MH-Lab | Oleg A. Filippov

Home >
Team >
Oleg A. Filippov

Поздравляем РНФ с 10-летием! Все эти годы мы с вами. Благодарим за объективную экспертизу, справедливый подход, открытость и готовность к сотрудничеству! Огромное вам спасибо! Желаем всем сотрудникам фонда здоровья и плодотворной работы, а нам и коллегам - новых успешных проектов!

Oleg A. Filippov

Leading researcher

Personal Info

Date Of Birth

12/10/1977

Address

A.N. Nesmeyanov Institute of Organoelement Compounds
Russian Academy of Sciences
Vavilov St. 28, Moscow, Russia, 119991

Send Email

Academic Degree

1999 - M.Sc. Lomonosov Moscow State University, Chemistry Department, Moscow, Russia
2003 - Ph.D. Lomonosov Moscow State University, Moscow Chemistry Department,, Russia
2017 - D.Sc. (Chem.), A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Experience

1994-99 - Student, Lomonosov Moscow State University, Moscow, Russia 1999-02 - Ph.D. student, Lomonosov Moscow State University, Moscow, Russia 2002-2007 - Research Scientist, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Moscow, Russia 2007-2019 - Senior Research Scientist, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Moscow, Russia 2019-present time - Leading Research Scientist, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Moscow, Russia 2007-2008 - Universitat Autònoma de Barcelona, 8 months fellowship as a part of the INTAS project in Barcelona, in the group of Prof. Agustí Lledós

Scientific Interests

Molecular spectroscopy of main group compounds and hydrides, intermolecular interactions, hydrogen bonding and proton transfer, computational methods in chemistry.

Additional

Supervisor of 3 Ph. D. Thesis

Publications

2023

Inorganics, 2023, 11(5), 212, DOI: 10.3390/inorganics11050212
V. A. Kirkina, V. Kulikova, E. I. Gutsul, Gafurov Zufar N., Sakhapov Ilias F., Yakhvarov Dmitry G., Nelyubina Yulia V., O. A. Filippov, E. S. Shubina, N. V. Belkova
Role of Non-Covalent Interactions in the Reactions between Palladium Hydrido Complex with Amidoarylphosphine Pincer Ligand and Brønsted Acids
Organometallics, 2023, DOI: 10.1021/acs.organomet.3c00125
E. S. Osipova, Sedlova D.V., E. I. Gutsul, Nelyubina Yulia V., Dorovatovsii Pavel V., L. M. Epstein, O. A. Filippov, E. S. Shubina, N. V. Belkova
Reactivity of heterobimetallic ion pairs in formic acid dehydrogenation
Eur. J. Inorg. Chem., 2023, e202300143, DOI: 10.1002/ejic.202300143
Matthieu Cavailles, O. A. Filippov, Vincent César, Noël Lugan, D. Valyaev
Half-Sandwich Manganese Complex Bearing Fused Oxazoline-NHC Ligand: Conformational Analysis and Evaluation in Asymmetric Ketone Hydrosilylation
Molecules, 2023, 28(8), 3368, DOI: 10.3390/molecules28083368
E. S. Osipova, S. Kovalenko, E. Gulyaeva, N. V. Kireev, Alexander A. Pavlov, O. A. Filippov, Anastasia A. Danshina, D. Valyaev, Yves Canac, E. S. Shubina, N. V. Belkova
The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes
Inorganics, 2023, 11(4), 175, DOI: 10.3390/inorganics11040175
Arina Olbrykh, A. A. Titov, Alexander Smol’yakov, O. A. Filippov, E. S. Shubina
Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex
Molecules, 2023, 28(3), 1189, DOI: 10.3390/molecules28031189
Yakovlev G. B., A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu, O. A. Filippov, E. S. Shubina
Tetranuclear Copper(I) and Silver(I) Pyrazolate Adducts with 1,1$\prime$-Dimethyl-2,2’-bibenzimidazole: Influence of Structure on Photophysics
Russ. Chem. Bull., 2023, 72(1), DOI: 10.1007/s11172-023-3716-2
N. V. Kireev, O. A. Filippov, L. M. Epstein, E. S. Shubina, N. V. Belkova
Activation of dinitrogen by group 6 metal complexes

