Evgenii I. Gutsul

Senior Researcher
Evgenii I. Gutsul
Personal Info
Date Of Birth
A.N. Nesmeyanov Institute of Organoelement Compounds
Russian Academy of Sciences (INEOS RAS)
Vavilov St. 28, 119991, Moscow, Russia
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Academic Degree
1997: M.Sc. Chemistry Department, Moscow State University, Moscow, Russia
2004 – Ph.D. thesis "Classical and non-classical transition metal hydrides in acid-base equilibriums" INEOS RAS, Moscow, Russia under supervision PhD N.Belkova Member of international research group of INTAS 00-0176 3-year project "Proton-transfer reactions orchestrated by transition metal hydrides"
1999-2002: Post-graduate Student, INEOS RAS, Moscow, Russia
2002- 2019: researcher "Laboratory of Metal Hydrides"
2019- present: senior researcher "Laboratory of Metal Hydrides"
Scientific Interests
Molecular spectroscopy of transition metal pi-complexes and hydrides, intermolecular interactions, hydrogen bonding and proton transfer
INTAS Postdoctoral Fellowship 04-83-2583, 2005-2007 “Proton transfer reactions in organometallic chemistry mediated by unconventional hydrogen bonded complexes”
Member of international research group in Research Training Network: Transition Metal Chemistry and Catalysis in Aqueous Media (AQUACHEM) Contract MRTN-CT-2003-503864. Individual grants according the RFBR programme “Young Scientists of Russia” in 2002 and 2003.
  • Molecules, 2022, 27(23), 8505, DOI: 10.3390/molecules27238505
    A. N. Bilyachenko, Khrustalev V. N., E. I. Gutsul, Zueva A. Y., Korlyukov A. A., Shul'pina L. S., Ikonnikov N. S., Dorovatovskii P. V., D. Gelman, E. S. Shubina, G. B. Shul’pin
    Hybrid Silsesquioxane/Benzoate Cu7-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity
  • J. Org. Chem, 2022, 87(18), 12182-12195, DOI: 10.1021/acs.joc.2c01339
    Afanasyev Oleg, Kliuev Fedor, Tsygankov Alexey, Nelyubina Yulia, E. I. Gutsul, Novikov Valentin, Chusov Denis
    Fluoride Additive as a Simple Tool to Qualitatively Improve Performance of Nickel-Catalyzed Asymmetric Michael Addition of Malonates to Nitroolefins
  • Inorg. Chem., 2022, 61(40), 16081-16092, DOI: 10.1021/acs.inorgchem.2c02478
    Nekrasov Roman I., Peganova Tat’yana A., Fedyanin Ivan V., E. I. Gutsul, O. A. Filippov, N. V. Belkova, Kalsin Alexander M.
    Versatile Reactivity of Half-Sandwich Rhodium(III) Iminophosphonamide Complexes
  • Inorg. Chem. Front., 2022, 9(17), 4525-4537, DOI: 10.1039/d2qi01054b
    G. S. Astakhov, Khrustalev Victor N., M. S. Dronova, E. I. Gutsul, Korlyukov Alexander, D. Gelman, Zubavichus Yan V., Novichkov Daniil, Trigub Alexander, E. S. Shubina, A. N. Bilyachenko
    Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
  • Inorg. Chem., 2022, 61(37), 14800-14814, DOI: 10.1021/acs.inorgchem.2c02217
    A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., G. S. Astakhov, Zueva Anna Y., Zubavichus Yan V., Kirillova Marina V., Shul’pina Lidia S., Ikonnikov Nikolay S., Dorovatovskii Pavel V., E. S. Shubina, A. Kirillov, G. B. Shul’pin
    Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
  • J. Inorg. Biochem., 2022, 235, 111908, DOI: 10.1016/j.jinorgbio.2022.111908
    Churusova Svetlana G., Aleksanyan Diana V., Rybalkina Ekaterina Yu., E. I. Gutsul, Peregudov Alexander S., Klemenkova Zinaida S., Nelyubina Yulia V., Buyanovskaya Anastasiya G., Kozlov Vladimir A.
