MH-Lab | Ekaterina M. Kozinets (Titova)

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Ekaterina M. Kozinets (Titova)

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Ekaterina M. Kozinets (Titova)

Researcher

Personal Info

Date Of Birth

07/18/1987

Address

Moscow, Vavilova str, 28

Phone

+74991356448

Send Email

Academic Degree

PhD

Experience

Ph.D. A.N.Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (Moscow) / Laboratoire de Chimie de Coordination, Universite Paul Sabatier (Toulouse, France) (2010-2013) Engineer. D. I. Mendeleyev University of Chemical Technology of Russia (Moscow, Russia) (2004-2010)

Scientific Interests

The synthesis of organometalic compounds, molecular spectroscopy, catalysis, mechanistic investigations

Publications

2023

Russian Chemical Reviews, 2023, 92(11), RCR5099, DOI: 10.59761/rcr5099
E. M. Kozinets (Titova), A. A. Titov, E. S. Shubina
Functional pyrazolylpyridine ligands in the design of metal complexes with tunable properties

2022

Molecules, 2022, 27(23), 8575, DOI: 10.3390/molecules27238575
Laskova J., Serdyukov A., Kosenko I., Ananyev I., E. M. Kozinets (Titova), Druzina A., Sivaev I., Antonets A.A., Nazarov A. A., Bregadze V. I.
New Azido Coumarins as Potential Agents for Fluorescent Labeling and Their “Click” Chemistry Reactions for the Conjugation with closo-Dodecaborate Anion
Molecules, 2022, 27(19), 6205, DOI: 10.3390/molecules27196205
A. N. Bilyachenko, Khrustalev V.N., A. Yu. Zueva, E. M. Kozinets (Titova), G. S. Astakhov, Zubavichus Y.V., Dorovatovskii P.V., Korlyukov A.S., Shul'pina L.S., E. S. Shubina, Kozlov Y.N., Ikonnikov N.S., D. Gelman, G. B. Shul’pin
A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity

2020

Inorg. Chem., 2020, 59(17), 11962–11975, DOI: 10.1021/acs.inorgchem.0c00797
V. A. Kirkina, G. A. Silantyev, De-botton Sophie, O. A. Filippov, E. M. Kozinets (Titova), Pavlov Alexander, N. V. Belkova, L. M. Epstein, D. Gelman, E. S. Shubina
Stereoisomerism as an Origin of Different Reactivity of Ir(III) PC(sp3)P Pincer Catalysts

2019

Eur. J. Inorg. Chem., 2019, 2019 (45), 4855-4861, DOI: 10.1002/ejic.201901050
S. K. Emashova, A. A. Titov, O. A. Filippov, A.F. Smol'yakov, E. M. Kozinets (Titova), L. M. Epstein, E. S. Shubina
Luminescent AgI Complexes with 2,2′-Bipyridine Derivatives Featuring [Ag-(CF3)2Pyrazolate]4 Units
Eur. J. Inorg. Chem., 2019, 10, 1389-1397, DOI: 10.1002/ejic.201801341
E. S. Osipova, E. Gulyaeva, O. A. Filippov, S. V. Safronov, A. A. Pavlov, A. V. Polukeev, V. A. Kirkina, E. M. Kozinets (Titova), E. S. Shubina, N. V. Belkova
Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes
Chemical Communications, 2019, 55, 290-293, DOI: 10.1039/C8CC08592G
A. A. Titov, V. A. Larionov, A. F. Smol’yakov, M. I. Godovikova, E. M. Kozinets (Titova), V. I. Maleev, E. S. Shubina
Interaction of a trinuclear copper(I) pyrazolate with alkynes and carbon–carbon triple bond activation
Eur. J. Inorg. Chem., 2019, 6, 821-827, DOI: 10.1002/ejic.201801318
A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., K. F. Baranova, E. M. Kozinets (Titova), Averin Aleksey A., E. S. Shubina
Dinuclear Cu(I) and Ag(I) pyrazolates supported with tertiary phosphines: Synthesis, structures and photophysical properties

2018

Organometallics, 2018, 37 (18), 3142-3153, DOI: 10.1021/acs.organomet.8b00488
L. Luconi, E. S. Osipova, G. Giambastiani, M. Peruzzini, A. Rossin, N. V. Belkova, O. A. Filippov, E. M. Kozinets (Titova), A. A. Pavlov, E. S. Shubina
Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance

2017

Journal of Molecular Catalysis A: Chemical, 2017, 426, 376-380, DOI: 10.1016/j.molcata.2016.08.014
E. M. Kozinets (Titova), Rahaman S. M. W, E. S. Shubina, R. Poli, N. V. Belkova, Manoury E.
Catalytic Redox Isomerization of Allylic Alcohols with Rhodium and Iridium Complexes with Ferrocene Phosphine-Thioether Ligands
ACS catalysis, 2017, 7, 2325-2333, DOI: 10.1021/acscatal.6b03207
E. M. Kozinets (Titova), E. S. Osipova, Pavlov Alexander A., O. A. Filippov, Safronov Sergey V., E. S. Shubina, N. V. Belkova
Mechanism of Dimethylamine–Borane Dehydrogenation Catalyzed by an Iridium(III) PCP-Pincer Complex
J. Organomet. Chem., 2017, 827, 86-95, DOI: 10.1016/j.jorganchem.2016.11.010
E. M. Kozinets (Titova), E. S. Osipova, E. Gulyaeva, V.N. Torocheshnikov, A.A. Pavlov, G. A. Silantyev, O. A. Filippov, E. S. Shubina, N. V. Belkova
Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases

2016

Eur. J. Inorg. Chem., 2016, 56–63, DOI: 10.1002/ejic.201501083
E. M. Kozinets (Titova), G. A. Silantyev, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, Fedor M. Dolgushin, N. V. Belkova
PCP Pincer Iridium Chemistry: Coordination of Pyridines to (tBuPCP)IrH(Cl)
Eur. J. Inorg. Chem., 2016, 1415–1424, DOI: 10.1002/ejic.201600034
E. S. Osipova, N. V. Belkova, L. M. Epstein, O. A. Filippov, V. A. Kirkina, E. M. Kozinets (Titova), A. Rossin, M. Peruzzini, E. S. Shubina
Dihydrogen Bonding and Proton Transfer from MH vs OH acids to Group 10 Metal Hydrides (tBuPCP)MH [tBuPCP = 3-2,6-(tBu2PCH2)2C6H3; M = Ni, Pd]

2015

Russ. Chem. Bull., 2015, 64(12), 2806–2810, DOI: 10.1007/s11172-015-1230-x
G. A. Silantyev, E. M. Kozinets (Titova), O. A. Filippov, E. I. Gutsul, D. Gelman, N. V. Belkova
Hydrogen bonds, coordination isomerism, and catalytic dehydrogenation of alcohols with the bifunctional iridium pincer complex (HOCH2)2(PCsp3P)IrHCl

2014

Russ. Chem. Bull., 2014, 63, 2434-2437, DOI: 10.1007/s11172-014-0759-4
G. A. Silantyev, E. M. Kozinets (Titova), O. A. Filippov, E. Yakurnova, N. V. Belkova
Dihydrogen bonding formed by (hydrido)[hydrotris(pyrazolyl)borato]ruthenium. The effect of ligands on the proton-withdrawing ability of ruthenium complexes

2013

Dalton Trans., 2013, 42, 11720-11730, DOI: 10.1039/C3DT51429C
E. M. Kozinets (Titova), M. Fekete, O. A. Filippov, N. V. Belkova, E. S. Shubina, R. Poli, S. Duckett, E. Manoury
Activation of a (cyclooctadiene) rhodium(I) complex supported by a chiral ferrocenyl phosphine thioether ligand for hydrogenation catalysis: a combined parahydrogen NMR and DFT study
Russ. Chem. Bull., 2013, 62, 751-757
E. M. Kozinets (Titova), G. A. Silantyev, N. V. Belkova, E. S. Shubina, R. Poli, E. Manoury
Iridium and rhodium complexes with the planar chiral thioether ligands in asymmetric hydrogenation of ketones and imines

2012

Dalton Trans., 2012, 41, 11849-11859
E. M. Kozinets (Titova), O. Koniev, O. A. Filippov, J.-C. Daran, R. Poli, E. S. Shubina, N. V. Belkova, E. Manoury
Coordination chemistry of diphenylphosphinoferrocenylthioethers on cyclooctadiene and norbornadiene rhodium(I) platforms