2022

Inorg. Chem. Front., 2022, 9(21), 5624-5634, DOI: 10.1039/d2qi01648f
S. K. Emashova, A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu, Godovikov Ivan A., Godovikova Maria I., Dorovatovskii Pavel V., Korlyukov Alexander A., O. A. Filippov, E. S. Shubina
Emissive Silver(I) Cyclic Trinuclear Complexes with Aromatic Amine Donor Pyrazolate Derivatives: Way to Efficiency
Inorg. Chem., 2022, 61(40), 16081-16092, DOI: 10.1021/acs.inorgchem.2c02478
Nekrasov Roman I., Peganova Tat’yana A., Fedyanin Ivan V., E. I. Gutsul, O. A. Filippov, N. V. Belkova, Kalsin Alexander M.
Versatile Reactivity of Half-Sandwich Rhodium(III) Iminophosphonamide Complexes
Russian Journal of Coordination Chemistry, 2022, 48(10), 615-621, DOI: 10.1134/S1070328422100086
A. A. Titov, Smol'yakov A.F., O. A. Filippov, N. V. Belkova, E. S. Shubina
Halogen or Arene: Complexation of 4,4'-Dibromobiphenyl with a Three-Membered Silver(I) Macrocycle
Inorg. Chim. Acta, 2022, 539, 121004, DOI: 10.1016/j.ica.2022.121004
A. A. Titov, Smol'yakov Alexander F., Godovikov Ivan A., Chernyadyev Andrey Yu, Molotkov Alexander P., Loginov Dmitry A., O. A. Filippov, N. V. Belkova, E. S. Shubina
The role of weak intermolecular interactions in photophysical behavior of isocoumarins on the example of their interaction with cyclic trinuclear silver(I) pyrazolate
Chemical Communications, 2022, 58(32), 5017-5020, DOI: 10.1039/D2CC00999D
E. S. Osipova, E. Gulyaeva, N. V. Kireev, S. Kovalenko, Bijani Crisitan, Canac Yves, D. Valyaev, O. A. Filippov, N. V. Belkova, E. S. Shubina
Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(Ph2PCH2PPh2)Mn(CO)3H]
Chemical Communications, 2022, 58(6), 859-862, DOI: 10.1039/D1CC06401K
V. A. Kirkina, Kissel Alexander A., Selikhov Alexander N., Nelyubina Yulia V., O. A. Filippov, N. V. Belkova, Trifonov Alexander A., E. S. Shubina
Amine-boranes reactions promoted by lanthanide(ii) ions

2021

J. Organomet. Chem., 2021, 942, 121813, DOI: 10.1016/j.jorganchem.2021.121813
A. A. Titov, Smol’yakov A.F., O. A. Filippov
Heterobimetallic silver(I) and copper(I) pyrazolates supported with 1,1'-bis(diphenylphosphino)ferrocene
Organic and Biomolecular Chemistry, 2021, 19(43), 9421 - 9426, DOI: 10.1039/D1OB01711J
Petropavlovskikh D.A., Vorobyeva D.V., Godovikov I.A., Nefedov S.E., O. A. Filippov, Osipov S.N.
Lossen rearrangement by Rh(III)-catalyzed C-H activation/annulation of aryl hydroxamates with alkynes: access to quinolone-containing amino acid derivatives
Molecules, 2021, 26(22), 6869, DOI: 10.3390/molecules26226869
K. F. Baranova, A. A. Titov, Smol’yakov A.F., Chernyadyev A.Y., O. A. Filippov, E. S. Shubina
Mononuclear copper(I) 3-(2-pyridyl)pyrazole complexes: the crucial role of phosphine on photoluminescence
Russian Journal of Inorganic Chemistry, 2021, 66(11), 1639 - 1648, DOI: 10.3390/molecules26123754
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The mechanism of halogenation of decahydro-closo-decaborate dianion by hydrogen chloride
Molecules, 2021, 26(12), 3754, DOI: 10.3390/molecules26123754
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The reaction of hydrogen halides with tetrahydroborate anion and hexahydro-closo-hexaborate dianion
Dalton Trans., 2021, 50(7) , 2671-2688, DOI: 10.1039/d0dt03857a
Stogniy Marina Yu, Anufriev Sergey A., Shmal'ko Akim V., Antropov Sergey M., Anisimov Aleksei A., Suponitsky Kyrill Yu, O. A. Filippov, Sivaev Igor B.
The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4’,4”-(MeOCH2CH2O)3-3,3’,3”-Co3(μ3-O)(μ3-S)(1,2-C2B9H10)3]
Molecules, 2021, 26(5), 1321, DOI: 10.3390/molecules26051321
Asawa Yasunobu, Arsent’eva Aleksandra V., Anufriev Sergey A., Anisimov Alexei A., Suponitsky Kyrill Yu, O. A. Filippov, Nakamura Hiroyuki, Sivaev Igor B
Synthesis of Bis(Carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) and Attempt of Synthesis of Gadolinium Bis(Dicarbollide)
Mendeleev Communications, 2021, 31(2), 170-172, DOI: 10.1016/j.mencom.2021.03.008
A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., Averin Alexey A., E. S. Shubina
New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2'-bipyridine
Inorg. Chem., 2021, 60 (6) , 4015–4025, DOI: 10.1021/acs.inorgchem.1c00073
Grineva Alina A., O. A. Filippov, Canac Yves, Sortais Jean-Baptiste, Nefedov Sergei E., Lugan Noël, César Vincent, D. Valyaev
Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes
Coord. Chem. Rev., 2021, 438, 213799, DOI: 10.1016/j.ccr.2021.213799
N. V. Belkova, O. A. Filippov, E. S. Osipova, S. V. Safronov, L. M. Epstein, E. S. Shubina
Iinfluence of phosphine (pincer) ligands on the transition metal hydrides reactivity
Chemical science, 2021, 12, 3682-3692, DOI: DOI: 10.1039/D0SC06114J
E. S. Osipova, E. Gulyaeva, E. I. Gutsul, V. A. Kirkina, A. A. Pavlov, Y. V. Nelyubina, A. Rossin, M. Peruzzini, L. M. Epstein, N. V. Belkova, O. A. Filippov, E. S. Shubina
Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”

