MH-Lab | Evgenii I. Gutsul

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Evgenii I. Gutsul

Evgenii I. Gutsul

Senior Researcher

Personal Info

Date Of Birth

08/03/1974

Address

A.N. Nesmeyanov Institute of Organoelement Compounds
Russian Academy of Sciences (INEOS RAS)
Vavilov St. 28, 119991, Moscow, Russia

Phone

+7(499)1356448

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Academic Degree

1997: M.Sc. Chemistry Department, Moscow State University, Moscow, Russia
2004 – Ph.D. thesis "Classical and non-classical transition metal hydrides in acid-base equilibriums" INEOS RAS, Moscow, Russia under supervision PhD N.Belkova Member of international research group of INTAS 00-0176 3-year project "Proton-transfer reactions orchestrated by transition metal hydrides"

Experience

1999-2002: Post-graduate Student, INEOS RAS, Moscow, Russia
2002- 2019: researcher "Laboratory of Metal Hydrides"
2019- present: senior researcher "Laboratory of Metal Hydrides"

Scientific Interests

Molecular spectroscopy of transition metal pi-complexes and hydrides, intermolecular interactions, hydrogen bonding and proton transfer

Awards

INTAS Postdoctoral Fellowship 04-83-2583, 2005-2007 “Proton transfer reactions in organometallic chemistry mediated by unconventional hydrogen bonded complexes”

Additional

Member of international research group in Research Training Network: Transition Metal Chemistry and Catalysis in Aqueous Media (AQUACHEM) Contract MRTN-CT-2003-503864. Individual grants according the RFBR programme “Young Scientists of Russia” in 2002 and 2003.

Publications

2023

Inorganics, 2023, 11(5), 212, DOI: 10.3390/inorganics11050212
V. A. Kirkina, V. Kulikova, E. I. Gutsul, Gafurov Zufar N., Sakhapov Ilias F., Yakhvarov Dmitry G., Nelyubina Yulia V., O. A. Filippov, E. S. Shubina, N. V. Belkova
Role of Non-Covalent Interactions in the Reactions between Palladium Hydrido Complex with Amidoarylphosphine Pincer Ligand and Brønsted Acids
Organometallics, 2023, DOI: 10.1021/acs.organomet.3c00125
E. S. Osipova, Sedlova D.V., E. I. Gutsul, Nelyubina Yulia V., Dorovatovsii Pavel V., L. M. Epstein, O. A. Filippov, E. S. Shubina, N. V. Belkova
Reactivity of heterobimetallic ion pairs in formic acid dehydrogenation
Pharmaceutics, 2023, 15(4), 1088, DOI: 10.3390/pharmaceutics15041088
Diana V. Aleksanyan, Aleksandr V. Konovalov, Svetlana G. Churusova, Ekaterina Yu. Rybalkina, Alexander S. Peregudov, Svetlana A. Aksenova, E. I. Gutsul, Zinaida S. Klemenkova, Vladimir A. Kozlov
Modulation of the Cytotoxic Properties of Pd(II) Complexes Based on Functionalized Carboxamides Featuring Labile Phosphoryl Coordination Sites

