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Evgenii I. Gutsul

Senior Researcher
Evgenii I. Gutsul
Personal Info
Date Of Birth
08/03/1974
Address
A.N. Nesmeyanov Institute of Organoelement Compounds
Russian Academy of Sciences (INEOS RAS)
Vavilov St. 28, 119991, Moscow, Russia
Phone
+7(499)1356448
Email
Send Email
Academic Degree
1997: M.Sc. Chemistry Department, Moscow State University, Moscow, Russia
2004 – Ph.D. thesis "Classical and non-classical transition metal hydrides in acid-base equilibriums" INEOS RAS, Moscow, Russia under supervision PhD N.Belkova Member of international research group of INTAS 00-0176 3-year project "Proton-transfer reactions orchestrated by transition metal hydrides"
Experience
1999-2002: Post-graduate Student, INEOS RAS, Moscow, Russia
2002- 2019: researcher "Laboratory of Metal Hydrides"
2019- present: senior researcher "Laboratory of Metal Hydrides"
Scientific Interests
Molecular spectroscopy of transition metal pi-complexes and hydrides, intermolecular interactions, hydrogen bonding and proton transfer
Awards
INTAS Postdoctoral Fellowship 04-83-2583, 2005-2007 “Proton transfer reactions in organometallic chemistry mediated by unconventional hydrogen bonded complexes”
Additional
Member of international research group in Research Training Network: Transition Metal Chemistry and Catalysis in Aqueous Media (AQUACHEM) Contract MRTN-CT-2003-503864. Individual grants according the RFBR programme “Young Scientists of Russia” in 2002 and 2003.
Publications
2024
  • Dalton Trans., 2024, 53(11), 4976-4983, DOI: 10.1039/d3dt04388f
    Rumyantsev Andrey V., Bushkov Nikolai S., Ryzhikova Margarita A., Zhizhin Anton A., Takazova Rina, Talanova Valeria, E. I. Gutsul, Novikov Roman A., Zhizhko Pavel A., Zarubin Dmitry N.
    Readily available Ti-based in situ catalytic system for oxo/imido heterometathesis
  • ChemPlusChem, 2024, e202400029, DOI: 10.1002/cplu.202400029
    Bushkov Nikolai S., Rumyantsev Andrey V., Zhizhin Anton A., Strelkova Tatyana V., Novikov Roman A., E. I. Gutsul, Takazova Rina U., Kitaeva Dinara Kh, Ustynyuk Nikolai A., Zhizhko Pavel A., Zarubin Dmitry N.
    Tungsten Oxide Dispersed on Silica as Robust and Readily Available Oxo/Imido Heterometathesis Catalyst
  • Chem. Eur. J., 2024, e202401164, DOI: 10.1002/chem.202401164
    A. Yu. Zueva, A. N. Bilyachenko, Arteev I. S., Khrustalev Victor N., Dorovatovskii Pavel V., Shul’pina Lidia S., Ikonnikov Nikolay S., E. I. Gutsul, Rahimov Karim G., E. S. Shubina, Conceição Nuno Reis, Mahmudov Kamran T., Guedes da Silva M.Fátima C, Pombeiro Armando J.L.
