MH-Lab | Alexey A. Titov

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Alexey A. Titov

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Alexey A. Titov

Senior Researcher

Personal Info

Date Of Birth

05/11/1989

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Academic Degree

Ph. D. (Chem.), A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (2014)

Experience

Ph.D., A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences (2011-2015)
M.Sc., Higher College of Chemistry of the Russian Academy of Sciences at D. Mendeleyev University of Chemical Technology of Russia (2006-2011)

Scientific Interests

Coordination chemistry, pyrazolate complexes of transition metal, structure-reactivity relationships. Intermolecular interactions. Molecular and electronic spectroscopy.

Awards

1st prize at Young Scientists' Competition at International Conference on Organometallic and Coordination Chemistry, 2008.
M. E. Vol’pin award at the first symposium “INEOS Open”, 2015

Publications

2024

Inorg. Chem., 2024, DOI: 10.1021/acs.inorgchem.4c00751
K. F. Baranova, A. A. Titov, Shakirova Julia R., Baigildin Vadim A., Smol’yakov Alexander F., D. Valyaev, Ning Guo-Hong, O. A. Filippov, S. P. Tunik, E. S. Shubina
Substituents’ Effect on the Photophysics of Trinuclear Copper(I) and Silver(I) Pyrazolate–Phosphine Cages
Chemical Communications, 2024, 60, 847-850, DOI: 10.1039/D3CC05659G
A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu., Godovikov Ivan A., O. A. Filippov, E. S. Shubina
Pyrazolate vs phenylethynide: direct exchange of anionic bridging ligand in cyclic trinuclear silver complex

2023

Inorganics, 2023, 11(4), 175, DOI: 10.3390/inorganics11040175
Arina Olbrykh, A. A. Titov, Alexander Smol’yakov, O. A. Filippov, E. S. Shubina
Exploring the Interaction of Pyridine-Based Chalcones with Trinuclear Silver(I) Pyrazolate Complex
Molecules, 2023, 28(3), 1189, DOI: 10.3390/molecules28031189
Yakovlev G. B., A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu, O. A. Filippov, E. S. Shubina
Tetranuclear Copper(I) and Silver(I) Pyrazolate Adducts with 1,1$\prime$-Dimethyl-2,2’-bibenzimidazole: Influence of Structure on Photophysics
Russian Chemical Reviews, 2023, 92(11), RCR5099, DOI: 10.59761/rcr5099
E. M. Kozinets (Titova), A. A. Titov, E. S. Shubina
Functional pyrazolylpyridine ligands in the design of metal complexes with tunable properties

2022

Inorg. Chem. Front., 2022, 9(21), 5624-5634, DOI: 10.1039/d2qi01648f
S. K. Emashova, A. A. Titov, Smol’yakov Alexander F., Chernyadyev Andrey Yu, Godovikov Ivan A., Godovikova Maria I., Dorovatovskii Pavel V., Korlyukov Alexander A., O. A. Filippov, E. S. Shubina
Emissive Silver(I) Cyclic Trinuclear Complexes with Aromatic Amine Donor Pyrazolate Derivatives: Way to Efficiency
Russian Journal of Coordination Chemistry, 2022, 48(10), 615-621, DOI: 10.1134/S1070328422100086
A. A. Titov, Smol'yakov A.F., O. A. Filippov, N. V. Belkova, E. S. Shubina
Halogen or Arene: Complexation of 4,4'-Dibromobiphenyl with a Three-Membered Silver(I) Macrocycle
Inorg. Chim. Acta, 2022, 539, 121004, DOI: 10.1016/j.ica.2022.121004
A. A. Titov, Smol'yakov Alexander F., Godovikov Ivan A., Chernyadyev Andrey Yu, Molotkov Alexander P., Loginov Dmitry A., O. A. Filippov, N. V. Belkova, E. S. Shubina
The role of weak intermolecular interactions in photophysical behavior of isocoumarins on the example of their interaction with cyclic trinuclear silver(I) pyrazolate

