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Igor E. Golub
Researcher
Personal Info
Date Of Birth
01/31/1989
Address
28, Vavilov Str., 119991, Moscow, Russia
Phone
+7(499)135-6448
Email
Academic Degree
PhD, Chemistry of Organoelement Compounds & Physical Chemistry
Experience
Sept. 2010 – Present
Researcher
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Sept. 2006 – June 2011
Specialist in Chemistry, Chemistry of Organoelement Compounds
Lomonosov Moscow State University, Department of Chemistry
Oct. 2011 – Oct. 2014
PhD Student, Chemistry of Organoelement Compounds & Physical Chemistry
Lomonosov Moscow State University, Department of Chemistry
Researcher
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Sept. 2006 – June 2011
Specialist in Chemistry, Chemistry of Organoelement Compounds
Lomonosov Moscow State University, Department of Chemistry
Oct. 2011 – Oct. 2014
PhD Student, Chemistry of Organoelement Compounds & Physical Chemistry
Lomonosov Moscow State University, Department of Chemistry
Scientific Interests
Organometallic complexes, transition metal and main-group hydrides. Intermolecular interactions and hydrogen bonding. DFT calculations of medium and large-size system (ONIOM), electron density analysis (NBO, QTAIM, NCI) and molecular dynamic. Molecular spectroscopy (FTIR, UV-vis). Mechanism of reactions with proton/hydride transfer and hydrogen evolution (dehydrogenation and dehydrocoupling). Chemical compounds for reversible hydrogen storage systems.
Awards
XIX International Lomonosov Moscow State University Conference “Lomonosov 2012”, 9-13 April 2012, Moscow, the 1-st prize on Organic Chemistry Section for Oral contribution.
XXI International Lomonosov Moscow State University Conference “Lomonosov 2014”, 7-11 April 2014, Moscow, the 1-st prize on Physical Chemistry Section for Oral contribution.
XXI International Lomonosov Moscow State University Conference “Lomonosov 2014”, 7-11 April 2014, Moscow, the 1-st prize on Physical Chemistry Section for Oral contribution.
Publications
2024
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Spectroscopic characterization of black N- and P-doped zeolite templated carbons
2021
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The mechanism of halogenation of decahydro-closo-decaborate dianion by hydrogen chloride
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The reaction of hydrogen halides with tetrahydroborate anion and hexahydro-closo-hexaborate dianion
2020
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Dichotomous Si–H Bond Activation by Alkoxide and Alcohol in Base-Catalyzed Dehydrocoupling of Silanes
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Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes
2019
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Synthesis, Structural Properties and Reactivity of Ruthenocene-based Pincer Pd(II) Tetrahydroborate
2018
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Hydride donating abilities of the tetracoordinated boron hydrides
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Comprehensive Insight into Hydrogen Bonding of Silanes
2017
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Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
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Ammonia Borane Dehydrogenation Catalyzed by (κ4‑EP3)Co(H) [EP3 = E(CH2CH2PPh2)3; E = N, P] and H2 Evolution from Their Interaction with NH Acids
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The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis
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Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ3-P-CH3C(CH2CH2PPh2)3}RuH(η2-BH4)]
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Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(2-BH4)2] Dichloromethane Solvate
2016
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A Heterometallic (Fe6Na8) Cage-like Silsesquioxane: Synthesis, Structure, Spin Glass Behavior and High Catalytic Activity
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Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]
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First Cage-Like Pentanuclear Co(II)-Silsesquioxane
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Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity
2015
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Dihydrogen Bond Intermediated Alcoholysis of Dimethylamine-Borane in Non-Aqueous Media
2014
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Dihydrogen bonding in complex (PP3)RuH(η1-BH4) featuring two proton-accepting hydride sites: experimental and theoretical studies
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Transition metal hydride M—H bond activation upon the formation of complexes with acids and bases
2013
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Russ. Chem. Bull., 2013, 62, 1829-1834Complexation of trimeric copper(I) and silver(I) 3,5-bis(trifluoromethyl)pyrazolates with amine-borane
2012
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Inorg. Chem., 2012, 51, 6486-6497Dimerization Mechanism of Bis(triphenylphosphine)copper(I) Tetrahydroborate: Proton Transfer via a Dihydrogen Bond