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Vladislava A. Kirkina
Researcher
Personal Info
Date Of Birth
10/14/1987
Address
A.N. Nesmeyanov Institute of Organoelement Compounds
Russian Academy of Sciences (INEOS RAS)
Vavilov St. 28, 119991, Moscow, Russia
Russian Academy of Sciences (INEOS RAS)
Vavilov St. 28, 119991, Moscow, Russia
Phone
+7(499)1356448
Email
Academic Degree
Ph. D. (Chem.), A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (2012)
Experience
Ph. D. Student (Chem.) and Junior Researcher, A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences (2009-2012)
M.Sc., Higher College of Chemistry of the Russian Academy of Sciences at D. Mendeleyev University of Chemical Technology of Russia (2004-2009)
M.Sc., Higher College of Chemistry of the Russian Academy of Sciences at D. Mendeleyev University of Chemical Technology of Russia (2004-2009)
Scientific Interests
Transition-metal complexes and hydrides, structure-reactivity relationships. Intermolecular interactions, hydrogen bonding and proton transfer. Catalysis and studies of mechanisms. Molecular spectroscopy.
Awards
1st prize at Young Scientists' Competition at International Conference on Organometallic and Coordination Chemistry, 2008
2nd prize at Annual Young Scientists' Competition at the A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 2008
2nd prize at Annual Young Scientists' Competition at the A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 2008
Publications
2024
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Electrocatalytic Radical Degradation of 2-Aminoethanol by Nickel, Palladium and Platinum Complexes Bearing Non-Innocent Diarylamido/bis(Phosphine) Pincer Ligand
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Electrochemical generation and in situ EPR- and UV–vis- observation of aminyl-radical diarylamido/bis(phosphine) pincer complexes of Ni, Pd and Pt
2023
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Role of Non-Covalent Interactions in the Reactions between Palladium Hydrido Complex with Amidoarylphosphine Pincer Ligand and Brønsted Acids
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Basicity and hydride-donating ability of palladium(II) hydride complex with diarylamido-bis-phosphine pincer ligand
2022
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Amine-boranes reactions promoted by lanthanide(ii) ions
2021
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Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
2020
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Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
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Stereoisomerism as an Origin of Different Reactivity of Ir(III) PC(sp3)P Pincer Catalysts
2019
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Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes
2016
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Dihydrogen Bonding and Proton Transfer from MH vs OH acids to Group 10 Metal Hydrides (tBuPCP)MH [tBuPCP = 3-2,6-(tBu2PCH2)2C6H3; M = Ni, Pd]
2014
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Transition metal hydride M—H bond activation upon the formation of complexes with acids and bases
2013
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Z. Phys. Chem., 2013, 227, 69–88First Example of Hydrogen Bonding to Platinum Hydride
2011
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J. Organomet. Chem., 2011, 696, 1174-1183Modeling the platinum-catalyzed intermolecular hydroamination of ethylene: the nucleophilic addition of HNEt2 to coordinated ethylene in trans-PtBr2(C2H4)(HNEt2)
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Angew. Chem. Int. Ed., 2011, 50, 1367–1370Acid-base interaction between transition metal hydrides results in dihydrogen bonding and assists H2 evolution
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Inorg. Chem., 2011, 50, 12539-52Coordination and Organometallic Chemistry of Relevance to the Rhodium-Based Catalyst for Ethylene Hydroamination