MH-Lab | Gleb A. Silantyev

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Gleb A. Silantyev

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Gleb A. Silantyev

Researcher

Personal Info

Date Of Birth

02/10/1989

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Academic Degree

Ph.D.

Experience

Ph.D., A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences (2011-2015) M.Sc., Higher College of Chemistry of the Russian Academy of Sciences at D. Mendeleyev University of Chemical Technology of Russia (2006-2011) Visiting Student, Ernst-Moritz-Arndt University of Greifswald (2010-2014) and Free University of Berlin (2010)

Scientific Interests

Organometallic chemistry; transition-metal hydrides; structure-reactivity relationships; intra- and intermolecular interactions; hydrogen bonding and proton transfer; IR, UV-vis and NMR spectroscopy; homogeneous catalysis; reaction mechanisms

Awards

Poster Prize at the International Symposium “Modern Trends in Organometallic Chemistry and Catalysis” dedicated to the 90th anniversary of the academician M. E. Vol’pin (2013), Moscow, Russia 1st RSC Catalysis Science & Technology Poster Prize at the International Symposium “Frontiers of Organometallic Chemistry” (2012), St. Petersburg, Russia Poster Prize at the XIX EuCheMS Conference on Organometallic Chemistry (2011), Toulouse, France

Publications

2020

Mendeleev Communications, 2020, 30(3), 276-278, DOI: 10.1016/j.mencom.2020.05.004
V. A. Kirkina, E. S. Osipova, O. A. Filippov, G. A. Silantyev, D. Gelman, E. S. Shubina, N. V. Belkova
Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
Inorg. Chem., 2020, 59(17), 11962–11975, DOI: 10.1021/acs.inorgchem.0c00797
V. A. Kirkina, G. A. Silantyev, De-botton Sophie, O. A. Filippov, E. M. Kozinets (Titova), Pavlov Alexander, N. V. Belkova, L. M. Epstein, D. Gelman, E. S. Shubina
Stereoisomerism as an Origin of Different Reactivity of Ir(III) PC(sp3)P Pincer Catalysts

2017

J. Organomet. Chem., 2017, 827, 86-95, DOI: 10.1016/j.jorganchem.2016.11.010
E. M. Kozinets (Titova), E. S. Osipova, E. Gulyaeva, V.N. Torocheshnikov, A.A. Pavlov, G. A. Silantyev, O. A. Filippov, E. S. Shubina, N. V. Belkova
Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
Angew. Chem. Int. Ed., 2017, 56, 5872-5876
G. A. Silantyev, M. Förster, B. Schluschaß, J. Abbenseth, C. Würtele, C. Volkmann, M. C. Holthausen, S. Schneider
Dinitrogen Splitting Coupled to Protonation

2016

Eur. J. Inorg. Chem., 2016, 56–63, DOI: 10.1002/ejic.201501083
E. M. Kozinets (Titova), G. A. Silantyev, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, Fedor M. Dolgushin, N. V. Belkova
PCP Pincer Iridium Chemistry: Coordination of Pyridines to (tBuPCP)IrH(Cl)

2015

Russ. Chem. Bull., 2015, 64(12), 2806–2810, DOI: 10.1007/s11172-015-1230-x
G. A. Silantyev, E. M. Kozinets (Titova), O. A. Filippov, E. I. Gutsul, D. Gelman, N. V. Belkova
Hydrogen bonds, coordination isomerism, and catalytic dehydrogenation of alcohols with the bifunctional iridium pincer complex (HOCH2)2(PCsp3P)IrHCl

2014

Russ. Chem. Bull., 2014, 63, 2434-2437, DOI: 10.1007/s11172-014-0759-4
G. A. Silantyev, E. M. Kozinets (Titova), O. A. Filippov, E. Yakurnova, N. V. Belkova
Dihydrogen bonding formed by (hydrido)[hydrotris(pyrazolyl)borato]ruthenium. The effect of ligands on the proton-withdrawing ability of ruthenium complexes
Organometallics, 2014, 33, 5964-5973, DOI: 10.1021/om500308g
G. A. Silantyev, O. A. Filippov, S. Musa, D. Gelman, N. V. Belkova, K. Weisz, L. M. Epstein, E. S. Shubina
Conformational Flexibility of Dibenzobarrelene-Based PC(sp3)P Pincer Iridium Hydride Complexes: The Role of Hemilabile Functional Groups and External Coordinating Solvents

2013

Chem. Eur. J., 2013, 19, 16906–16909, DOI: 10.1002/chem.201303311
S. Musa, O. A. Filippov, N. V. Belkova, E. S. Shubina, G. A. Silantyev, L. Ackermann, D. Gelman
Ligand–Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation
Inorg. Chem., 2013, 52, 1787−1797, DOI: 10.1021/ic301585k
G. A. Silantyev, O. A. Filippov, P.M. Tolstoy, N. V. Belkova, L. M. Epstein, K. Weisz, E. S. Shubina
Hydrogen bonding and proton transfer to ruthenium hydride complex CpRuH(dppe): metal and hydride dichotomy.
Russ. Chem. Bull., 2013, 62, 751-757
E. M. Kozinets (Titova), G. A. Silantyev, N. V. Belkova, E. S. Shubina, R. Poli, E. Manoury
Iridium and rhodium complexes with the planar chiral thioether ligands in asymmetric hydrogenation of ketones and imines