2022

Molecules, 2022, 27(23), 8505, DOI: 10.3390/molecules27238505
A. N. Bilyachenko, Khrustalev V. N., E. I. Gutsul, Zueva A. Y., Korlyukov A. A., Shul'pina L. S., Ikonnikov N. S., Dorovatovskii P. V., D. Gelman, E. S. Shubina, G. B. Shul’pin
Hybrid Silsesquioxane/Benzoate Cu7-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity
J. Org. Chem, 2022, 87(18), 12182-12195, DOI: 10.1021/acs.joc.2c01339
Afanasyev Oleg, Kliuev Fedor, Tsygankov Alexey, Nelyubina Yulia, E. I. Gutsul, Novikov Valentin, Chusov Denis
Fluoride Additive as a Simple Tool to Qualitatively Improve Performance of Nickel-Catalyzed Asymmetric Michael Addition of Malonates to Nitroolefins
Inorg. Chem., 2022, 61(40), 16081-16092, DOI: 10.1021/acs.inorgchem.2c02478
Nekrasov Roman I., Peganova Tat’yana A., Fedyanin Ivan V., E. I. Gutsul, O. A. Filippov, N. V. Belkova, Kalsin Alexander M.
Versatile Reactivity of Half-Sandwich Rhodium(III) Iminophosphonamide Complexes
Inorg. Chem. Front., 2022, 9(17), 4525-4537, DOI: 10.1039/d2qi01054b
G. S. Astakhov, Khrustalev Victor N., M. S. Dronova, E. I. Gutsul, Korlyukov Alexander, D. Gelman, Zubavichus Yan V., Novichkov Daniil, Trigub Alexander, E. S. Shubina, A. N. Bilyachenko
Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
Inorg. Chem., 2022, 61(37), 14800-14814, DOI: 10.1021/acs.inorgchem.2c02217
A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., G. S. Astakhov, Zueva Anna Y., Zubavichus Yan V., Kirillova Marina V., Shul’pina Lidia S., Ikonnikov Nikolay S., Dorovatovskii Pavel V., E. S. Shubina, A. Kirillov, G. B. Shul’pin
Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
J. Inorg. Biochem., 2022, 235, 111908, DOI: 10.1016/j.jinorgbio.2022.111908
Churusova Svetlana G., Aleksanyan Diana V., Rybalkina Ekaterina Yu., E. I. Gutsul, Peregudov Alexander S., Klemenkova Zinaida S., Nelyubina Yulia V., Buyanovskaya Anastasiya G., Kozlov Vladimir A.
Pincer–dipeptide and pseudodipeptide conjugates: synthesis and bioactivity studies

2021

Inorg. Chem., 2021, 60(13), 9880-9898, DOI: 10.1021/acs.inorgchem.1c01138
Churusova S.G., Aleksanyan D.V., Rybalkina E.Y., Susova O.Y., Peregudov A.S., Brunova V.V., E. I. Gutsul, Klemenkova Z.S., Nelyubina Y.V., Glushko V.N., Kozlov V.A.
Palladium(II) pincer complexes of functionalized amides with S-modified cysteine and homocysteine residues: cytotoxic activity and different aspects of their biological effect on living cells
Chemical science, 2021, 12, 3682-3692, DOI: DOI: 10.1039/D0SC06114J
E. S. Osipova, E. Gulyaeva, E. I. Gutsul, V. A. Kirkina, A. A. Pavlov, Y. V. Nelyubina, A. Rossin, M. Peruzzini, L. M. Epstein, N. V. Belkova, O. A. Filippov, E. S. Shubina
Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”

2019

Dalton Trans., 2019, 48, 12720 - 12729, DOI: 10.1039/C9DT02176K
S. V. Safronov, E. I. Gutsul, I. E. Golub, F. M. Dolgushin, Y. V. Nelyubina, O. A. Filippov, L. M. Epstein, A. S. Peregudov, N. V. Belkova, E. S. Shubina
Synthesis, Structural Properties and Reactivity of Ruthenocene-based Pincer Pd(II) Tetrahydroborate

2018

Inorg. Chem., 2018, 57 (1), 528–534, DOI: 10.1021/acs.inorgchem.7b02881
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, A. N. Kulakova, X. Bantreil, F. Lamaty, M. M. Levitsky, E. I. Gutsul, E. S. Shubina, G. B. Shul’pin
Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
Crystal Growth and Design, 2018, 18 (4), 2452–2457, DOI: 10.1021/acs.cgd.8b00082
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, A. V. Vologzhanina, G. Astakhov, E. I. Gutsul, E. S. Shubina, M. M. Levitsky
High-nuclearity (Cu8-based) cage silsesquioxanes: Synthesis and structural study