2020

ChemCatChem, 2020, 12(23), 5959-5965, DOI: 10.1002/cctc.202001308
D. Gelman, De-Botton Sophie, O. A. Filippov, E. S. Shubina, N. V. Belkova
Regioselective Isomerization of Terminal Alkenes Catalyzed by a PC(sp3)P Pincer Complex with a Hemilabile Pendant Arm
Crystals, 2020, 10(10), 881, DOI: 10.3390/cryst10100881
K. F. Baranova, A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., Averin Alexey A., E. S. Shubina
Dinuclear Silver(I) Nitrate Complexes with Bridging Bisphosphinomethanes: Argentophilicity and Luminescence
Inorg. Chem., 2020, 59(17), 12240–12251, DOI: 10.1021/acs.inorgchem.0c01293
E. D. Voronova, I. E. Golub, Pavlov A., N. V. Belkova, O. A. Filippov, L. M. Epstein, E. S. Shubina
Dichotomous Si–H Bond Activation by Alkoxide and Alcohol in Base-Catalyzed Dehydrocoupling of Silanes
Mendeleev Communications, 2020, 30(3), 366-368, DOI: 10.1016/j.mencom.2020.05.035
Khotina I. A., O. A. Filippov, Kovalev A. I.
Microporous polyphenylenes based on diacetylaromatic compounds
Molecules, 2020, 25(9), 2236, DOI: 10.3390/molecules25092236
Safronov S. V., E. S. Osipova, Nelyubina Y. V., O. A. Filippov, Barakovskaya I. G., N. V. Belkova, E. S. Shubina
Steric and Electronic Effect of Cp-Substituents on the Structure of the Ruthenocene Based Pincer Palladium Borohydrides
Mendeleev Communications, 2020, 30(3), 276-278, DOI: 10.1016/j.mencom.2020.05.004
V. A. Kirkina, E. S. Osipova, O. A. Filippov, G. A. Silantyev, D. Gelman, E. S. Shubina, N. V. Belkova
Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
Molecules, 2020, 25(12), 2920, DOI: 10.3390/molecules25122920
I. E. Golub, O. A. Filippov, V. Kulikova, N. V. Belkova, L. M. Epstein, E. S. Shubina
Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes
Inorg. Chem., 2020, 59(17), 11962–11975, DOI: 10.1021/acs.inorgchem.0c00797
V. A. Kirkina, G. A. Silantyev, De-botton Sophie, O. A. Filippov, E. M. Kozinets (Titova), Pavlov Alexander, N. V. Belkova, L. M. Epstein, D. Gelman, E. S. Shubina
Stereoisomerism as an Origin of Different Reactivity of Ir(III) PC(sp3)P Pincer Catalysts
Chemical Communications, 2020, 56, 2139-2142, DOI: 10.1039/C9CC07713H
N. V. Kireev, O. A. Filippov, E. Gulyaeva, E. S. Shubina, Laure Vendier, Yves CANAC, Jean-Baptiste Sortais, Noël Lugan, D. Valyaev
Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation
Molecules, 2020, 24(24), 4449, DOI: 10.3390/molecules24244449
Sergey A. Anufriev, Kyrill Yu. Suponitsky, O. A. Filippov, Igor B. Sivaev
Synthesis and Structure of Methylsulfanyl Derivatives of Nickel Bis(Dicarbollide)
RSC Adv., 2020, 10(5), 2887-2896, DOI: 10.1039/c9ra08551c
Marina Yu. Stogniy, Olga N. Kazheva, Denis M. Chudak, Gennady V. Shilov, O. A. Filippov, Igor B. Sivaev, Andrey V. Kravchenko, Vladimir A. Starodub, Lev I. Buravov, Vladimir I. Bregadze, Oleg A. Dyachenkob
Synthesis and study of C-substituted methylthio derivatives of cobalt bis(dicarbollide)

