bilyachenko
Cage-like metallsilsesquioxanes in catalysis: A review
Inorg. Chem., 2017, 56 (7), 4093-4103, DOI: 10.1021/acs.inorgchem.7b00061
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Petrov, Alexander A. Korlyukov, Lidia S. Shul’pina, Victor N. Khrustalev, Pavel V. Dorovatovskii, Anna V. Vologzhanina, Ulyana S. Tsareva, I. E. Golub, E. Gulyaeva, E. S. Shubina, G. B. Shul’pin
Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
Catalysts, 2017, 7(4), 101, DOI: 10.3390/catal7040101
A. I. Yalymov, A. N. Bilyachenko, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, L. S. Shul’pina, P. V. Dorovatovskii, M. A. Es’kova, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, E. S. Shubina, Y. N. Kozlov, G. B. Shul’pin
High Catalytic Activity of Heterometallic (Fe6Na7 and Fe6Na6) Cage Silsesquioxanes in Oxidations with Peroxides
J. Organomet. Chem., 2017, 849–850 , 201-218, DOI: 10.1016/j.jorganchem.2017.05.007
M. M. Levitsky, A. N. Bilyachenko, G. B. Shul’pin
Oxidation of C‒H compounds with peroxides catalyzed by polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks
ChemCatChem, 2017, 9 (23), 4437–4447, DOI: 10.1002/cctc.201701063
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, A. V. Vologzhanina, A. A. Titov, P. V. Dorovatovskii, L. S. Shul’pina, F. Lamaty, X. Bantreil, B. Villemejeanne, C. Ruiz, J. Martinez, E. S. Shubina, G. B. Shul’pin
Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
Dalton Trans., 2017, 46(38), 12935-12949, DOI: 10.1039/C7DT02017A
A. N. Bilyachenko, A. A. Korlyukov, A. V. Vologzhanina, V. N. Khrustalev, A. N. Kulakova, J. Long, J. Larionova, Y. Guari, M. S. Dronova, U. S. Tsareva, P. V. Dorovatovskii, E. S. Shubina, M. M. Levitsky
Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
Inorg. Chem., 2017, 56, 12751-12763, DOI: 10.1021/acs.inorgchem.7b01436
A. N. Bilyachenko, A. I. Yalymov, M. S. Dronova, Alexander Korlyukov, Anna Vologzhanina, Marina Es’kova, Jérôme Long, J. Larionova, Yannick Guari, Pavel Dorovatovskii, E. S. Shubina, M. M. Levitsky
Family of Polynuclear Nickel Cagelike Phenylsilsesquioxanes; Features of Periodic Networks and Magnetic Properties
Inorg. Chem., 2017, 56 (24), 15026–15040, DOI: 10.1021/acs.inorgchem.7b02320
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, A. A. Korlyukov, Y. V. Zubavichus, P. V. Dorovatovskii, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, L. S. Shul’pina, E. S. Shubina, E. I. Gutsul, I. A. Mikhailov, N. S. Ikonnikov, U. S. Tsareva, G. B. Shul’pin
Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations

2016

Coord. Chem. Rev., 2016, 306, 235-269, DOI: 10.1016/j.ccr.2015.07.007
M. M. Levitsky, A. N. Bilyachenko
Modern concepts and methods in the chemistry of polyhedral metallasiloxanes
Dalton Trans., 2016, 45, 7320 - 7327, DOI: 10.1039/C6DT00113K
A. N. Bilyachenko, A. I. Yalymov, A. Korlyukov, J. Long, J. Larionova, Y. Guari, A. V. Vologzhanina, M. Eskova, E. S. Shubina, M. M. Levitsky
Unusual penta- and hexanuclear Ni(II)-based silsesquioxane polynuclear complexes
RSC Adv., 2016, 6, 48165 - 48180, DOI: 10.1039/C6RA07081G
A. N. Bilyachenko, M. M. Levitsky, A. I. Yalymov, A. Korlyukov, A. Vologzhanina, Yu. Kozlov, L. Shul'pina, D. Nesterov, A. Pombeiro, F. Lamaty, X. Bantreil, A. Fetre, D. Liu, J. Martinez, J. Long, J. Larionova, Y. Guari, A. Trigub, Y. Zubavichus, I. E. Golub, O. A. Filippov, E. S. Shubina, G. B. Shul’pin
A Heterometallic (Fe6Na8) Cage-like Silsesquioxane: Synthesis, Structure, Spin Glass Behavior and High Catalytic Activity
Molecules, 2016, 21, 665, DOI: 10.3390/molecules21050665
A. N. Bilyachenko, A. I. Yalymov, Shul’pina L.S., Mandelli, D., Korlyukov, A.A., Vologzhanina A.V., Es’kova M.A., E. S. Shubina, M. M. Levitsky, G. B. Shul’pin
Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
Dalton Trans., 2016, 45, 13663 - 13666, DOI: 10.1039/C6DT02026G
A. N. Bilyachenko, A. I. Yalymov, M. M. Levitsky, A. Korlyukov, M. Eskova, J. Long, J. Larionova, Y. Guari, L.S. Shul'pina, N.S. Ikonnikov, A. Trigub, Y.V. Zubavichus, I. E. Golub, E. S. Shubina, G. B. Shul’pin
First Cage-Like Pentanuclear Co(II)-Silsesquioxane
Angew. Chem. Int. Ed., 2016, 55, 15360-15363, DOI: 10.1002/anie.201607189
A. N. Bilyachenko, M. M. Levitsky, A. I. Yalymov, A.A. Korlyukov, V.N. Khrustalev, A.V. Vologzhanina, L.S. Shul’pina, N.S. Ikonnikov, A.E. Trigub, P.V. Dorovatovsky, X. Bantreil, F. Lamaty, J. Long, J. Larionova, I. E. Golub, E. S. Shubina, G. B. Shul’pin
Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity

2015

Chem. A Eur. J., 2015, 21, 8758-8770, DOI: 10.1002/chem.201500791
A. N. Bilyachenko, M. S. Dronova, A. I. Yalymov, F. Lamaty, X. Bantreil, J. Martinez, C. Bizet, L. S. Shul'pina, A. A. Korlyukov, D. E. Arkhipov, M. M. Levitsky, E. S. Shubina, A. M. Kirillov, G. B. Shul’pin
Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
New J. Chem., 2015, 39, 187-199, DOI: 10.1039/C4NJ01163E
M. M. Vinogradov, Yu. N. Kozlov, A. N. Bilyachenko, D. S. Nesterov, L. S. Shul'pina, Ya. V. Zubavichus, A. J. L. Pombeiro, M. M. Levitsky, A. I. Yalymov, G. B. Shul’pin
Alkane oxidation with peroxides catalyzed by cage-like copper(II) silsesquioxanes
Chem. Eur. J., 2015, 21, 18563–18565, DOI: 10.1002/chem.201503635
A. N. Bilyachenko, A. I. Yalymov, A. A. Korlyukov, J. Long, J. Larionova, Y. Guari, Y. V. Zubavichus, A. L. Trigub, E. S. Shubina, I. L. Eremenko, N. N. Efimov, M. M. Levitsky
Heterometallic Na6Co3 Phenylsilsesquioxane Exhibiting Slow Dynamic Behavior in its Magnetization

2014

Dalton Trans., 2014, 43, 872 – 882, DOI: 10.1039/C3DT52508B
M. S. Dronova, A. N. Bilyachenko, A. I. Yalymov, Kozlov Y.N., Shul’pina L.S., Korlyukov A.A., Arkhipov D.E., M. M. Levitsky, E. S. Shubina, G. B. Shul’pin
Solvent-controlled synthesis of tetranuclear cage-like copper(II) silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation of benzene and alcohols with peroxides
Russ. Chem. Bull., 2014, 63, 821-825, DOI: 10.1007/s11172-014-0515-9
A. I. Yalymov, M. S. Dronova, O. A. Filippov, A. N. Bilyachenko, M. M. Levitsky
Quantum chemical study of the template synthesis of cage-like metallasiloxanes

2013

Eur. J. Inorg. Chem., 2013, 5240-5246, DOI: 10.1002/ejic.201300878
A. N. Bilyachenko, M. S. Dronova, A. I. Yalymov, A.A. Korlyukov, L.S. Shul’pina, D.E. Arkhipov, E. S. Shubina, M. M. Levitsky, A.D. Kirilin, G. B. Shul’pin
New Binuclear Cage-like Copper(II) Silsesquioxane (“Cooling Tower”); Its High Catalytic Activity in Oxidation of Benzene and Alcohols
Russ. Chem. Bull., 2013, 62, 1941-1943
M. S. Dronova, A. N. Bilyachenko, A.A. Korlyukov, D.E. Arkhipov, A.D. Kirilin, E. S. Shubina, G. M. Babakhina, M. M. Levitsky
A new type of supramolecular organization in the cage-like metallasiloxanes

2012

Eur. J. Inorg. Chem., 2012, 5554–5561
A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A.F. Smol’yakov, F.M. Dolgushin, V.K. Belsky, I.A. Godovikov, L. M. Epstein, E. S. Shubina
Complexes of Trinuclear Macrocyclic Copper(I) and Silver(I) 3,5- Bis(Trifluoromethyl)Pyrazolates with Ketones
Russ. Chem. Bull., 2012, 61, 200-203
M. M. Levitsky, A. N. Bilyachenko, M. S. Dronova, A.I. Dmitriev, R.B. Morgunov, E. S. Shubina, A.D. Kirilin
Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments

2011

Inorg. Chem., 2011, 50, 3325-3331
V. N.Tsupreva, A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A. F.Smol'yakov, F. M. Dolgushin, D. V. Agapkin, I. A. Godovikov, L. M. Epstein, E. S. Shubina
Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds

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