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Oleg A. Filippov

Leading researcher
Oleg A. Filippov
Personal Info
Date Of Birth
12/10/1977
Address
A.N. Nesmeyanov Institute of Organoelement Compounds
Russian Academy of Sciences
Vavilov St. 28, Moscow, Russia, 119991
Email
Send Email
Academic Degree
1999 - M.Sc. Lomonosov Moscow State University, Chemistry Department, Moscow, Russia
2003 - Ph.D. Lomonosov Moscow State University, Moscow Chemistry Department,, Russia
2017 - D.Sc. (Chem.), A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Experience
1994-99 - Student, Lomonosov Moscow State University, Moscow, Russia 1999-02 - Ph.D. student, Lomonosov Moscow State University, Moscow, Russia 2002-2007 - Research Scientist, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Moscow, Russia 2007-2019 - Senior Research Scientist, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Moscow, Russia 2019-present time - Leading Research Scientist, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, Moscow, Russia 2007-2008 - Universitat Autònoma de Barcelona, 8 months fellowship as a part of the INTAS project in Barcelona, in the group of Prof. Agustí Lledós
Scientific Interests
Molecular spectroscopy of main group compounds and hydrides, intermolecular interactions, hydrogen bonding and proton transfer, computational methods in chemistry.
Additional
Supervisor of 3 Ph. D. Thesis
Publications
2024
  • Microporous and Mesoporous Materials, 2024, 381, 113347, DOI: 10.1016/j.micromeso.2024.113347
    Tan Shuang, Dalena Francesco, I. E. Golub, Dib Eddy, O. A. Filippov, Pace Ludovica, Guillet-Nicolas Rémy, Valtchev Valentin, Guo Hailing, Mintova Svetlana
    Spectroscopic characterization of black N- and P-doped zeolite templated carbons
  • Russian Journal of Coordination Chemistry, 2024, 50(5), 316-325
    E. Gulyaeva, E. I. Gutsul, Nelyubina Y.V., E. S. Osipova, O. A. Filippov, E. S. Shubina, N. V. Belkova
    Isonitrile Coordination to Pincer Iridium Hydrido Chlorides
  • Inorg. Chem., 2024, DOI: 10.1021/acs.inorgchem.4c00751
    K. F. Baranova, A. A. Titov, Shakirova Julia R., Baigildin Vadim A., Smol’yakov Alexander F., D. Valyaev, Ning Guo-Hong, O. A. Filippov, S. P. Tunik, E. S. Shubina
    Substituents’ Effect on the Photophysics of Trinuclear Copper(I) and Silver(I) Pyrazolate–Phosphine Cages
  • Nat. Commun., 2024, 15, 5758, DOI: 10.1038/s41467-024-50164-9
    Alexander G. Medvedev, Pavel A. Egorov, Alexey A. Mikhaylov, Evgeny S. Belyaev, Gayane A. Kirakosyan, Yulia G. Gorbunova, O. A. Filippov, N. V. Belkova, E. S. Shubina, Maria N. Brekhovskikh, Anna A. Kirsanova, Maria V. Babak, Ovadia Lev, Petr V. Prikhodchenko
    Synergism of primary and secondary interactions in a crystalline hydrogen peroxide complex with tin
  • Mendeleev Communications, 2024, 34, 192–194, DOI: 10.1016/j.mencom.2024.02.010
    Sedlova D.V., E. S. Osipova, E. I. Gutsul, Ivan A. Godovikov, O. A. Filippov, E. S. Shubina, N. V. Belkova
    Stepwise carbon dioxide hydrosylilation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(But PCP)]
  • Chem. Eur. J., 2024, e202304201, DOI: 10.1002/chem.202304201
    E. Gulyaeva, Ruqaya Buhaibeh, Mohamed Boundor, Karim Azouzi, Jérémy Willot, Stéphanie Bastin, Carine Duhayon, Noël Lugan, O. A. Filippov, Jean-Baptiste Sortais, D. Valyaev, and Yves Canac
    Impact of the Methylene Bridge Substitution in Chelating NHC- Phosphine Mn(I) Catalyst for Ketone Hydrogenation
  • Chemical science, 2024, 15, 1409-1417, DOI: 10.1039/D3SC05356C
    E. Gulyaeva, E. S. Osipova, S. Kovalenko, O. A. Filippov, N. V. Belkova, Vendier Laure, Canac Yves, E. S. Shubina, D. Valyaev
    Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation
  • Chemical Communications, 2024, 60, 847-850, DOI: 10.1039/D3CC05659G
    A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu., Godovikov Ivan A., O. A. Filippov, E. S. Shubina
    Pyrazolate vs phenylethynide: direct exchange of anionic bridging ligand in cyclic trinuclear silver complex
2023
2022
2021
  • J. Organomet. Chem., 2021, 942, 121813, DOI: 10.1016/j.jorganchem.2021.121813
    A. A. Titov, Smol’yakov A.F., O. A. Filippov
    Heterobimetallic silver(I) and copper(I) pyrazolates supported with 1,1'-bis(diphenylphosphino)ferrocene
  • Organic and Biomolecular Chemistry, 2021, 19(43), 9421 - 9426, DOI: 10.1039/D1OB01711J
    Petropavlovskikh D.A., Vorobyeva D.V., Godovikov I.A., Nefedov S.E., O. A. Filippov, Osipov S.N.
    Lossen rearrangement by Rh(III)-catalyzed C-H activation/annulation of aryl hydroxamates with alkynes: access to quinolone-containing amino acid derivatives
  • Molecules, 2021, 26(22), 6869, DOI: 10.3390/molecules26226869
    K. F. Baranova, A. A. Titov, Smol’yakov A.F., Chernyadyev A.Y., O. A. Filippov, E. S. Shubina
    Mononuclear copper(I) 3-(2-pyridyl)pyrazole complexes: the crucial role of phosphine on photoluminescence
  • Russian Journal of Inorganic Chemistry, 2021, 66(11), 1639 - 1648, DOI: 10.1134/s0036023621110073
    I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
    The mechanism of halogenation of decahydro-closo-decaborate dianion by hydrogen chloride
  • Molecules, 2021, 26(12), 3754, DOI: 10.3390/molecules26123754
    I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, E. S. Shubina
    The reaction of hydrogen halides with tetrahydroborate anion and hexahydro-closo-hexaborate dianion
  • Dalton Trans., 2021, 50(7) , 2671-2688, DOI: 10.1039/d0dt03857a
    Stogniy Marina Yu, Anufriev Sergey A., Shmal'ko Akim V., Antropov Sergey M., Anisimov Aleksei A., Suponitsky Kyrill Yu, O. A. Filippov, Sivaev Igor B.
    The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4’,4”-(MeOCH2CH2O)3-3,3’,3”-Co3(μ3-O)(μ3-S)(1,2-C2B9H10)3]
  • Molecules, 2021, 26(5), 1321, DOI: 10.3390/molecules26051321
    Asawa Yasunobu, Arsent’eva Aleksandra V., Anufriev Sergey A., Anisimov Alexei A., Suponitsky Kyrill Yu, O. A. Filippov, Nakamura Hiroyuki, Sivaev Igor B
    Synthesis of Bis(Carboranyl)amides 1,1′-μ-(CH2NH(O)C(CH2)n-1,2-C2B10H11)2 (n = 0, 1) and Attempt of Synthesis of Gadolinium Bis(Dicarbollide)
  • Mendeleev Communications, 2021, 31(2), 170-172, DOI: 10.1016/j.mencom.2021.03.008
    A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., Averin Alexey A., E. S. Shubina
    New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2'-bipyridine
  • Inorg. Chem., 2021, 60 (6) , 4015–4025, DOI: 10.1021/acs.inorgchem.1c00073
    Grineva Alina A., O. A. Filippov, Canac Yves, Sortais Jean-Baptiste, Nefedov Sergei E., Lugan Noël, César Vincent, D. Valyaev
    Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes
  • Coord. Chem. Rev., 2021, 438, 213799, DOI: 10.1016/j.ccr.2021.213799
    N. V. Belkova, O. A. Filippov, E. S. Osipova, S. V. Safronov, L. M. Epstein, E. S. Shubina
    Iinfluence of phosphine (pincer) ligands on the transition metal hydrides reactivity
  • Chemical science, 2021, 12, 3682-3692, DOI: DOI: 10.1039/D0SC06114J
    E. S. Osipova, E. Gulyaeva, E. I. Gutsul, V. A. Kirkina, A. A. Pavlov, Y. V. Nelyubina, A. Rossin, M. Peruzzini, L. M. Epstein, N. V. Belkova, O. A. Filippov, E. S. Shubina
    Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
2020
2019
2018
2017
2016
2015
2014
2013
2012
2011
  • Angew. Chem. Int. Ed., 2011, 50, 1367–1370
    V. A. Kirkina, A. Rossin, N. V. Belkova, M. R. Chierotti, L. M. Epstein, O. A. Filippov, R. Gobetto, L. Gonsalvi, A. Lledos, E. S. Shubina, F. Zanobini, M. Peruzzini
    Acid-base interaction between transition metal hydrides results in dihydrogen bonding and assists H2 evolution
  • Inorg. Chem., 2011, 50, 3325-3331
    V. N.Tsupreva, A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A. F.Smol'yakov, F. M. Dolgushin, D. V. Agapkin, I. A. Godovikov, L. M. Epstein, E. S. Shubina
    Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds
  • Inorg. Chem., 2011, 50, 444-450
    O.N. Kazheva, G.G. Alexandrov, A.V. Kravchenko, I.D. Kosenko, I.A. Lobanova, I.B. Sivaev, O. A. Filippov, E. S. Shubina, V.I. Bregadze, V.A. Starodub, L.V. Titov, L.I. Buravov, O.A. Dyachenko
    Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion
  • Inorg. Chem., 2011, 50, 12539-52
    A. Béthegnies, V. A. Kirkina, O. A. Filippov, J.-C. Daran, N. V. Belkova, E. S. Shubina, R. Poli
    Coordination and Organometallic Chemistry of Relevance to the Rhodium-Based Catalyst for Ethylene Hydroamination
@ LMH | Laboratory Of Metal Hydrides 2001 - 2023