2019

Mendeleev Communications, 2019, 29 (5), 570-572, DOI: 10.1016/j.mencom.2019.09.031
A. A. Titov, O. A. Filippov, A.F. Smol’yakov, A.A. Averin, E. S. Shubina
Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
Eur. J. Inorg. Chem., 2019, 2019 (45), 4855-4861, DOI: 10.1002/ejic.201901050
S. K. Emashova, A. A. Titov, O. A. Filippov, A.F. Smol'yakov, E. M. Kozinets (Titova), L. M. Epstein, E. S. Shubina
Luminescent AgI Complexes with 2,2′-Bipyridine Derivatives Featuring [Ag-(CF3)2Pyrazolate]4 Units
Dalton Trans., 2019, 48, 12720 - 12729, DOI: 10.1039/C9DT02176K
S. V. Safronov, E. I. Gutsul, I. E. Golub, F. M. Dolgushin, Y. V. Nelyubina, O. A. Filippov, L. M. Epstein, A. S. Peregudov, N. V. Belkova, E. S. Shubina
Synthesis, Structural Properties and Reactivity of Ruthenocene-based Pincer Pd(II) Tetrahydroborate
Inorg. Chem., 2019, 58(13), 8645-8656, DOI: 10.1021/acs.inorgchem.9b00991
A. A. Titov, O. A. Filippov, A.F. Smolyakov, I.A. Godovikov, J.R. Shakirova, S. P. Tunik, I.S. Podkorytov, E. S. Shubina
Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane
Organometallics, 2019, 38(11), 2330-2337, DOI: 10.1021/acs.organomet.9b00151
A.A. Grineva, O. A. Filippov, S.E. Nefedov, Noël Lugan, Vincent César, D. Valyaev
Direct Access to IMesF and IMesF2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes
Dalton Trans., 2019, 48, 8410-8417, DOI: 10.1039/c9dt01355e
A. A. Titov, O. A. Filippov, A.F. Smol’yakov, A.A. Averin, E. S. Shubina
Syntheses, Structures and Luminescence of multinuclear Silver(I) pyrazolate adducts with 1, 10-Phenanthroline derivatives
Angew. Chem. Int. Ed., 2019, 58 (20), 6727-6731, DOI: 10.1002/anie.201901169
R. Buhaibeh, O. A. Filippov, J. Willot, C. Duhayon, D. Valyaev, N. Lugan, Y. Canac, J.-B. Sortais
Phosphine‐NHC Manganese Hydrogenation Catalyst Exhibiting a Non‐Classical Metal‐Ligand Cooperative H2 Activation Mode
Mendeleev Communications, 2019, 29, 121–127, DOI: 10.1016/j.mencom.2019.03.001
E. S. Osipova, O. A. Filippov, E. S. Shubina, N. V. Belkova
Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes
Eur. J. Inorg. Chem., 2019, 10, 1389-1397, DOI: 10.1002/ejic.201801341
E. S. Osipova, E. Gulyaeva, O. A. Filippov, S. V. Safronov, A. A. Pavlov, A. V. Polukeev, V. A. Kirkina, E. M. Kozinets (Titova), E. S. Shubina, N. V. Belkova
Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes
Eur. J. Inorg. Chem., 2019, 1, 18-22, DOI: 10.1002/ejic.201801094
Aullón Gabriel, Laguna Antonio, O. A. Filippov, Oliva-Enrich Josep M.
Trinuclear Gold-Carborane Cluster as a Host Structure
Eur. J. Inorg. Chem., 2019, 6, 821-827, DOI: 10.1002/ejic.201801318
A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., K. F. Baranova, E. M. Kozinets (Titova), Averin Aleksey A., E. S. Shubina
Dinuclear Cu(I) and Ag(I) pyrazolates supported with tertiary phosphines: Synthesis, structures and photophysical properties

