MH-Lab | Grigorii S. Astakhov

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Grigorii S. Astakhov

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Grigorii S. Astakhov

Engineer researcher

Personal Info

Date Of Birth

11/14/1989

Phone

+7-499-135-93-69

Send Email

Academic Degree

Master of Science

Experience

Master degree (2017, RUDN University):2017-present: PhD Student

Scientific Interests

Cage-like compounds of transition metals, complexation reactions, synthesis of heterocyclic compounds: domino-, multi-step and one-top reactions

Publications

2023

Organometallics, 2023, DOI: 10.1021/acs.organomet.2c00649
A. N. Bilyachenko, Victor N. Khrustalev, G. S. Astakhov, A. Yu. Zueva, Arteev I. S., Yan V. Zubavichus, Alexander A. Korlyukov, Pavel V. Dorovatovskii, Lidia S. Shul’pina, Nikolay S. Ikonnikov, Marina V. Kirillova, E. S. Shubina, * Yuriy N. Kozlov, A. Kirillov, G. B. Shul’pin
Cagelike Rb2‑, K2‑, and Na2‑Tetracopper(II) Silsesquioxanes with Quaternary Ammonium Cations: Synthesis, Structures, and Catalytic Activity

2022

Inorg. Chem. Front., 2022, 9(17), 4525-4537, DOI: 10.1039/d2qi01054b
G. S. Astakhov, Khrustalev Victor N., M. S. Dronova, E. I. Gutsul, Korlyukov Alexander, D. Gelman, Zubavichus Yan V., Novichkov Daniil, Trigub Alexander, E. S. Shubina, A. N. Bilyachenko
Cagelike Manganesesilsesquioxanes. Features of Synthesis, Unique Structure, and Catalytic Activity in Oxidative Amidations
Molecules, 2022, 27(19), 6205, DOI: 10.3390/molecules27196205
A. N. Bilyachenko, Khrustalev V.N., A. Yu. Zueva, E. M. Kozinets (Titova), G. S. Astakhov, Zubavichus Y.V., Dorovatovskii P.V., Korlyukov A.S., Shul'pina L.S., E. S. Shubina, Kozlov Y.N., Ikonnikov N.S., D. Gelman, G. B. Shul’pin
A Novel Family of Cage-like (CuLi, CuNa, CuK)-phenylsilsesquioxane Complexes with 8-hydroxyquinoline Ligands: Synthesis, Structure, and Catalytic Activity
Inorg. Chem., 2022, 61(37), 14800-14814, DOI: 10.1021/acs.inorgchem.2c02217
A. N. Bilyachenko, E. I. Gutsul, Khrustalev Victor N., G. S. Astakhov, A. Yu. Zueva, Zubavichus Yan V., Kirillova Marina V., Shul’pina Lidia S., Ikonnikov Nikolay S., Dorovatovskii Pavel V., E. S. Shubina, A. Kirillov, G. B. Shul’pin
Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of Alkanes
Crystal Growth and Design, 2022, 22(4), 2146-2157, DOI: 10.1021/acs.cgd.1c01225
A. N. Bilyachenko, G. S. Astakhov, A. N. Kulakova, Korlyukov Alexander A., Zubavichus Yan V., Dorovatovskii Pavel V., Shul’pina Lidia S., E. S. Shubina, Ikonnikov Nikolay S., Kirillova Marina V., A. Yu. Zueva, A. Kirillov, G. B. Shul’pin
Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures

2021

Inorg. Chem., 2021, 60(11), 8062-8074, DOI: 10.1021/acs.inorgchem.1c00586
G. S. Astakhov, M. M. Levitsky, Zubavichus Y. V., Khrustalev Victor N., A. A. Titov, Dorovatovskii Pavel V., Smol’yakov Alexander F., E. S. Shubina, Kirillova Marina V., A. Kirillov, A. N. Bilyachenko
Cu6- and Cu8-Cage Sil- and Germsesquioxanes: Synthetic and Structural Features, Oxidative Rearrangements, and Catalytic Activity

2020

J. Organomet. Chem., 2020, 906, DOI: 10.1016/j.jorganchem.2019.121022
G. S. Astakhov, M. M. Levitsky, Bantreil X., F. Lamaty, Khrustalev V.N., Zubavichus Y.V., Dorovatovskii P.V., E. S. Shubina, A. N. Bilyachenko
Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
Inorg. Chem., 2020, 59(7) , 4536–4545, DOI: 10.1021/acs.inorgchem.9b03680
G. S. Astakhov, A. N. Bilyachenko, M. M. Levitsky, Lidia S. Shulpina, Alexander A. Korlyukov, Yan V. Zubavichus, Victor N. Khrustalev, Anna V. Vologzhanina, E. S. Shubina, Pavel V. Dorovatovskii, G. B. Shul’pin
Coordination Affinity of Cu(II)-Based Silsesquioxanes toward N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic Products Exhibiting a High Catalytic Activity in Oxidation Reactions

2019

J. Organomet. Chem., 2019, DOI: 10.1016/j.jorganchem.2019.121022
G. S. Astakhov, M. M. Levitsky, X. Bantreil, F. Lamaty, V.N. Khrustalev, Y.V. Zubavichus, P.V. Dorovatovskii, E. S. Shubina, A. N. Bilyachenko
Cu(II)-silsesquioxanes as efficient precatalysts for Chan-Evans-Lam coupling
Catalysts, 2019, 9(9), 701-719, DOI: 10.3390/catal9090701
G. S. Astakhov, M. M. Levitsky, A. A. Korlyukov, L. S. Shul’pina, E. S. Shubina, N. S. Ikonnikov, A. V. Vologzhanina, A. N. Bilyachenko, P. V. Dorovatovskii, Y. N. Kozlov, G. B. Shul’pin
New Cu4Na4- and Cu5-Based Phenylsilsesquioxanes. Synthesis via Complexation with 1,10-Phenanthroline, Structures and High Catalytic Activity in Alkane Oxidations with Peroxides in Acetonitrile

2018

Crystal Growth and Design, 2018, 18(9), 5377–5384, DOI: 10.1021/acs.cgd.8b00778
G. S. Astakhov, A. N. Bilyachenko, M. M. Levitsky, A.A. Korlyukov, Y.V. Zubavichus, P.V. Dorovatovskii, V.N. Khrustalev, A.V. Vologzhanina, E. S. Shubina
Tridecanuclear CuII11Na2 cagelike silsesquioxanes
Inorg. Chem., 2018, 57 (18), 11524–11529, DOI: 10.1021/acs.inorgchem.8b01496
G. S. Astakhov, A. N. Bilyachenko, A. Korlyukov, M. M. Levitsky, L. Shul'pina, X. Bantreil, F. Lamaty, A. Vologzhanina, E. S. Shubina, P. Dorovatovskii, D. Nesterov, A. Pombeiro, G. B. Shul’pin
High cluster (Cu9) cage silsesquioxanes. Synthesis, structure and catalytic activity

2017

Synthesis, 2017, 49(23), 5251-5257, DOI: 10.1055/s-0036-1588486
M. D. Matveevaa, T. N. Borisova, A. A. Titov, L. V. Anikina, S. V. Dyachenko, G. S. Astakhov, A. V. Varlamov, L. G. Voskressensky
Domino reactions of 1-aroyl-3,4-dihydroisoquinolines with ,-unsaturated aldehydes