    A family of hexacopper phenylsilsesquioxane/acetate complexes: synthesis, solvent‐controlled cage structures, and catalytic activity
  • Mendeleev Communications, 2024, 34, 192–194, DOI: 10.1016/j.mencom.2024.02.010
    Stepwise carbon dioxide hydrosylilation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(But PCP)]
  • Journal of Electroanalytical Chemistry, 2024, DOI: 10.1016/j.jelechem.2024.118084
    Alexey A. Kagilev, Zufar N. Gafurov, Il'yas F. Sakhapov, Vladimir I. Morozov, Artyom O. Kantyukov, Ruslan B. Zaripov, Ekaterina M. Zueva, Ilya K. Mikhailov, Alexey B. Dobrynin, V. Kulikova, V. A. Kirkina, E. I. Gutsul, E. S. Shubina, N. V. Belkova, Oleg G. Sinyashin, Dmitry G. Yakhvarov
    Electrochemical generation and in situ EPR- and UV–vis- observation of aminyl-radical diarylamido/bis(phosphine) pincer complexes of Ni, Pd and Pt
2023
  • Inorg. Chem., 2023, 62(38), 15537-15549, DOI: 10.1021/acs.inorgchem.3c02040
    A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., Chusova Olga, Dorovatovskii Pavel V., Aliyeva Vusala A., Paninho Ana B., Nunes Ana V.M., Mahmudov Kamran T., E. S. Shubina, Pombeiro Armando J.L
    A Family of сagelike Mn-silsesquioxane/bathophenanthroline complexes: synthesis, structure, and catalytic and antifungal activity
  • Crystal Growth and Design, 2023, 23(12), 8707–8717, DOI: 10.1021/acs.cgd.3c00863
    A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., Dorovatovskii Pavel V., E. S. Shubina, Guari Yannick, Félix Gautier, J. Larionova, Mahmoud Abdallah G., Pombeiro Armando J.L
    Cagelike manganesesilsesquioxane complexes: synthesis via an acetone approach, structure, and catalytic activity for toluene oxidation
  • Inorganics, 2023, 11(5), 212, DOI: 10.3390/inorganics11050212
    V. A. Kirkina, V. Kulikova, E. I. Gutsul, Gafurov Zufar N., Sakhapov Ilias F., Yakhvarov Dmitry G., Nelyubina Yulia V., O. A. Filippov, E. S. Shubina, N. V. Belkova
    Role of Non-Covalent Interactions in the Reactions between Palladium Hydrido Complex with Amidoarylphosphine Pincer Ligand and Brønsted Acids
  • Organometallics, 2023, 42(18), 2651–2660, DOI: 10.1021/acs.organomet.3c00125
    E. S. Osipova, Sedlova D.V., E. I. Gutsul, Nelyubina Yulia V., Dorovatovsii Pavel V., L. M. Epstein, O. A. Filippov, E. S. Shubina, N. V. Belkova
    Reactivity of heterobimetallic ion pairs in formic acid dehydrogenation
  • Pharmaceutics, 2023, 15(4), 1088, DOI: 10.3390/pharmaceutics15041088
    Diana V. Aleksanyan, Aleksandr V. Konovalov, Svetlana G. Churusova, Ekaterina Yu. Rybalkina, Alexander S. Peregudov, Svetlana A. Aksenova, E. I. Gutsul, Zinaida S. Klemenkova, Vladimir A. Kozlov
    Modulation of the Cytotoxic Properties of Pd(II) Complexes Based on Functionalized Carboxamides Featuring Labile Phosphoryl Coordination Sites
  • Russian Journal of Inorganic Chemistry, 2023, 68(9), 1200-1208, DOI: 10.1134/S0036023623601320
    V. Kulikova, V. A. Kirkina, E. I. Gutsul, Gafurov Z. N., Kagliev A. A., Sakhapov I. F., Yakhvarov D. G., O. A. Filippov, N. V. Belkova, E. S. Shubina
    Basicity and hydride-donating ability of palladium(II) hydride complex with diarylamido-bis-phosphine pincer ligand
2022
  • Molecules, 2022, 27(23), 8505, DOI: 10.3390/molecules27238505
    A. N. Bilyachenko, Khrustalev V. N., E. I. Gutsul, A. Yu. Zueva, Korlyukov A. A., Shul'pina L. S., Ikonnikov N. S., Dorovatovskii P. V., D. Gelman, E. S. Shubina, G. B. Shul’pin
    Hybrid Silsesquioxane/Benzoate Cu7-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity
  • J. Org. Chem, 2022, 87(18), 12182-12195, DOI: 10.1021/acs.joc.2c01339
    Afanasyev Oleg, Kliuev Fedor, Tsygankov Alexey, Nelyubina Yulia, E. I. Gutsul, Novikov Valentin, Chusov Denis
    Fluoride Additive as a Simple Tool to Qualitatively Improve Performance of Nickel-Catalyzed Asymmetric Michael Addition of Malonates to Nitroolefins
  • Inorg. Chem., 2022, 61(40), 16081-16092, DOI: 10.1021/acs.inorgchem.2c02478
    Nekrasov Roman I., Peganova Tat’yana A., Fedyanin Ivan V., E. I. Gutsul, O. A. Filippov, N. V. Belkova, Kalsin Alexander M.
