MH-Lab | Alena N. Kulakova

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Alena N. Kulakova

Alena N. Kulakova

Engeneer

Personal Info

Address

28 Vavilov Str., Moscow 119334, Russia

Phone

+7-499-135-93-69

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Academic Degree

M.Sc., Mendeleev University of Chemical Technology of Russia, 2016

Experience

2012-2015: Master diploma, Zelinsky Institute of Russian Academy of Sciences (Laboratory for Studies of Homolytic Reactions, under supervision of Prof. A.O. Terentev)
December 2015 – present: Research Fellow in the laboratory of Prof. Elena S. Shubina under supervision of Dr. A.N. Bilyachenko

Scientific Interests

Organic and Organometallic Chemistry; Cage Compounds; Heterocycles; Supramolecular Aggregation; Catalysis

Publications

2019

J. Organomet. Chem., 2019, 899, DOI: 10.1016/j.jorganchem.2019.120911
A. N. Kulakova, E.E.Sedykh, M. M. Levitsky, P.V.Dorovatovskii, V.N.Khrustalev, L.S.Shul'pina, E. S. Shubina, Y.N.Kozlov, N.S.Ikonnikova, A. N. Bilyachenko, G. B. Shul’pin
The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
J. Organomet. Chem., 2019, 884, 17-28, DOI: 10.1016/j.jorganchem.2019.01.004
A. N. Kulakova, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Xavier Bantreil, Lidia S. Shul'pina, M. M. Levitsky, Nikolay S. Ikonnikov, E. S. Shubina, F. Lamaty, A. N. Bilyachenko, G. B. Shul’pin
Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
Catalysts, 2019, 9, 154, DOI: 10.3390/catal9020154
A. N. Kulakova, V.N. Khrustalev, Y.V. Zubavichus, L.S. Shul’pina, E. S. Shubina, M. M. Levitsky, N.S. Ikonnikov, A. N. Bilyachenko, Y.N. Kozlov, G. B. Shul’pin
Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides

2018

Inorg. Chem., 2018, 57 (1), 528–534, DOI: 10.1021/acs.inorgchem.7b02881
A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, L. S. Shul’pina, A. N. Kulakova, X. Bantreil, F. Lamaty, M. M. Levitsky, E. I. Gutsul, E. S. Shubina, G. B. Shul’pin
Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
J. Organomet. Chem., 2018, 867, 133-141, DOI: 10.1016/j.jorganchem.2017.10.033
A. N. Bilyachenko, A. N. Kulakova, L. S. Shul'pina, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, U. S. Tsareva, E. S. Shubina, A. A. Petrov, N. V. Vorontsov, G. B. Shul’pin
Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
Dalton Trans., 2018, 47(20), 6893-6897, DOI: 10.1039/C8DT00900G
A. N. Kulakova, A. N. Bilyachenko, A. Korlyukov, Jérôme Long, M. M. Levitsky, E. S. Shubina, Yannick Guari, J. Larionova
New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
Dalton Trans., 2018, 47, 15666-15669, DOI: 10.1039/C8DT03209B
A. N. Kulakova, A. N. Bilyachenko, A. A. Korlyukov, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, N. S. Ikonnikov, G. B. Shul’pin
A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
Catalysts, 2018, 8(10), 484, DOI: 10.3390/catal8100484
A. N. Kulakova, A. N. Bilyachenko, V. N. Khrustalev, Y. V. Zubavichus, P. V. Dorovatovskii, L. S. Shul’pina, X. Bantreil, F. Lamaty, E. S. Shubina, M. M. Levitsky, G. B. Shul’pin
Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity

2017

Journal of Molecular Catalysis A: Chemical, 2017, 426, Part B, 297-304, DOI: 10.1016/j.molcata.2016.06.016
M. M. Levitsky, A. I. Yalymov, A. N. Kulakova, A. A. Petrov, A. N. Bilyachenko
Cage-like metallsilsesquioxanes in catalysis: A review
Inorg. Chem., 2017, 56 (7), 4093-4103, DOI: 10.1021/acs.inorgchem.7b00061
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Petrov, Alexander A. Korlyukov, Lidia S. Shul’pina, Victor N. Khrustalev, Pavel V. Dorovatovskii, Anna V. Vologzhanina, Ulyana S. Tsareva, I. E. Golub, E. Gulyaeva, E. S. Shubina, G. B. Shul’pin
Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
ChemCatChem, 2017, 9 (23), 4437–4447, DOI: 10.1002/cctc.201701063
A. N. Bilyachenko, A. N. Kulakova, M. M. Levitsky, A. A. Korlyukov, V. N. Khrustalev, A. V. Vologzhanina, A. A. Titov, P. V. Dorovatovskii, L. S. Shul’pina, F. Lamaty, X. Bantreil, B. Villemejeanne, C. Ruiz, J. Martinez, E. S. Shubina, G. B. Shul’pin
Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
Dalton Trans., 2017, 46(38), 12935-12949, DOI: 10.1039/C7DT02017A
A. N. Bilyachenko, A. A. Korlyukov, A. V. Vologzhanina, V. N. Khrustalev, A. N. Kulakova, J. Long, J. Larionova, Y. Guari, M. S. Dronova, U. S. Tsareva, P. V. Dorovatovskii, E. S. Shubina, M. M. Levitsky
Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
Inorg. Chem., 2017, 56 (24), 15026–15040, DOI: 10.1021/acs.inorgchem.7b02320
A. N. Kulakova, A. N. Bilyachenko, M. M. Levitsky, V. N. Khrustalev, A. A. Korlyukov, Y. V. Zubavichus, P. V. Dorovatovskii, F. Lamaty, X. Bantreil, B. Villemejeanne, J. Martinez, L. S. Shul’pina, E. S. Shubina, E. I. Gutsul, I. A. Mikhailov, N. S. Ikonnikov, U. S. Tsareva, G. B. Shul’pin
Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations

2015

Tetrahedron, 2015, 71, C. 8985 - 8990
Terent'ev A. O., Zdvizhkov A. T., Fleury F., Pototskiy R. A., A. N. Kulakova, Levitsky D. O., Nikishin G. I.
Organocatalytic peroxidation of malonates, b-ketoesters, and cyanoacetic esters using n-Bu4NI/t-BuOOH-mediated intermolecular oxidative C(sp3)-O coupling

2014

2014, 4, C. 7579 – 7587
Terent'ev A. O., Zdvizhkov A. T., A. N. Kulakova, Novikov R. A., Arzumanyan A. V. and Nikishin G. I.
Reactions of mono- and bicyclic enol ethers with the I2–hydroperoxide system

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