    Pincer–dipeptide and pseudodipeptide conjugates: synthesis and bioactivity studies
  • Inorg. Chem., 2021, 60(13), 9880-9898, DOI: 10.1021/acs.inorgchem.1c01138
    Churusova S.G., Aleksanyan D.V., Rybalkina E.Y., Susova O.Y., Peregudov A.S., Brunova V.V., E. I. Gutsul, Klemenkova Z.S., Nelyubina Y.V., Glushko V.N., Kozlov V.A.
    Palladium(II) pincer complexes of functionalized amides with S-modified cysteine and homocysteine residues: cytotoxic activity and different aspects of their biological effect on living cells
  • Chemical science, 2021, 12, 3682-3692, DOI: DOI: 10.1039/D0SC06114J
    E. S. Osipova, E. Gulyaeva, E. I. Gutsul, V. A. Kirkina, A. A. Pavlov, Y. V. Nelyubina, A. Rossin, M. Peruzzini, L. M. Epstein, N. V. Belkova, O. A. Filippov, E. S. Shubina
    Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
  • Inorg. Chim. Acta, 2017, 456, 113-119, DOI: 10.1016/j.ica.2016.10.037
    The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis
  • Eur. J. Inorg. Chem., 2017, 4673–4682, DOI: 10.1002/ejic.201700624
    Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ3-P-CH3C(CH2CH2PPh2)3}RuH(η2-BH4)]
  • Crystals, 2017, 7(10), 318-335, DOI: 10.3390/cryst7100318
    N. V. Belkova, I. E. Golub, E. I. Gutsul, K. A. Lyssenko, A. S. Peregudov, V. D. Makhaev, O. A. Filippov, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
    Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
  • Inorg. Chem., 2017, 56 (16), 9834–9850, DOI: 10.1021/acs.inorgchem.7b01348
    Svetlana G. Churusova, Diana V. Aleksanyan, Ekaterina Yu. Rybalkina, Olga Yu. Susova, Valentina V. Brunova, Rinat R. Aysin, Yulia V. Nelyubina, Alexander S. Peregudov, E. I. Gutsul, Zinaida S. Klemenkova, and Vladimir A. Kozlov
    Highly Cytotoxic Palladium(II) Pincer Complexes Based on Picolinylamides Functionalized with Amino Acids Bearing Ancillary S-Donor Groups
  • Inorg. Chem., 2017, 56 (24), 15026–15040, DOI: 10.1021/acs.inorgchem.7b02320
    A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, A. A. Korlyukov, Y. V. Zubavichus, P. V. Dorovatovskii, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, L. S. Shul’pina, E. S. Shubina, E. I. Gutsul, I. A. Mikhailov, N. S. Ikonnikov, U. S. Tsareva, G. B. Shul’pin
    Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
  • Eur. J. Inorg. Chem., 2017, 48, 5663–5669, DOI: 10.1002/ejic.201701160
    M.M. Vinogradov, D.S. Perekalin, E. I. Gutsul, V.V. Novikov, A.F. Smol'yakov, H. Wadepohl, A.R. Kudinov, D.A. Loginov
    Cluster [Co3(CO)32-CO)33-C8H8)] as a Ligand: Experimental and Theoretical Study
  • Dalton Trans., 2011, 40, 1535-46?
    D V Aleksanyan, V A Kozlov, Y V Nelyubina, K A Lyssenko, L N Puntus, E. I. Gutsul, N E Shepel, A A Vasil'ev, P V Petrovskii, I L Odinets
    Synthesis, catalytic activity, and photophysical properties of 5,6-membered Pd and Pt SCS'-pincer complexes based on thiophosphorylated 3-amino(hydroxy)benzoic acid thioanilides