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Alena N. Kulakova
Engeneer researcher
Personal Info
Academic Degree
PhD (Chem.) | ICGM, University of Montpellier, France (2020); Prof J. Larionova
PhD (Chem.) | Department of Inorganic Chemistry, Faculty of science, RUDN University, Russia (2020); Prof V.N. Khrustalev
Master Degree | Mendeleev University of Chemical Technology of Russia, Moscow (2016)
M.Sc., Mendeleev University of Chemical Technology of Russia, 2016
PhD (Chem.) | Department of Inorganic Chemistry, Faculty of science, RUDN University, Russia (2020); Prof V.N. Khrustalev
Master Degree | Mendeleev University of Chemical Technology of Russia, Moscow (2016)
M.Sc., Mendeleev University of Chemical Technology of Russia, 2016
Experience
02/2016-present: young scientific researcher in laboratory of metal Hydrides» in A.N.Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russia. Supervisor - E.S. Shubina and A.N. Bilyachenko
08/2020 – 12/2020: assistant – Inorganic chemistry department RUDN University, Moscow, Russia
06/2017 – 08/2017 – trainee – IBMM, University of Montpellier, France
10/2012 - 12/2015: lab assistant in laboratory for studies of homolytic reactions, Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia. Supervisor – Prof Dr. A.O. Terent'ev
December 2015 – present: Research Fellow in the laboratory of Prof. Elena S. Shubina under supervision of Dr. A.N. Bilyachenko
08/2020 – 12/2020: assistant – Inorganic chemistry department RUDN University, Moscow, Russia
06/2017 – 08/2017 – trainee – IBMM, University of Montpellier, France
10/2012 - 12/2015: lab assistant in laboratory for studies of homolytic reactions, Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia. Supervisor – Prof Dr. A.O. Terent'ev
December 2015 – present: Research Fellow in the laboratory of Prof. Elena S. Shubina under supervision of Dr. A.N. Bilyachenko
Scientific Interests
Cagelike metallacomplexes and coordination polymers; sesquioxane ligands; lanthanide complexes, complexation reactions; catalysis; molecular magnetism; photophysical properties.
Awards
Scholarship VERNADSKI | French Embassy in Russia (10th May 2017)
Scholarship of the President of the Russian Federation | Awarding organization (30th April 2019)
The winner of PhD students competition | RUDN University (08th October 2017, 30th September, 2018, 10th October2019)
Scholarship of the President of the Russian Federation | Awarding organization (30th April 2019)
The winner of PhD students competition | RUDN University (08th October 2017, 30th September, 2018, 10th October2019)
Publications
2024
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Luminescent Ln3+-based silsesquioxanes with a β-diketonate antenna ligand: toward the design of efficient temperature sensors
2023
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Tetranuclear lanthanide-based silsesquioxanes: towards a combination of a slow relaxation of the magnetization and a luminescent thermometry
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New family of luminescent tetranuclear lanthanide-based germsesquioxanes: luminescence and temperature sensing
2022
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Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures
2021
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Temperature sensing in Tb3+/Eu3+-based tetranuclear silsesquioxane cages with tunable emission
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Novel carbonate/pyridine tetranuclear nickel complex, exhibiting slow relaxation of the magnetization
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New Magnetic and Luminescent Dy(III) and Dy(III)/Y(III) Based Tetranuclear Silsesquioxane Cages
2020
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New Luminescent Tetranuclear Lanthanide‐based Silsesquioxane Cage‐like Architectures
2019
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The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
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Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
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Palanquin-Like Cu4Na4 Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides
2018
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Heptanuclear Fe5Cu2-Phenylgermsesquioxane containing 2,2-Bipyridine: Synthesis, Structure, and Catalytic Activity in Oxidation of CH Compounds
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Family of penta- and hexanuclear metallasilsesquioxanes: Synthesis, structure and catalytic properties in oxidations
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New Ni4Na2-Phenylgermsesquioxane Architecture: Synthesis, Structure and Slow Dynamic Behaviour
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A new “Bicycle Helmet”-like copper(II),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity
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Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity
2017
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Journal of Molecular Catalysis A: Chemical, 2017, 426, Part B, 297-304, DOI: 10.1016/j.molcata.2016.06.016Cage-like metallsilsesquioxanes in catalysis: A review
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Unusual tri-, hexa- and nonanuclear Cu(II) cage methylsilsesquioxanes: Synthesis, Structures and Catalytic Activity in Oxidations with Peroxides
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Ionic Complexes of Tetra- and Nonanuclear Cage Cu(II)-phenylsilsesquioxanes: Synthesis and High Activity in Oxidative Catalysis
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Tuning linkage isomerism and magnetic properties of bi- and tri-metallic cage silsesquioxanes by cation and solvent effects
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Si10Cu6N4 Cage Hexacoppersilsesquioxanes Containing N-Ligands: Synthesis, Structure, and High Catalytic Activity in Peroxide Oxidations
2015
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Tetrahedron, 2015, 71, C. 8985 - 8990Organocatalytic peroxidation of malonates, b-ketoesters, and cyanoacetic esters using n-Bu4NI/t-BuOOH-mediated intermolecular oxidative C(sp3)-O coupling
2014
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2014, 4, C. 7579 – 7587Reactions of mono- and bicyclic enol ethers with the I2–hydroperoxide system