2017

Inorg. Chim. Acta, 2017, 456, 113-119, DOI: 10.1016/j.ica.2016.10.037
I. E. Golub, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, N. V. Belkova
The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis
Eur. J. Inorg. Chem., 2017, 4673–4682, DOI: 10.1002/ejic.201700624
I. E. Golub, O. A. Filippov, N. V. Belkova, E. I. Gutsul, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ³-P-CH₃C(CH₂CH₂PPh₂)₃}RuH(η²-BH₄)]
Crystals, 2017, 7(10), 318-335, DOI: 10.3390/cryst7100318
N. V. Belkova, I. E. Golub, E. I. Gutsul, K. A. Lyssenko, A. S. Peregudov, V. D. Makhaev, O. A. Filippov, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
Inorg. Chem., 2017, 56 (16), 9834–9850, DOI: 10.1021/acs.inorgchem.7b01348
Svetlana G. Churusova, Diana V. Aleksanyan, Ekaterina Yu. Rybalkina, Olga Yu. Susova, Valentina V. Brunova, Rinat R. Aysin, Yulia V. Nelyubina, Alexander S. Peregudov, E. I. Gutsul, Zinaida S. Klemenkova, and Vladimir A. Kozlov
Highly Cytotoxic Palladium(II) Pincer Complexes Based on Picolinylamides Functionalized with Amino Acids Bearing Ancillary S-Donor Groups
Inorg. Chem., 2017, 56 (24), 15026–15040, DOI: 10.1021/acs.inorgchem.7b02320
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, A. A. Korlyukov, Y. V. Zubavichus, P. V. Dorovatovskii, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, L. S. Shul’pina, E. S. Shubina, E. I. Gutsul, I. A. Mikhailov, N. S. Ikonnikov, U. S. Tsareva, G. B. Shul’pin
Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
Eur. J. Inorg. Chem., 2017, 48, 5663–5669, DOI: 10.1002/ejic.201701160
M.M. Vinogradov, D.S. Perekalin, E. I. Gutsul, V.V. Novikov, A.F. Smol'yakov, H. Wadepohl, A.R. Kudinov, D.A. Loginov
Cluster [Co₃(CO)₃(µ₂-CO)₃(µ₃-C₈H₈)]^– as a Ligand: Experimental and Theoretical Study

2016

Eur. J. Inorg. Chem., 2016, 56–63, DOI: 10.1002/ejic.201501083
E. M. Kozinets (Titova), G. A. Silantyev, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, Fedor M. Dolgushin, N. V. Belkova
PCP Pincer Iridium Chemistry: Coordination of Pyridines to (tBuPCP)IrH(Cl)

2015

Russ. Chem. Bull., 2015, 64(12), 2806–2810, DOI: 10.1007/s11172-015-1230-x
G. A. Silantyev, E. M. Kozinets (Titova), O. A. Filippov, E. I. Gutsul, D. Gelman, N. V. Belkova
Hydrogen bonds, coordination isomerism, and catalytic dehydrogenation of alcohols with the bifunctional iridium pincer complex (HOCH2)2(PCsp3P)IrHCl

2014

Inorg. Chem., 2014, 53, 1080–1090, DOI: 10.1021/ic4026206
N. V. Belkova, E. V. Bakhmutova-Albert, E. I. Gutsul, V. I. Bakhmutov, I. E. Golub, O. A. Filippov, L. M. Epstein, M. Peruzzini, A. Rossin, F. Zanobini, E. S. Shubina
Dihydrogen bonding in complex (PP3)RuH(η1-BH4) featuring two proton-accepting hydride sites: experimental and theoretical studies
Russ. Chem. Bull., 2014, 63, 2428-2433, DOI: 10.1007/s11172-014-0758-5
O. A. Filippov, I. E. Golub, E. S. Osipova, V. A. Kirkina, E. I. Gutsul, N. V. Belkova
Transition metal hydride M—H bond activation upon the formation of complexes with acids and bases

2012

Inorg. Chem., 2012, 51, 6486-6497
I. E. Golub, O. A. Filippov, E. I. Gutsul, N. V. Belkova, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond

2011

Dalton Trans., 2011, 40, 1535-46?
D V Aleksanyan, V A Kozlov, Y V Nelyubina, K A Lyssenko, L N Puntus, E. I. Gutsul, N E Shepel, A A Vasil'ev, P V Petrovskii, I L Odinets
Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS'-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides