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Ekaterina Gulyaeva
PhD-student Junior researcher
Personal Info
Date Of Birth
07/03/1997
Address
28, Vavilov Str., 119991, Moscow, Russia
Phone
+7(499)135-6448
Email
Experience
Sept. 2015 – Present
Research engineer
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Sept. 2014 – Present
Undergraduate Student
Lomonosov Moscow State University, Department of Chemistry
Research engineer
A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences
Sept. 2014 – Present
Undergraduate Student
Lomonosov Moscow State University, Department of Chemistry
Scientific Interests
Organometallic complexes, transition metal and main-group hydrides. Intermolecular interactions and hydrogen bonding. Molecular spectroscopy (FTIR, UV-vis). Mechanism of reactions with proton/hydride transfer and hydrogen evolution (dehydrogenation and dehydrocoupling). Chemical compounds for reversible hydrogen storage systems.
Awards
International conference “Organometallic and Coordination Chemistry: Achievements and Challenges.” (VI Razuvaev Lectures), 18-23 September 2015, Nizhny Novgorod, the 1-st prize for poster presentation.
Publications
2024
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Russian Journal of Coordination Chemistry, 2024, 50(5), 316-325Isonitrile Coordination to Pincer Iridium Hydrido Chlorides
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Impact of the Methylene Bridge Substitution in Chelating NHC- Phosphine Mn(I) Catalyst for Ketone Hydrogenation
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Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation
2023
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Phosphine-NHC-phosphonium ylide pincer ligand: complexation with Pd(II) and unconventional P-coordination of the ylide moiety
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The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes
2022
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Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(Ph2PCH2PPh2)Mn(CO)3H]
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Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
2021
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Bifunctional activation of amine-boranes by the W/Pd bimetallic analogs of “frustrated Lewis pairs”
2020
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Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation
2019
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Ligands effect on the Lewis acidity of the metal and the N-bases binding to iridium pincer complexes
2017
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Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
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Mild activation of Ir-Cl bond upon the interaction of pincer iridium hydride (tBuPCP)IrH(Cl) with acids and bases
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The interplay of proton accepting and hydride donor abilities in the mechanism of step-wise boron hydrides alcoholysis
2016
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PCP Pincer Iridium Chemistry: Coordination of Pyridines to (tBuPCP)IrH(Cl)
2015
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Dihydrogen Bond Intermediated Alcoholysis of Dimethylamine-Borane in Non-Aqueous Media