MH-Lab | Ekaterina Gulyaeva

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Ekaterina Gulyaeva

Ekaterina Gulyaeva

PHD student

Personal Info

Date Of Birth

07/03/1997

Address

28, Vavilov Str., 119991, Moscow, Russia

Phone

+7(499)135-6448

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Experience

Sept. 2015 – Present
Research engineer
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Sept. 2014 – Present
Undergraduate Student
Lomonosov Moscow State University, Department of Chemistry

Scientific Interests

Organometallic complexes, transition metal and main-group hydrides. Intermolecular interactions and hydrogen bonding. Molecular spectroscopy (FTIR, UV-vis). Mechanism of reactions with proton/hydride transfer and hydrogen evolution (dehydrogenation and dehydrocoupling). Chemical compounds for reversible hydrogen storage systems.

Awards

International conference “Organometallic and Coordination Chemistry: Achievements and Challenges.” (VI Razuvaev Lectures), 18-23 September 2015, Nizhny Novgorod, the 1-st prize for poster presentation.

Publications

2023

Molecules, 2023, 28(8), 3368, DOI: 10.3390/molecules28083368
E. S. Osipova, S. Kovalenko, E. Gulyaeva, N. V. Kireev, Alexander A. Pavlov, O. A. Filippov, Anastasia A. Danshina, D. Valyaev, Yves Canac, E. S. Shubina, N. V. Belkova
The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes

2022

Chemical Communications, 2022, 58(32), 5017-5020, DOI: 10.1039/D2CC00999D
E. S. Osipova, E. Gulyaeva, N. V. Kireev, Kovalenko Sergey A., Bijani Crisitan, Canac Yves, D. Valyaev, O. A. Filippov, N. V. Belkova, E. S. Shubina
Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(Ph2PCH2PPh2)Mn(CO)3H]
Coord. Chem. Rev., 2022, 458, 214421, DOI: 10.1016/j.ccr.2022.214421
E. Gulyaeva, E. S. Osipova, Buhaibeh Ruqaya, Canac Yves, Sortais Jean-Baptiste, D. Valyaev
Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes

2021

Chemical science, 2021, 12, 3682-3692, DOI: DOI: 10.1039/D0SC06114J
E. S. Osipova, E. Gulyaeva, E. I. Gutsul, V. A. Kirkina, A. A. Pavlov, Y. V. Nelyubina, A. Rossin, M. Peruzzini, L. M. Epstein, N. V. Belkova, O. A. Filippov, E. S. Shubina
Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”

2020

Chemical Communications, 2020, 56, 2139-2142, DOI: 10.1039/C9CC07713H
N. V. Kireev, O. A. Filippov, E. Gulyaeva, E. S. Shubina, Laure Vendier, Yves CANAC, Jean-Baptiste Sortais, Noël Lugan, D. Valyaev
Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation

2019

Eur. J. Inorg. Chem., 2019, 10, 1389-1397, DOI: 10.1002/ejic.201801341
E. S. Osipova, E. Gulyaeva, O. A. Filippov, S. V. Safronov, A. A. Pavlov, A. V. Polukeev, V. A. Kirkina, E. M. Kozinets (Titova), E. S. Shubina, N. V. Belkova
Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes

2017

Inorg. Chem., 2017, 56 (7), 4093-4103, DOI: 10.1021/acs.inorgchem.7b00061
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Petrov, Alexander A. Korlyukov, Lidia S. Shul’pina, Victor N. Khrustalev, Pavel V. Dorovatovskii, Anna V. Vologzhanina, Ulyana S. Tsareva, I. E. Golub, E. Gulyaeva, E. S. Shubina, G. B. Shul’pin
Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
J. Organomet. Chem., 2017, 827, 86-95, DOI: 10.1016/j.jorganchem.2016.11.010
E. M. Kozinets (Titova), E. S. Osipova, E. Gulyaeva, V.N. Torocheshnikov, A.A. Pavlov, G. A. Silantyev, O. A. Filippov, E. S. Shubina, N. V. Belkova
Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
Inorg. Chim. Acta, 2017, 456, 113-119, DOI: 10.1016/j.ica.2016.10.037
I. E. Golub, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, N. V. Belkova
The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis

2016

Eur. J. Inorg. Chem., 2016, 56–63, DOI: 10.1002/ejic.201501083
E. M. Kozinets (Titova), G. A. Silantyev, O. A. Filippov, E. Gulyaeva, E. I. Gutsul, Fedor M. Dolgushin, N. V. Belkova
PCP Pincer Iridium Chemistry: Coordination of Pyridines to (tBuPCP)IrH(Cl)

2015

J. Phys. Chem. A, 2015, 119, 3853-3868, DOI: 10.1021/acs.jpca.5b01921
I. E. Golub, E. Gulyaeva, O. A. Filippov, V. P. Dyadchenko, N. V. Belkova, L. M. Epstein, D. E. Arkhipov, E. S. Shubina
Dihydrogen Bond Intermediated Alcoholysis of Dimethylamine-Borane in Non-Aqueous Media