2018

Inorg. Chim. Acta, 2018, 470, 22-35, DOI: 10.1016/j.ica.2017.07.015
A. A. Titov, O. A. Filippov, L. M. Epstein, N. V. Belkova, E. S. Shubina
Macrocyclic Copper(I) and Silver(I) Pyrazolates: Principles of Supramolecular Assemblies with Lewis Bases
Inorg. Chem., 2018, 57, 1656−1664, DOI: 10.1021/acs.inorgchem.7b03027
N. V. Kireev, O. A. Filippov, A. A. Pavlov, L. M. Epstein, V. D. Makhaev, V. P. Dyadchenko, E. S. Shubina, N. V. Belkova
Steric and Acidity Control in Hydrogen Bonding and Proton Transfer to trans-W(N₂)₂(dppe)₂
Chem. Eur. J., 2018, 24(7), 1464–1470, DOI: 10.1002/chem.201704203
N. V. Belkova, O. A. Filippov, E. S. Shubina
Z-H bond activation in (di)hydrogen bonding as a way to proton/hydride transfer and H2 evolution
J. Organomet. Chem., 2018, 865, 247-256, DOI: 10.1016/j.jorganchem.2018.03.020
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
Hydride donating abilities of the tetracoordinated boron hydrides
Angew. Chem. Int. Ed., 2018, 57(27), 7986-7991, DOI: 10.1002/anie.201801530
N. Lugan, D. Valyaev, A.A. Grineva, V. César, O. A. Filippov, V.N. Khrustalev, S.N. Nefedov
Oxidative Coupling of Anionic Abnormal N‐Heterocyclic Carbenes: an Efficient Access to Janus‐Type 4,4'‐Bis(2H‐Imidazol‐2‐Ylidenes)
Mendeleev Communications, 2018, 28(4), 387-389, DOI: 10.1016/j.mencom.2018.07.015
A. A. Titov, A F. Smol'yakov, K. F. Baranova, O. A. Filippov, E. S. Shubina
Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis-(trifluoromethyl)pyrazolates
Chemistry - An Asian Journal, 2018, 13, 3084-3089, DOI: 10.1002/asia.201801156
E. D. Voronova, I. E. Golub, A. A. Pavlov, N. V. Belkova, O. A. Filippov, L. M. Epstein, E. S. Shubina
Comprehensive Insight into Hydrogen Bonding of Silanes
Organometallics, 2018, 37 (18), 3142-3153, DOI: 10.1021/acs.organomet.8b00488
L. Luconi, E. S. Osipova, G. Giambastiani, M. Peruzzini, A. Rossin, N. V. Belkova, O. A. Filippov, E. M. Kozinets (Titova), A. A. Pavlov, E. S. Shubina
Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance
Eur. J. Inorg. Chem., 2018, 47, 5098-5107, DOI: 10.1002/ejic.201801119
Peganova T. A., O. A. Filippov, N. V. Belkova, Fedyanin I. V., Kalsin A. M.
The Origin of the MNXN Metallacycle Flexibility in the Chelate Iminophosphonamide and Amidinate Transition Metal Complexes