    Versatile Reactivity of Half-Sandwich Rhodium(III) Iminophosphonamide Complexes
  • Inorg. Chem. Front., 2022, 9(17), 4525-4537, DOI: 10.1039/d2qi01054b
    G. S. Astakhov, Khrustalev Victor N., M. S. Dronova, E. I. Gutsul, Korlyukov Alexander, D. Gelman, Zubavichus Yan V., Novichkov Daniil, Trigub Alexander, E. S. Shubina, A. N. Bilyachenko
    Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
  • Inorg. Chem., 2022, 61(37), 14800-14814, DOI: 10.1021/acs.inorgchem.2c02217
    A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., G. S. Astakhov, A. Yu. Zueva, Zubavichus Yan V., Kirillova Marina V., Shul’pina Lidia S., Ikonnikov Nikolay S., Dorovatovskii Pavel V., E. S. Shubina, A. Kirillov, G. B. Shul’pin
    Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
  • J. Inorg. Biochem., 2022, 235, 111908, DOI: 10.1016/j.jinorgbio.2022.111908
    Churusova Svetlana G., Aleksanyan Diana V., Rybalkina Ekaterina Yu., E. I. Gutsul, Peregudov Alexander S., Klemenkova Zinaida S., Nelyubina Yulia V., Buyanovskaya Anastasiya G., Kozlov Vladimir A.
    Pincer–dipeptide and pseudodipeptide conjugates: synthesis and bioactivity studies
2021
  • Inorg. Chem., 2021, 60(13), 9880-9898, DOI: 10.1021/acs.inorgchem.1c01138
    Churusova S.G., Aleksanyan D.V., Rybalkina E.Y., Susova O.Y., Peregudov A.S., Brunova V.V., E. I. Gutsul, Klemenkova Z.S., Nelyubina Y.V., Glushko V.N., Kozlov V.A.
    Palladium(II) pincer complexes of functionalized amides with S-modified cysteine and homocysteine residues: cytotoxic activity and different aspects of their biological effect on living cells
  • Chemical science, 2021, 12, 3682-3692, DOI: DOI: 10.1039/D0SC06114J
    E. S. Osipova, E. Gulyaeva, E. I. Gutsul, V. A. Kirkina, A. A. Pavlov, Y. V. Nelyubina, A. Rossin, M. Peruzzini, L. M. Epstein, N. V. Belkova, O. A. Filippov, E. S. Shubina
    Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
2019
2018
2017
  • Inorg. Chim. Acta, 2017, 456, 113-119, DOI: 10.1016/j.ica.2016.10.037
    The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis
  • Eur. J. Inorg. Chem., 2017, 4673–4682, DOI: 10.1002/ejic.201700624
    Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ3-P-CH3C(CH2CH2PPh2)3}RuH(η2-BH4)]
  • Crystals, 2017, 7(10), 318-335, DOI: 10.3390/cryst7100318
    N. V. Belkova, I. E. Golub, E. I. Gutsul, K. A. Lyssenko, A. S. Peregudov, V. D. Makhaev, O. A. Filippov, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
    Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
  • Inorg. Chem., 2017, 56 (16), 9834–9850, DOI: 10.1021/acs.inorgchem.7b01348
    Svetlana G. Churusova, Diana V. Aleksanyan, Ekaterina Yu. Rybalkina, Olga Yu. Susova, Valentina V. Brunova, Rinat R. Aysin, Yulia V. Nelyubina, Alexander S. Peregudov, E. I. Gutsul, Zinaida S. Klemenkova, and Vladimir A. Kozlov
    Highly Cytotoxic Palladium(II) Pincer Complexes Based on Picolinylamides Functionalized with Amino Acids Bearing Ancillary S-Donor Groups
  • Inorg. Chem., 2017, 56 (24), 15026–15040, DOI: 10.1021/acs.inorgchem.7b02320
    A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, A. A. Korlyukov, Y. V. Zubavichus, P. V. Dorovatovskii, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, L. S. Shul’pina, E. S. Shubina, E. I. Gutsul, I. A. Mikhailov, N. S. Ikonnikov, U. S. Tsareva, G. B. Shul’pin
    Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
  • Eur. J. Inorg. Chem., 2017, 48, 5663–5669, DOI: 10.1002/ejic.201701160
    M.M. Vinogradov, D.S. Perekalin, E. I. Gutsul, V.V. Novikov, A.F. Smol'yakov, H. Wadepohl, A.R. Kudinov, D.A. Loginov
    Cluster [Co3(CO)32-CO)33-C8H8)] as a Ligand: Experimental and Theoretical Study
2016
2015
2014
2012
2011
  • Dalton Trans., 2011, 40, 1535-46?
    D V Aleksanyan, V A Kozlov, Y V Nelyubina, K A Lyssenko, L N Puntus, E. I. Gutsul, N E Shepel, A A Vasil'ev, P V Petrovskii, I L Odinets
    Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS'-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides