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Elena S. Osipova
PhD-student
Personal Info
Date Of Birth
07/30/1992
Address
28 Vavilov Str., Moscow 119334, RUSSIA
Phone
+7 499 135 6448
Email
Academic Degree
Ph. D. (Chem.), A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (2019),
M.Sc., Lomonosov Moscow State University (2009-2014)
M.Sc., Lomonosov Moscow State University (2009-2014)
Experience
June 2014 - Master diploma, Department of Chemistry, Lomonosov Moscow State University, Moscow, RUSSIA
2011–2014 - Undergraduate student, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2013 - Training in the group of prof. Maurizio Peruzzini, Institute of Chemistry of OrganoMetallic Compounds ICCOM-CNR, Florence, Italy
2014–pres. - PhD studies in the group of Prof. Elena S. Shubina under supervision of Prof. Natalia V. Belkova. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2011–2014 - Undergraduate student, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2013 - Training in the group of prof. Maurizio Peruzzini, Institute of Chemistry of OrganoMetallic Compounds ICCOM-CNR, Florence, Italy
2014–pres. - PhD studies in the group of Prof. Elena S. Shubina under supervision of Prof. Natalia V. Belkova. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Scientific Interests
Organometallic chemistry; transition-metal hydrides; acid-base interactions; hydrogen bonding and proton transfer; IR, UV-vis and NMR spectroscopy; theoretical calculations
Awards
Prize for the Poster Presentation at the Conference on Organometallic and Coordination Chemistry: Fundamental and Applied Aspects, September 1-7, 2013, Nizhny Novgorod, Russia
Publications
2024
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Isonitrile Coordination to Pincer Iridium Hydrido Chlorides
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Stepwise carbon dioxide hydrosylilation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(But PCP)]
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Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation
2023
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Reactivity of heterobimetallic ion pairs in formic acid dehydrogenation
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The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes
2022
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Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(Ph2PCH2PPh2)Mn(CO)3H]
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Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
2021
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Iinfluence of phosphine (pincer) ligands on the transition metal hydrides reactivity
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Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
2020
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Steric and Electronic Effect of Cp-Substituents on the Structure of the Ruthenocene Based Pincer Palladium Borohydrides
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Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
2019
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Non-covalent interactions in stoichiometric and catalytic reactions of iridium pincer complexes
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Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes
2018
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Amine Boranes Dehydrogenation Mediated by an Unsymmetrical Iridium Pincer Hydride: (PCN) vs (PCP) Improved Catalytic Performance
2017
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Mechanism of Dimethylamine–Borane Dehydrogenation Catalyzed by an Iridium(III) PCP-Pincer Complex
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Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
2016
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Dihydrogen Bonding and Proton Transfer from MH vs OH acids to Group 10 Metal Hydrides (tBuPCP)MH [tBuPCP = 3-2,6-(tBu2PCH2)2C6H3; M = Ni, Pd]
2014
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Transition metal hydride M—H bond activation upon the formation of complexes with acids and bases