2017

ACS catalysis, 2017, 7, 2325-2333, DOI: 10.1021/acscatal.6b03207
E. M. Kozinets (Titova), E. S. Osipova, Pavlov Alexander A., O. A. Filippov, Safronov Sergey V., E. S. Shubina, N. V. Belkova
Mechanism of Dimethylamine–Borane Dehydrogenation Catalyzed by an Iridium(III) PCP-Pincer Complex
J. Organomet. Chem., 2017, 827, 86-95, DOI: 10.1016/j.jorganchem.2016.11.010
E. M. Kozinets (Titova), E. S. Osipova, E. Gulyaeva, V.N. Torocheshnikov, A.A. Pavlov, G. A. Silantyev, O. A. Filippov, E. S. Shubina, N. V. Belkova
Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
Inorg. Chem., 2017, 56, 4296−4307, DOI: 10.1021/acs.inorgchem.6b02673
Stefano Todisco, Lapo Luconi, Giuliano Giambastiani, Andrea Rossin, M. Peruzzini, I. E. Golub, O. A. Filippov, N. V. Belkova, E. S. Shubina
Ammonia Borane Dehydrogenation Catalyzed by (κ4‑EP3)Co(H) [EP3 = E(CH2CH2PPh2)3; E = N, P] and H2 Evolution from Their Interaction with NH Acids
Inorg. Chim. Acta, 2017, 456, 113-119, DOI: 10.1016/j.ica.2016.10.037
I. E. Golub, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, N. V. Belkova
The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis
Eur. J. Inorg. Chem., 2017, 4673–4682, DOI: 10.1002/ejic.201700624
I. E. Golub, O. A. Filippov, N. V. Belkova, E. I. Gutsul, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ³-P-CH₃C(CH₂CH₂PPh₂)₃}RuH(η²-BH₄)]
Chem. Eur. J., 2017, 23 (61), 15424-15435, DOI: 10.1002/chem.201702862
I. S. Sinoplanikova, T. y. A. Peganova, V. V. Novikov, I. V. Fedyanin, O. A. Filippov, N. V. Belkova, E. S. Shubina, R. Poli, A. M. Kalsin
Coordinatively labile 18-electron arene ruthenium iminophosphonamide complexes
Eur. J. Inorg. Chem., 2017, 4444–4451, DOI: 10.1002/ejic.201700575
Sergey A. Anufriev, Svetlana A. Erokhina, Kyrill Yu. Suponitsky, Ivan A. Godovikov, O. A. Filippov, Fabrizia Fabrizi de Biani, Maddalena Corsini, Alexander O. Chizhov, Igor B. Sivaev
Methylsulfanyl-Stabilized Rotamers of Cobalt Bis(dicarbollide)
Crystals, 2017, 7(10), 318-335, DOI: 10.3390/cryst7100318
N. V. Belkova, I. E. Golub, E. I. Gutsul, K. A. Lyssenko, A. S. Peregudov, V. D. Makhaev, O. A. Filippov, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
Crystal Growth and Design, 2017, 17 (12), 6770–6779, DOI: 10.1021/acs.cgd.7b01351
A. A. Titov, A. Smol’yakov, O. A. Filippov, I. Godovikov, D. Muratov, F. Dolgushin, L. M. Epstein, E. S. Shubina
Supramolecular design of the trinuclear silver(I) and copper(I) metal pyrazolates complexes with ruthenium sandwich compounds via intermolecular metal-π interactions
Russ. Chem. Bull., 2017, 66 (9), 1563–1568, DOI: 10.1007/s11172-017-1925-2
A. A. Titov, A F. Smol´yakov, A. N. Rodionov, I. D. Kosenko, E. Guseva, Ya. V. Zubavichus, P. V. Dorovatovskii, O. A. Filippov, E. S. Shubina
Ferrocenecontaining tri and tetranuclear cyclic copper(I) and silver(I) pyrazolates

2016

Chemical Reviews, 2016, 116, 8545-8587, DOI: 10.1021/acs.chemrev.6b00091
N. V. Belkova, L. M. Epstein, O. A. Filippov, E. S. Shubina
Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides
Eur. J. Inorg. Chem., 2016, 56–63, DOI: 10.1002/ejic.201501083
E. M. Kozinets (Titova), G. A. Silantyev, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, Fedor M. Dolgushin, N. V. Belkova
PCP Pincer Iridium Chemistry: Coordination of Pyridines to (tBuPCP)IrH(Cl)
Eur. J. Inorg. Chem., 2016, 1415–1424, DOI: 10.1002/ejic.201600034
E. S. Osipova, N. V. Belkova, L. M. Epstein, O. A. Filippov, V. A. Kirkina, E. M. Kozinets (Titova), A. Rossin, M. Peruzzini, E. S. Shubina
Dihydrogen Bonding and Proton Transfer from MH vs OH acids to Group 10 Metal Hydrides (tBuPCP)MH [tBuPCP = 3-2,6-(tBu2PCH2)2C6H3; M = Ni, Pd]
RSC Adv., 2016, 6, 48165 - 48180, DOI: 10.1039/C6RA07081G
A. N. Bilyachenko, M. M. Levitsky, A. I. Yalymov, A. Korlyukov, A. Vologzhanina, Yu. Kozlov, L. Shul'pina, D. Nesterov, A. Pombeiro, F. Lamaty, X. Bantreil, A. Fetre, D. Liu, J. Martinez, J. Long, J. Larionova, Y. Guari, A. Trigub, Y. Zubavichus, I. E. Golub, O. A. Filippov, E. S. Shubina, G. B. Shul’pin
A Heterometallic (Fe6Na8) Cage-like Silsesquioxane: Synthesis, Structure, Spin Glass Behavior and High Catalytic Activity
Dalton Trans., 2016, 45, 9127 - 9135, DOI: 10.1039/c6dt01104g
I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]
J. Phys. Chem. A, 2016, DOI: 10.1021/acs.jpca.6b06579
A. A. Titov, E. Guseva, O. A. Filippov, G. M. Babakhina, I. A. Godovikov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The Role of Weak Interactions in Strong Intermolecular M•••Cl Complexes of Coinage Metal Pyrazolates: Spectroscopic and DFT Study