2021

J. Organomet. Chem., 2021, 942, 121813, DOI: 10.1016/j.jorganchem.2021.121813
A. A. Titov, Smol’yakov A.F., O. A. Filippov
Heterobimetallic silver(I) and copper(I) pyrazolates supported with 1,1'-bis(diphenylphosphino)ferrocene
Molecules, 2021, 26(22), 6869, DOI: 10.3390/molecules26226869
K. F. Baranova, A. A. Titov, Smol’yakov A.F., Chernyadyev A.Y., O. A. Filippov, E. S. Shubina
Mononuclear copper(I) 3-(2-pyridyl)pyrazole complexes: the crucial role of phosphine on photoluminescence
Inorg. Chem., 2021, 60(11), 8062-8074, DOI: 10.1021/acs.inorgchem.1c00586
G. S. Astakhov, M. M. Levitsky, Zubavichus Y. V., Khrustalev Victor N., A. A. Titov, Dorovatovskii Pavel V., Smol’yakov Alexander F., E. S. Shubina, Kirillova Marina V., A. Kirillov, A. N. Bilyachenko
Cu6- and Cu8-Cage Sil- and Germsesquioxanes: Synthetic and Structural Features, Oxidative Rearrangements, and Catalytic Activity
Mendeleev Communications, 2021, 31(2), 170-172, DOI: 10.1016/j.mencom.2021.03.008
A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., Averin Alexey A., E. S. Shubina
New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2'-bipyridine

2020

Crystals, 2020, 10(10), 881, DOI: 10.3390/cryst10100881
K. F. Baranova, A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., Averin Alexey A., E. S. Shubina
Dinuclear Silver(I) Nitrate Complexes with Bridging Bisphosphinomethanes: Argentophilicity and Luminescence
Journal of Catalysis, 2020, 390, 37-45, DOI: 10.1016/j.jcat.2020.07.010
Larionov V. A., Stashneva A. R., A. A. Titov, Lisov A. A., Medvedev M. G., Smol’yakov A. F., Tsedilin A. M., E. S. Shubina, Maleev V. I.
Mechanistic Study in Azide-Alkyne Cycloaddition (CuAAC) Catalyzed by Bifunctional Trinuclear Copper(I) Pyrazolate Complex: Shift in Rate-Determining Step

2019

Mendeleev Communications, 2019, 29 (5), 570-572, DOI: 10.1016/j.mencom.2019.09.031
A. A. Titov, O. A. Filippov, A.F. Smol’yakov, A.A. Averin, E. S. Shubina
Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
Eur. J. Inorg. Chem., 2019, 2019 (45), 4855-4861, DOI: 10.1002/ejic.201901050
S. K. Emashova, A. A. Titov, O. A. Filippov, A.F. Smol'yakov, E. M. Kozinets (Titova), L. M. Epstein, E. S. Shubina
Luminescent AgI Complexes with 2,2′-Bipyridine Derivatives Featuring [Ag-(CF3)2Pyrazolate]4 Units
Inorg. Chem., 2019, 58(13), 8645-8656, DOI: 10.1021/acs.inorgchem.9b00991
A. A. Titov, O. A. Filippov, A.F. Smolyakov, I.A. Godovikov, J.R. Shakirova, S. P. Tunik, I.S. Podkorytov, E. S. Shubina
Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane
Dalton Trans., 2019, 48, 8410-8417, DOI: 10.1039/c9dt01355e
A. A. Titov, O. A. Filippov, A.F. Smol’yakov, A.A. Averin, E. S. Shubina
Syntheses, Structures and Luminescence of multinuclear Silver(I) pyrazolate adducts with 1, 10-Phenanthroline derivatives
Chemical Communications, 2019, 55, 290-293, DOI: 10.1039/C8CC08592G
A. A. Titov, V. A. Larionov, A. F. Smol’yakov, M. I. Godovikova, E. M. Kozinets (Titova), V. I. Maleev, E. S. Shubina
Interaction of a trinuclear copper(I) pyrazolate with alkynes and carbon–carbon triple bond activation
Eur. J. Inorg. Chem., 2019, 6, 821-827, DOI: 10.1002/ejic.201801318
A. A. Titov, O. A. Filippov, Smol’yakov Alexander F., K. F. Baranova, E. M. Kozinets (Titova), Averin Aleksey A., E. S. Shubina
Dinuclear Cu(I) and Ag(I) pyrazolates supported with tertiary phosphines: Synthesis, structures and photophysical properties

2018

Inorg. Chim. Acta, 2018, 470, 22-35, DOI: 10.1016/j.ica.2017.07.015
A. A. Titov, O. A. Filippov, L. M. Epstein, N. V. Belkova, E. S. Shubina
Macrocyclic Copper(I) and Silver(I) Pyrazolates: Principles of Supramolecular Assemblies with Lewis Bases
Mendeleev Communications, 2018, 28(4), 387-389, DOI: 10.1016/j.mencom.2018.07.015
A. A. Titov, A F. Smol'yakov, K. F. Baranova, O. A. Filippov, E. S. Shubina
Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis-(trifluoromethyl)pyrazolates
ChemistrySelect, 2018, 3(2), 653-656, DOI: 10.1002/slct.201702689
Larionov V. A., Yashkina L. V., Smolyakov A. F., Zubavichus Y.V., Babevsky K. K., Akatyev N. V., A. A. Titov, Belokon Y. N., Maleev V. I.
Synthesis and Investigations of Chiral NNO Type Copper(II) coordination Polymers

2017

ChemCatChem, 2017, 9 (23), 4437–4447, DOI: 10.1002/cctc.201701063
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, A. V. Vologzhanina, A. A. Titov, P. V. Dorovatovskii, L. S. Shul’pina, F. Lamaty, X. Bantreil, B. Villemejeanne, C. Ruiz, J. Martinez, E. S. Shubina, G. B. Shul’pin
Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
Crystal Growth and Design, 2017, 17 (12), 6770–6779, DOI: 10.1021/acs.cgd.7b01351
A. A. Titov, A. Smol’yakov, O. A. Filippov, I. Godovikov, D. Muratov, F. Dolgushin, L. M. Epstein, E. S. Shubina
Supramolecular design of the trinuclear silver(I) and copper(I) metal pyrazolates complexes with ruthenium sandwich compounds via intermolecular metal-π interactions
Russ. Chem. Bull., 2017, 66 (9), 1563–1568, DOI: 10.1007/s11172-017-1925-2
A. A. Titov, A F. Smol´yakov, A. N. Rodionov, I. D. Kosenko, E. Guseva, Ya. V. Zubavichus, P. V. Dorovatovskii, O. A. Filippov, E. S. Shubina
Ferrocenecontaining tri and tetranuclear cyclic copper(I) and silver(I) pyrazolates

2016

J. Phys. Chem. A, 2016, DOI: 10.1021/acs.jpca.6b06579
A. A. Titov, E. Guseva, O. A. Filippov, G. M. Babakhina, I. A. Godovikov, N. V. Belkova, L. M. Epstein, E. S. Shubina
The Role of Weak Interactions in Strong Intermolecular M•••Cl Complexes of Coinage Metal Pyrazolates: Spectroscopic and DFT Study

2015

Chem. Eur. J., 2015, 21, 13176-13180, DOI: 10.1002/chem.201502085
O. A. Filippov, A. A. Titov, E. Guseva, D. A. Loginov, A. F. Smol'yakov, F. M. Dolgushin, N. V. Belkova, L. M. Epstein, E. S. Shubina
Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene

2014

RSC Adv., 2014, 4, 8350 – 8359, DOI: 10.1039/C3RA47040G
A. A. Titov, O. A. Filippov, E. Guseva, A. F. Smol’yakov, F. M. Dolgushin, L. M. Epstein, V. K. Belsky, E. S. Shubina
Role of basic sites of substituted ferrocenes in interaction with the trinuclear 3,5-bis(trifluoromethyl)pyrazolates: thermodynamics and structure of complexes

2013

Russ. Chem. Bull., 2013, 62, 1829-1834
A. A. Titov, E. Guseva, A. F. Smol’yakov, F. M. Dolgushin, O. A. Filippov, I. E. Golub, ^krylova#, G. M. Babakhina, L. M. Epstein, E. S. Shubina
Complexation of trimeric copper(I) and silver(I) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane

2012

Eur. J. Inorg. Chem., 2012, 5554–5561
A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A.F. Smol’yakov, F.M. Dolgushin, V.K. Belsky, I.A. Godovikov, L. M. Epstein, E. S. Shubina
Complexes of Trinuclear Macrocyclic Copper(I) and Silver(I) 3,5- Bis(Trifluoromethyl)Pyrazolates with Ketones

2011

Inorg. Chem., 2011, 50, 3325-3331
V. N.Tsupreva, A. A. Titov, O. A. Filippov, A. N. Bilyachenko, A. F.Smol'yakov, F. M. Dolgushin, D. V. Agapkin, I. A. Godovikov, L. M. Epstein, E. S. Shubina
Peculiarities of the Complexation of Copper and Silver Adducts of a 3,5-Bis(trifluoromethyl)pyrazolate Ligand with Organoiron Compounds