2015

Chem. Eur. J., 2015, 21, 13176-13180, DOI: 10.1002/chem.201502085
O. A. Filippov, A. A. Titov, E. Guseva, D. A. Loginov, A. F. Smol'yakov, F. M. Dolgushin, N. V. Belkova, L. M. Epstein, E. S. Shubina
Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene
J. Phys. Chem. A, 2015, 119, 3853-3868, DOI: 10.1021/acs.jpca.5b01921
I. E. Golub, E. Gulyaeva, O. A. Filippov, V. P. Dyadchenko, N. V. Belkova, L. M. Epstein, D. E. Arkhipov, E. S. Shubina
Dihydrogen Bond Intermediated Alcoholysis of Dimethylamine-Borane in Non-Aqueous Media
Angew. Chem. Int. Ed., 2015, 54(21), 6315-6319, DOI: 10.1002/anie.201501256
D. Valyaev, O. A. Filippov, N. Lugan, G. Lavigne, N. A. Ustynyuk
Umpolung of Methylenephosphonium Ions in Their Manganese Half-Sandwich Complexes and Application to the Synthesis of Chiral Phosphorus-Containing Ligand Scaffolds
Russ. Chem. Bull., 2015, 64(12), 2806–2810, DOI: 10.1007/s11172-015-1230-x
G. A. Silantyev, E. M. Kozinets (Titova), O. A. Filippov, E. I. Gutsul, D. Gelman, N. V. Belkova
Hydrogen bonds, coordination isomerism, and catalytic dehydrogenation of alcohols with the bifunctional iridium pincer complex (HOCH2)2(PCsp3P)IrHCl

2014

Advances in Organometallic Chemistry, 2014, First Edition. Ed.: A. J. L. Pombeiro. John Willey & Sons, Inc. chapt. 8, 97-109. (book chapter)
E. S. Shubina, N. V. Belkova, O. A. Filippov, L. M. Epstein
The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book. Weak Interactions and M-H Bond Activation
Inorg. Chem., 2014, 53, 1080–1090, DOI: 10.1021/ic4026206
N. V. Belkova, E. V. Bakhmutova-Albert, E. I. Gutsul, V. I. Bakhmutov, I. E. Golub, O. A. Filippov, L. M. Epstein, M. Peruzzini, A. Rossin, F. Zanobini, E. S. Shubina
Dihydrogen bonding in complex (PP3)RuH(η1-BH4) featuring two proton-accepting hydride sites: experimental and theoretical studies
RSC Adv., 2014, 4, 8350 – 8359, DOI: 10.1039/C3RA47040G
A. A. Titov, O. A. Filippov, E. Guseva, A. F. Smol’yakov, F. M. Dolgushin, L. M. Epstein, V. K. Belsky, E. S. Shubina
Role of basic sites of substituted ferrocenes in interaction with the trinuclear 3,5-bis(trifluoromethyl)pyrazolates: thermodynamics and structure of complexes
Russ. Chem. Bull., 2014, 63, 821-825, DOI: 10.1007/s11172-014-0515-9
A. I. Yalymov, M. S. Dronova, O. A. Filippov, A. N. Bilyachenko, M. M. Levitsky
Quantum chemical study of the template synthesis of cage-like metallasiloxanes
Russ. Chem. Bull., 2014, 63, 2434-2437, DOI: 10.1007/s11172-014-0759-4
G. A. Silantyev, E. M. Kozinets (Titova), O. A. Filippov, E. Yakurnova, N. V. Belkova
Dihydrogen bonding formed by (hydrido)[hydrotris(pyrazolyl)borato]ruthenium. The effect of ligands on the proton-withdrawing ability of ruthenium complexes
Organometallics, 2014, 33, 5964-5973, DOI: 10.1021/om500308g
G. A. Silantyev, O. A. Filippov, S. Musa, D. Gelman, N. V. Belkova, K. Weisz, L. M. Epstein, E. S. Shubina
Conformational Flexibility of Dibenzobarrelene-Based PC(sp3)P Pincer Iridium Hydride Complexes: The Role of Hemilabile Functional Groups and External Coordinating Solvents
Russ. Chem. Bull., 2014, 63, 2428-2433, DOI: 10.1007/s11172-014-0758-5
O. A. Filippov, I. E. Golub, E. S. Osipova, V. A. Kirkina, E. I. Gutsul, N. V. Belkova
Transition metal hydride M—H bond activation upon the formation of complexes with acids and bases

2013

J. Organomet. Chem., 2013, 747, 30-42, DOI: 10.1016/j.jorganchem.2013.04.025
O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
Chemistry of boron hydrides orchestrated by dihydrogen bonds
Z. Phys. Chem., 2013, 227, 69–88
O. A. Filippov, V. A. Kirkina, N. V. Belkova, S. Stoccoro, A. Zucca, G. M. Babakhina, L. M. Epstein, E. S. Shubina
First Example of Hydrogen Bonding to Platinum Hydride
Chem. Eur. J., 2013, 19, 16906–16909, DOI: 10.1002/chem.201303311
S. Musa, O. A. Filippov, N. V. Belkova, E. S. Shubina, G. A. Silantyev, L. Ackermann, D. Gelman
Ligand–Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation
Inorg. Chem., 2013, 52, 1787−1797, DOI: 10.1021/ic301585k
G. A. Silantyev, O. A. Filippov, P.M. Tolstoy, N. V. Belkova, L. M. Epstein, K. Weisz, E. S. Shubina
Hydrogen bonding and proton transfer to ruthenium hydride complex CpRuH(dppe): metal and hydride dichotomy.
Dalton Trans., 2013, 42, 11720-11730, DOI: 10.1039/C3DT51429C
E. M. Kozinets (Titova), M. Fekete, O. A. Filippov, N. V. Belkova, E. S. Shubina, R. Poli, S. Duckett, E. Manoury
Activation of a (cyclooctadiene) rhodium(I) complex supported by a chiral ferrocenyl phosphine thioether ligand for hydrogenation catalysis: a combined parahydrogen NMR and DFT study
Russ. Chem. Bull., 2013, 62, 1829-1834
A. A. Titov, E. Guseva, A. F. Smol’yakov, F. M. Dolgushin, O. A. Filippov, I. E. Golub, ^krylova#, G. M. Babakhina, L. M. Epstein, E. S. Shubina
Complexation of trimeric copper(I) and silver(I) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane

2012

Spectrosc. Prop. Inorg. Organomet. Compd., 2012, 43, 1–28 (book chapter)
N. V. Belkova, L. M. Epstein, O. A. Filippov, E. S. Shubina
IR spectroscopy of hydrides and its application to hydrogen bonding and proton transfer studies
ChemPhysChem, 2012, 13, 2677
O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Lledos, E. S. Shubina
Directionality of Dihydrogen Bonds: The Role of Transition Metal Atoms
Comput Theor Chem, 2012, 998, 129-140
O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Lledos, E. S. Shubina
Hydrogen–deuterium exchange in hydride chemistry: Dihydrogen bonded complexes as key intermediates
Inorg. Chem., 2012, 51, 6486-6497
I. E. Golub, O. A. Filippov, E. I. Gutsul, N. V. Belkova, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond
Eur. J. Inorg. Chem., 2012, 5554–5561
A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A.F. Smol’yakov, F.M. Dolgushin, V.K. Belsky, I.A. Godovikov, L. M. Epstein, E. S. Shubina
Complexes of Trinuclear Macrocyclic Copper(I) and Silver(I) 3,5- Bis(Trifluoromethyl)Pyrazolates with Ketones
Dalton Trans., 2012, 41, 11849-11859
E. M. Kozinets (Titova), O. Koniev, O. A. Filippov, J.-C. Daran, R. Poli, E. S. Shubina, N. V. Belkova, E. Manoury
Coordination chemistry of diphenylphosphinoferrocenylthioethers on cyclooctadiene and norbornadiene rhodium(I) platforms

2011

Angew. Chem. Int. Ed., 2011, 50, 1367–1370
V. A. Kirkina, A. Rossin, N. V. Belkova, M. R. Chierotti, L. M. Epstein, O. A. Filippov, R. Gobetto, L. Gonsalvi, A. Lledos, E. S. Shubina, F. Zanobini, M. Peruzzini
Acid-base interaction between transition metal hydrides results in dihydrogen bonding and assists H2 evolution
Inorg. Chem., 2011, 50, 3325-3331
V. N.Tsupreva, A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A. F.Smol'yakov, F. M. Dolgushin, D. V. Agapkin, I. A. Godovikov, L. M. Epstein, E. S. Shubina
Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds
Inorg. Chem., 2011, 50, 444-450
O.N. Kazheva, G.G. Alexandrov, A.V. Kravchenko, I.D. Kosenko, I.A. Lobanova, I.B. Sivaev, O. A. Filippov, E. S. Shubina, V.I. Bregadze, V.A. Starodub, L.V. Titov, L.I. Buravov, O.A. Dyachenko
Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion
Inorg. Chem., 2011, 50, 12539-52
A. Béthegnies, V. A. Kirkina, O. A. Filippov, J.-C. Daran, N. V. Belkova, E. S. Shubina, R. Poli
Coordination and Organometallic Chemistry of Relevance to the Rhodium-Based Catalyst for Ethylene Hydroamination